• 제목/요약/키워드: Surface tension effect

검색결과 389건 처리시간 0.032초

저온 Plasma를 이용한 Poly(ethylene terephthalate)에의 Acrylic Acid의 기상 Graft 공중합 반응(I) (The Graft Polymerization of Acrylic Acid in Vapour Phase onto Poly(ethylene terephthalate) by Cold Plasma Part (I))

  • 천태일;최석철;모상영
    • 한국염색가공학회지
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    • 제1권1호
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    • pp.7-18
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    • 1989
  • The distinguishing characteristic of the glow discharge is that chemical reaction induced by partially ionized gases are limited only to the substrate surface. Most studies have been done on the plasma etching and polymerization. The graft polymerization in vapour phase by cold plasma has been rarely investigated. In this study the system of tub3ar reaction chamber with capacitively coupled electrode of alternative current of 60 Hz was employed for the graft polymerization. The graft polymerization of Acylic Acid(AA) onto the poly (ethylene terephthalate) (PET) was carried out by treatment of PET film and fabric by cold plasma (glow discharge of argon gas), followed by the supply of AA vapour. The graft yield was about 1 wt%. The surface property was determined by contact angle, the surface tension was evaluated by zisman’s plot and equation of surface tension mesurement. The results were as follows: 1. In order to obtain lower contact angle, it was effective to avoid the vicinity of electrodes for a setting position of substrate. 2. Contact angle affected on the monomer pressure and its duration of exposure to the acid vapour. 3. Polymer radical formation was influenced by the changes of the value of current density and plasma treatment time. 4. Total surface tension of plasma grafted PET film increased. With an increase in the carboxylic acid content, the dispersion force decreased, while, the polar force and hydrogen bonding force increased. 5. The contact angle decreased from $75^\circ$ to around $30^\circ$ by plasma grafting. There was no ageing effect on the contact angle after 4 months.

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Rosin변성 phenol수지의 분자량 변화에 따른 평판인쇄 잉크의 물성변화에 관한 연구 (The Effect of Changing Molecular Weight of Rosin Modified Phenol Resin on Physical Properties of Litho Printing Inks)

  • 김성빈
    • 한국인쇄학회지
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    • 제12권1호
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    • pp.145-157
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    • 1994
  • Litho printing ink vehicles based on rosin modified phenolic are faster drying, have better durability, are harder and glosser and have greater resistance to water than ones based on ester gums. Ink-Water balance and rheological properties are important in litho printing process. These physical properties is concerned with molecular weight of Resin to use vehicle. So this paper was studied about the effects of changing molecular weight of Rosin modified phenolic on surface tension, viscosity, pseudoplasticity and printability of Litho Inks. The results were as follows. 1) The surface tension of model inks depended on the molecular \veight of the resin : Dispersion componnent of ink increase but non dispersion component decrease as molecular weight of Resin increase. 2) Water pick-up of litho ink is more fast balance, using low molecular weight of Resin. 3) Viscosity, Yield value and Newtonian value of model inks increase as molecular weight of Resin increase. 4) The litho ink prepared with the modified phenolic of which molecular weight is about 20000 showed the highest printing density and gloss.

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초소형 밀폐형 이상 써모싸이폰 기포의 거동에 관한 해석적인 연구 (Analytical Study on the Behavior of the Bubble in the Micro Two-Phase Closed Thermosyphon)

  • 이윤표;이영수;이영
    • 설비공학논문집
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    • 제5권2호
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    • pp.85-93
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    • 1993
  • The rise of a large gas bubble or slug in a Micro Two-Phase Closed Thermosyphon with a thin wire insert has been analiged by the potential flow theory. The effect of the interfacial surface tension is explicitly accounted by application of the Kelvin-Laplace equation and solved for the bubble shape. The solution is expressed in terms of the Stokes stream function which consists of an infinite series of Bessel functions. The conditions of the bubble movement in a Micro Two-Phase Closed Thermosyphon were theoretically ascertained.

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삼각형 요소와 사각형 요소에 기초한 상승기포의 모사를 위한 Level set 방법 (Level set method for the simulation of rising bubble based on triangular and Quadrilateral elements)

  • 조명환;최형권;전병진;유정열
    • 한국전산유체공학회:학술대회논문집
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    • 한국전산유체공학회 2011년 춘계학술대회논문집
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    • pp.10-13
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    • 2011
  • A level set method is proposed to simulate the incompressible two-phase flow considering the effect of surface tension. For reinitialization of level set junction, a direct approach method is employed, instead of solving hyperbolic type equation. A mixed element is adopted, so that the continuity mid Navier-Stokes equations are solved by using the quadratic elements (six-node triangular element mid nine-node quadrilateral element), mid the level set function is solved by using the linear elements (three-node triangular element mid four-node quadrilateral element). In order to verify the accuracy mid robustness of the codes, the present methods are applied to a few benchmark problems. It is confirmed that the present results are in good qualitative mid quantitative agreements with the existing studies.

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초음파 에너지 부가 지젤연료의 화학적, 물리적 특성에 관한 연구 (A Study on the Chamical and Physical Characteristics of Ultrasonic-Energy-Added Diesel Fuel)

  • 최두석;윤면근;류정인
    • 한국자동차공학회논문집
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    • 제4권3호
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    • pp.147-155
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    • 1996
  • This study investigated the characteristics of ultrasonic-energy-added diesel fuel. We compared the characteristics used H-NMR spectrum, FT-IR spectrum, viscosity and surface tension between conventional diesel fuel and ultrasonic-energy-added diesel fuel. The result are obtained as follow : We knew that ultrasonic energy result to reduce BI and weaken viscosity and surface tension. Also, the ultrasonic energy caused to reduce aromatics Ha and increase Alkanes Hγ. The effect of ultrasonic-energy-added dieselfuel was principally caused by change of chemical structures and a physical characteristics.

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Effect of Hydrogenated Lecithin on Cytotoxicity of Liposome

  • Bae, Duck-Hwan;Shin, Jae-Sup;Jin, Fan-Long;Shin, Gwi-Su;Park, Soo-Jin
    • Bulletin of the Korean Chemical Society
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    • 제30권2호
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    • pp.339-342
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    • 2009
  • In this study, a hydrogenated lecithin-containing liposome was prepared using a sonicator and microfluidizer at high shear. The surface tension, particle size, turbidity, and transition temperature ($T_c$) of the liposome were investigated and compared with the commercially available standard surfactant Tween-60. The cytotoxicities were characterized using the MTT method. The surface tension of hydrogenated lecithin was found to be higher than that of Tween-60. The particle size prepared at above $T_c$ was smaller than that prepared below $T_c$. The results of the cytotoxicity experiment indicated that Lecinol 10 exhibits the highest I$C_{50}$ value, which shows its high safety in this study.

Torque Shear형 고장력 볼트 이음부의 피로거동에 관한 실험적 연구 (An Experimental Study on the Fatigue Behavior of Torque Shear Type High Tension Bolted Joints)

  • 장동일;이성욱
    • 한국강구조학회 논문집
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    • 제8권3호통권28호
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    • pp.151-160
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    • 1996
  • The fatigue test under the constant amplitude repeated loading is performed to investigate the fatigue behavior of the Torque Shear type high tension bolted joint which is able to manage the axial force uniformly. From the test results, it's known that the reduction of the axial force of T/S bolt followed by the elasped time is similar to that of the high tension bolts. The difference of relaxation is not occurred according to the position of bolts, the size of the introduced axial force but the effect of the variation of temperature is large. In the reduction of the axial force followed by the cumulation of the fatigue load, the outer bolt is larger than the inner bolt. This result depends on the difference in the distribution of the non-slip zone. The variation of the surface roughness affects the slip and the reduction of the anal force.

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콘크리트 파괴거동특성의 실험적 연구I-이축응력시험 (Experimental Study on Failure Behavior of Plain Concrete - Biaxial Stress Test)

  • 이상근;이상민;박상순;한상훈;송영철
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 2003년도 봄 학술발표회 논문집
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    • pp.315-320
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    • 2003
  • Two different strength types of plain concrete plate specimens (200$\times$200$\times$60mm) were tested under different biaxial load combinations. The specimens were subjected to biaxial combinations covering the three regions of compression-compression, compression-tension, and tension-tension. The loading platens with Teflon pads were used to reduce a confining effect in boundary surface between the concrete specimen and the solid platen. The principal deformations in the specimens were recorded, and the failure modes along with each stress ratio were examined. Based on the strength data, the failure envelops were developed for each type of plain concrete. The biaxial stress-strain responses of concrete plate specimens for three biaxial loading regions were also plotted. The test data indicated that the strength of concrete under biaxial compression ($f_2 / f_1$$_1$=-1/-1) is about 17 percent larger than under uniaxial compression.

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알파술폰 고급지방산 폴리에틸렌글리콜 에스테르류의 계면물성 (Surfaces Properties of ${\alpha}-Sulfonated$ Fatty Acid Polyethylene Glycol Esters)

  • 김진현;연영흠;윤영균;남기대
    • 한국응용과학기술학회지
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    • 제15권2호
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    • pp.11-24
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    • 1998
  • All the surface activities including surface tension, foaming power, foam stability, emulsifying power, dispersion effect, and detergency were measured and critical micelle concentration(cmc) was evaluated in dilute aqueous solution. The cmc evaluated by the Ring method was $10^{-3}{\sim}10^{-4}mol/L$ in case of monoesters, and $10^{-3}{\sim}5.0{\times}10^{-5}mol/L$ in case of diesters, respectively. Surface tension of the aqueous solution was decreased to $45{\sim}50dyne/cm$, showing the tendency that the ability of lowering the surface tension was dependent on increasing of carbon atom number in alkyl chain. Foaming power of all the monoesters was better than that of diesters. while foam stability of diesters was to the contrary. Emulsifying power of soybean oil or benzene was specially expected to be good for emulsifiers in industrial application fields. HLB values of monoesters and diesters evaluated by Griffin's method were in the range of 8 to 12. Dispersion property of ferric oxide was stable in the range of $4.5{\times}10^{-5}{\sim}5.0{\times}^{-4}mol/L$ in case of monoesters, and $10^{-5}{\sim}10^{-4}mol/L$ in case of diesters.

Isolation, Characterization, and Investigation of Surface and Hemolytic Activities of a Lipopeptide Biosurfactant Produced by Bacillus subtilis ATCC 6633

  • Dehghan-Noudeh Gholamreza;Housaindokht Mohammadreza;Bazzaz Bibi Sedigeh Fazly
    • Journal of Microbiology
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    • 제43권3호
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    • pp.272-276
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    • 2005
  • Bacillus subtilis ATCC 6633 was grown in BHIB medium supplemented with $Mn^{2+}$ for 96 h at $37^{\circ}C$ in a shaker incubator. After removing the microbial biomass, a lipopeptide biosurfactant was extracted from the supernatant. Its structure was established by chemical and spectroscopy methods. The structure was confirmed by physical properties, such as Hydrophile-Lipophile Balance (HLB), surface activity and erythrocyte hemolytic capacity. The critical micelle concentration (cmc) and erythrocyte hemolytic capacity of the biosurfactant were compared to those of surfactants such as SDS, BC (benzalkonium chloride), TTAB (tetradecyltrimethylammonium bromide) and HTAB (hexadecyltrimethylammonium bromide). The maximum hemolytic effect for all surfactants mentioned was observed at concentrations above cmc. The maximum hemolytic effect of synthetic surfactants was more than that of the biosurfactant produced by B. subtilis ATCC 6633. Therefore, biosurfactant would be considered a suitable surface-active agent due to low toxicity to the membrane.