• 제목/요약/키워드: Surface polarity

검색결과 171건 처리시간 0.031초

불소수지의 무전해 동도금을 위한 단계적 플라즈마 전처리법에 관한 연구 (Study on Two Step Plasma Treatment for Electroless Cu Plating of Fluoropolymer)

  • 신승한;한성호;김영석
    • 한국표면공학회지
    • /
    • 제38권3호
    • /
    • pp.118-125
    • /
    • 2005
  • Low temperature plasma treatment with different gases and rf powers were performed to improve the adhesion strength between polytetrafluoroethylene(PTFE) and electroless deposited copper. According to the research, $H_2$ plasma having hydrogen radical was more effective in surface polarity modification than $O_2$ plasma due to the defluorination reaction. However, surface roughness of PTFE was more increased with $O_2$ than $H_2$ plasma. PTFE treated with $120W-O_2$ plasma and $250w-H_2$ plasma, consecutively showed rougher surface than single step $250w-H_2$ plasma treated one and more hydrophilic than single step $120W-O_2$ plasma treated one. And it showed 5B tape test grade, which is better adhesion property than 1B or 3B obtained by single step plasma treatment. In addition, adhesion strength between PTFE and Cu deposit is also deeply affected by residual water on its interface.

곡면 자기연마에서의 자기력 형성과 가공특성에 관한 연구 (Evaluations of Magnetic Abrasive Polishing and Distribution of Magnetic Flux Density on the Curvature of Non-Ferrous Material)

  • 김상오;곽재섭
    • 대한기계학회논문집A
    • /
    • 제36권3호
    • /
    • pp.259-264
    • /
    • 2012
  • 비자성체의 자유곡면 자기연마 공정에서 자기력 세기의 향상은 매우 중요하다. 비자성체 자유곡면의 표면에 발생하는 자기력의 세기에 따라 자기연마 입자가 가지는 수직 절삭력이 변화하기 때문이다. 이러한 자기력 향상을 위하여 전자석 배열 테이블이 적용된 제 2세대 자기연마공정이 비자성체의 자유곡면 자기연마에 적용된다. 본 연구에서는 이러한 제 2세대 자기연마공정에서 전자석 배열 테이블에 발생하는 자기력 세기 향상을 위한 극성배열 방법을 제시하고 이를 알루미늄합금의 곡률 자기연마에 적용하였다. 그 결과 볼록 및 오목 형상에서 각각 S-N-S와 S-N-N-N-S 극성 배열에서 가장 높은 표면거칠기의 향상을 확인하였다. 또한 상승 가공경로에서 상대적으로 높은 표면거칠기 향상을 나타내었다.

자외선 카메라 개발을 위한 직류 연면방전 특성 (Characteristics of DC Surface Discharge for the Development of UV Camera)

  • 방만식;최재형;김우진;김영석;김상현
    • 조명전기설비학회논문지
    • /
    • 제25권5호
    • /
    • pp.98-103
    • /
    • 2011
  • Recently, UV(ultra-violet rays) camera has attracted a great deal of interest from the view point of easy judgement in inspections and diagnoses of the safety of power equipment. Especilly, UV camera is applied the inspection of UV with corona discharge. One of the most important and difficult problems is the basic research of filter design, materials and corona discharge. In this paper, we will report on the UV generation, corona pulse count and the polarity effect of positive and negative DC surface discharge in air. Also, corona discharge characteristics are analyzed using prototype UV camera of Korea. UV generation and corona pulse count due to surface discharge in positive needle is higher than that of negative needle.

Surface and Mechanical Interfacial Properties of Oxyfluorinated Carbon Fibers-reinforced Composites

  • Park, Soo-Jin;Seo, Min-Kang;Lee, Young-Seak
    • Carbon letters
    • /
    • 제4권2호
    • /
    • pp.69-73
    • /
    • 2003
  • In this work, the effect of a direct oxyfluorination on surface and mechanical interfacial properties of PAN-based carbon fibers is investigated. The changes of surface functional groups and chemical composition of the oxyfluorinated carbon fibers are determined by FT-IR and XPS measurements, respectively. ILSS of the composites is also studied in terms of oxyfluorination conditions. As a result, FT-IR exhibits that the carboxyl/ester groups (C=O) at 1632 $cm^{-1} and hydroxyl group (O-H) at 3450 $cm^{-1} are observed in the oxyfluorinated carbon fibers. Especially, the oxyfluorinated carbon fibers have a higher O-H peak intensity than that of the fluorinated ones. XPS result also shows that the surface functional groups, including C-O, C=O, HO-C=O, and C-$F_x$ after oxyfluorination are formed on the carbon fiber surfaces, which are more efficient and reactive to undergo an interfacial reaction to matrix materials. Moreover, the formation of C-$F_x$ physical bonding of the carbon fibers with fluorine increases the surface polarity of the fibers, resulting in increasing ILSS of the composites. This is probably due to the improvement of interfacial adhesion between fibers and matrix resins.

  • PDF

코로나 대전 특성을 이용한 FRP의 표면 열화메커니즘의 해석 (The Analysis of Surface Degradation Mechanism on PRP(epoxy/glass fiber) by Corona Charging Properties)

  • 이백수;임경범;정의남;박종관;이덕출
    • 대한전기학회논문지:전기물성ㆍ응용부문C
    • /
    • 제48권5호
    • /
    • pp.373-378
    • /
    • 1999
  • In order to analyse the degradation mechanism of polymer materials for outdoor condition, FRP laminate was exposed to high temperature and ultraviolet rays. Then, thedegradation process was evaluated by comparing contact angle, surface potential decay, and polarity effect respectively. Especially, the analysis of surface degradation phenomena by corona charging method showed the exact correlation with the result of chemical properties. Therefore we can confirm that the application of corona charging method on the identification of degradation process is very useful. If this method is usedin degradation studies on the polymer surface, it will be more effective on the surface analysis of polymer insulators. With corona charging method and chemical spectrum analysis, it was possible concretely to define degradation process on the polymer surface exposed at the situation of different environmental conditions.

  • PDF

The Growth Rate Difference in Lithium Triborate Single Crystal Along the Polar Direction

  • Jung, Jin-Ho;Chung, Su-Jin
    • The Korean Journal of Ceramics
    • /
    • 제6권1호
    • /
    • pp.53-57
    • /
    • 2000
  • It was observed that the growth rates are different each other in the opposite direction along c-axis due to the crystal polarity. In according to the calculation based on diffusional equations with consideration of the electrical polarization and the surface charge, the difference of growth rates could be explained. Some experiments were compared with this kinetic explanation.

  • PDF

유기물 박막에서 탄소 함량에 따라서 달라지는 분극의 변화에 따른 특성 변화에 대한 연구 (Study on the Characteristic due to the Various Polarity based on the Carbon Contents in Organic Thin Film)

  • 오데레사
    • 한국정보통신학회논문지
    • /
    • 제14권9호
    • /
    • pp.2065-2070
    • /
    • 2010
  • 유기박막 반도체 소자에서 주로 보호막으로 사용되는 PMMA 코팅 박막의 특성에 대하여 FTIR 분석법을 이용하여 조사하였다. 희석된 PMMA 혼합액은 비율에 따라서 $SiO_2$ 박막의 표면을 친수성, 소수성 혹은 하이브리드 특성으로 변화시켰다. FTIR 분석에 의하여 탄소의 함량이 적은 샘플 7에서 화학적인 변화가 크게 일어나는 것을 확인하였다. 전자를 많이 포함한 소량의 탄소가 $SiO_2$ 박막의 분극성을 감소시키고 박막의 표면에너지를 감소시켜서 화학적으로 안정된 박막의 표면을 형성하여 누설전류가 감소되었다. FTIR 분석은 유기화합물 박막에서 일어나는 화학적 변화에 대하여 미세한 부분까지 측정할 수 있는 척도로서 유용한 분석 방법임을 확인하였다.

전력케이블용 절연재료의 캐리어 극성 및 공간전하 측정기술에 관한 연구-PE-EVA에서의 하전입자의 거동 (A Study on the Space Charge Measurement Technique and Carrier Polarity of Insulating Materials on Power Cable)

  • 국상훈;박중순;강용철;권영수
    • 대한전기학회논문지
    • /
    • 제41권2호
    • /
    • pp.185-191
    • /
    • 1992
  • In this paper, it is attempted to distinguish the charged particles and to judge the polarity by the use of Thermally Stimulated Current(TSC) and Temperature Gradient Thermally Stimulated Surface Potential Measurement(TG-TSSP)with experimental insulation material XLPE-EVA for power cables which is made by blending cross-linked polyethylene(XLPE) and ethylene-vinylacetate copolymer(EVA). In addition, it is performed to investigate the effect of EVA blending. From the experimental results, it is known that for the case of XLPE-EVA blended experimental material, the generation of space charged electric field is not obtained in the high temperature region due to the obatruction of the injection of trapping carrier by the electron and the positive hole.

  • PDF

폴리에틸렌-n-헥산-벤젠계에 대한 투과속도와 용해도 파라메타 사이의 관계 (The Relationship Between the Permeation Rate and the Solubility Parameter for Polyethylene-n-Hexane-Benzene System in Pervaporation)

  • Rhim, Ji-Won
    • 멤브레인
    • /
    • 제3권3호
    • /
    • pp.136-139
    • /
    • 1993
  • It is well known that the membrane permeation in pervaporation is governed by both the chemical nature of the membrane material and the physical structure of the membrane and also the separation can be achieved by differences in either solubility, size or shape. The solubility of the penerrant in the polymeric membrane can be described qualitively by applying the Hildebrand relation [1] which relates the energy of mixing of the penerrant and the polymer material. Froehling et al. have tried to predict the swelling behavior of polymers for the systems of polyvinylchloride(PVC)-toluene-methanol, PVC-trichloroethylene-nitromethane and PVC-n-butylacetate-nitromethane[2]. The former two systems which do not show the donor/acceptor interactions upon mixing showed the successful results[2]. In addition to this technique, there are several other possible approaches to predict the swelling behaviors of polymers, such as the surface thermodynamic approach[3, 4], the comparison of the membrane polarity with the solvent polarity in terms of Dimroth's solvent polarity value[5].

  • PDF

Polarity Index Dependence of M13 Bacteriophage-based Nanostructure for Structural Color-based Sensing

  • Lee, Yujin;Moon, Jong-Sik;Kim, Kyujung;Oh, Jin-Woo
    • Current Optics and Photonics
    • /
    • 제1권1호
    • /
    • pp.12-16
    • /
    • 2017
  • Color sensor systems based on M13 bacteriophage are being considerably researched. Although many studies on M13 bacteriophage-based chemical sensing of TNT, endocrine disrupting chemicals, and antibiotics have been undertaken, the fundamental physical and chemical properties of M13 bacteriophage-based nanostructures require further research. A simple M13 bacteriophage-based colorimetric sensor was fabricated by a simple pulling technique, and M13 bacteriophage was genetically engineered using a phage display technique to exhibit a negatively charged surface. Arrays of structurally and genetically modified M13 bacteriophage that can determine the polarity indexes of various alcohols were found. In this research, an M13 bacteriophage-based color sensor was used to detect various types of alcohols, including methanol, ethanol, and methanol/butanol mixtures, in order to investigate the polarity-related property of the sensor. Studies of the fundamental chemical sensing properties of M13 bacteriophage-based nanostructures should result in wider applications of M13 bacteriophage-based colorimetric sensors.