• KSCE Journal of Civil and Environmental Engineering Research
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• v.30 no.2C
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• pp.133-140
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• 2010

A series of triaxial test was performed in order to determine critical state parameters of calcareous Jeju sand, which comprises angular shape particles with many pores in the surface. It is observed that Jeju sand mainly shows the contractive behavior during triaxial shear due to high extreme void ratios and large compressibility. The peak friction angle of Jeju sand decreases slightly with increasing mean effective stress due to the particle crushing of carbonate materials. However, the peak friction angle of Jeju sand is higher than that of other silica sands because of the more angular particle shape. The critical state friction angle of Jeju sand gradually decreases when the mean effective stress at a critical state increases. Whereas, there is not a clear influence of void ratio on the critical state friction angle. Critical state parameters of Jeju sand are similar to those of calcareous sands, but significantly larger than those of common sands.

• Advances in nano research
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• v.16 no.5
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• pp.473-487
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• 2024

The current study employs the nonlocal Timoshenko beam (NTB) theory and von-Kármán's geometric nonlinearity to develop a non-classic beam model for evaluating the nonlinear free vibration of bi-directional functionally-graded (BFG) nanobeams. In order to avoid the stretching-bending coupling in the equations of motion, the problem is formulated based on the physical middle surface. The governing equations of motion and the relevant boundary conditions have been determined using Hamilton's principle, followed by discretization using the differential quadrature method (DQM). To determine the frequencies of nonlinear vibrations in the BFG nanobeams, a direct iterative algorithm is used for solving the discretized underlying equations. The model verification is conducted by making a comparison between the obtained results and benchmark results reported in prior studies. In the present work, the effects of amplitude ratio, nanobeam length, material distribution, nonlocality, and boundary conditions are examined on the nonlinear frequency of BFG nanobeams through a parametric study. As a main result, it is observed that the nonlinear vibration frequencies are greater than the linear vibration frequencies for the same amplitude of the nonlinear oscillator. The study finds that the difference between the dimensionless linear frequency and the nonlinear frequency is smaller for CC nanobeams compared to SS nanobeams, particularly within the α range of 0 to 1.5, where the impact of geometric nonlinearity on CC nanobeams can be disregarded. Furthermore, the nonlinear frequency ratio exhibits an increasing trend as the parameter µ is incremented, with a diminishing dependency on nanobeam length (L). Additionally, it is established that as the nanobeam length increases, a critical point is reached at which a sharp rise in the nonlinear frequency ratio occurs, particularly within the nanobeam length range of 10 nm to 30 nm. These findings collectively contribute to a comprehensive understanding of the nonlinear vibration behavior of BFG nanobeams in relation to various parameters.

• Tunnel and Underground Space
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• v.16 no.2 s.61
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• pp.166-178
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• 2006

Recently, the frequency of occurring dynamic events such as earthquakes, explosives blasting and other types of vibration has been increasing. Besides, the chances of exposure for rock discontinuities to free faces get higher as the scale of rock mass structures become larger. For that reason, the frictional behavior of rock joints under dynamic conditions needs to be investigated. In this study, artificially fractured rock joint specimens were prepared in order to examine the dynamic frictional behavior of rough rock joint. Roughness of each specimen was characterized by measuring surface topography using a laser profilometer and a series of shaking table tests was carried out. For mated joints, the static friction angle back-calculated ken the yield acceleration was $2.7^{\circ}$ lower than the tilt angle on average. The averaged dynamic friction angle for unmated joints was $1.8^{\circ}$ lower than the tilt angle. Displacement patterns of sliding block were classified into 4 types and proved to be related to the first order asperity of rock joint. The tilt angle and the static friction angle for mated joints seem to be correlated to micro average inclination angle which represents the second order asperity. The tilt angle and the dynamic friction angle for unmated Joints, however, have no correlation with roughness parameters. Friction angles obtained by shaking table test were lower than those by direct shear test.

• Korean Chemical Engineering Research
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• v.57 no.5
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• pp.679-686
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• 2019

Characteristics of adsorption equilibrium, kinetic and thermodynamic of aniline blue onto activated carbon from aqueous solution were investigated as function of initial concentration, contact time and temperature. Adsorption isotherm of aniline blue was analyzed by Langmuir, Freundlich, Redlich-Peterson, Temkin and Dubinin-Radushkevich models. Langmuir isotherm model fit better with isothermal data than other isotherm models. Estmated Langmuir separation factors ($R_L=0.036{\sim}0.068$) indicated that adsorption process of aniline blue by activated carbon could be an effective treatment method. Adsorption kinetic data were fitted to pseudo first order model, pseudo second order model and intraparticle diffusion models. The kinetic results showed that the adsorption of aniline blue onto activated carbon well followed pseudo second-order model. Adsorption mechanism was evaluated in two steps, film diffusion and intraparticle diffusion, by intraparticle diffusion model. Thermodynamic parameters such as Gibbs free energy, enthalpy and entropy for adsorption process were estimated. Enthalpy change (48.49 kJ/mol) indicated that this adsorption process was physical adsorption and endothermic. Since Gibbs free energy decreased with increasing temperature, the adsorption reaction became more spontaneously with increasing temperature. The isosteric heat of adsorption indicated that there is interaction between the adsorbent and the adsorbate because the energy heterogeneity of the adsorbent surface.

• Journal of Soil and Groundwater Environment
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• v.18 no.1
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• pp.26-35
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• 2013

Outbreak of animal infectious diseases such as foot-and-mouth disease, avian influenza are becoming prevalent worldwide. For prevent the further infection, tremendous numbers of the infected or culled stocks are buried around farm. This burial method can generate a wide range of detrimental components such as leachate, nutrient, salt, and pathogenic bacteria, consequently. In this study, for the stabilization of livestock carcasses leachate, advanced oxidation processes utilizing the Fenton reaction was investigated in lab-scale experiments for the treatment for $COD_{Cr}$ of livestock carcass leachate. $COD_{Cr}$ reduction by the Fenton oxidation was investigated response surface methodology using the Box-Begnken methods were applied to the experimental results. A central composite design was used to investigate the effects of the independent variables of pH ($x_1$), dosage of $FeCl_2{\cdot}4H_2O$ ($x_2$) and dosage of $H_2O_2$ ($x_3$) on the dependent variables $COD_{Cr}$ concentration ($y_1$). A 1 M NaOH and $H_2SO_4$ was using for pH control, $FeCl_2{\cdot}4H_2O$ was used as iron catalyst and NaOH was used for Fenton reaction. The optimal conditions for Fenton oxidation process were determined: pH, dosage of $FeCl_2{\cdot}4H_2O$ and dosage of $H_2O_2$ were 3, 0.6 g (0.0151 M) and 7 mL(0.259 M), respectively. Statistical results showed the order of significance of the independent variables to be pH > initial concentration of ferrous ion > initial concentration of hydrogen peroxide.

• Journal of the Computational Structural Engineering Institute of Korea
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• v.19 no.2 s.72
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• pp.171-185
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• 2006

A sophisticated reliability analysis method is proposed to evaluate the reliability of real nonlinear complicated dynamic structural systems excited by short duration dynamic loadings like earthquake motions by intelligently integrating the response surface method, the finite element method, the first-order reliability method, and the iterative linear interpolation scheme. The method explicitly considers all major sources of nonlinearity and uncertainty in the load and resistance-related random variables. The unique feature of the technique is that the seismic loading is applied in the time domain, providing an alternative to the classical random vibration approach. The four-parameter Richard model is used to represent the flexibility of connections of real steel frames. Uncertainties in the Richard parameters are also incorporated in the algorithm. The laterally flexible steel frame is then reinforced with reinforced concrete shear walls. The stiffness degradation of shear walls after cracking is also considered. The applicability of the method to estimate the reliability of real structures is demonstrated by considering three examples; a laterally flexible steel frame with fully restrained connections, the same steel frame with partially restrained connections with different rigidities, and a steel frame reinforced with concrete shear walls.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2008.11a
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• pp.363-363
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• 2008

The development of dry etching process for sapphire wafer with plasma has been key issues for the opto-electric devices. The challenges are increasing control and obtaining low plasma induced-damage because an unwanted scattering of radiation is caused by the spatial disorder of pattern and variation of surface roughness. The plasma-induced damages during plasma etching process can be classified as impurity contamination of residual etch products or bonding disruption in lattice due to charged particle bombardment. Therefor, fine pattern technology with low damaged etching process and high etch rate are urgently needed. Until now, there are a lot of reports on the etching of sapphire wafer with using $Cl_2$/Ar, $BCl_3$/Ar, HBr/Ar and so on [1]. However, the etch behavior of sapphire wafer have investigated with variation of only one parameter while other parameters are fixed. In this study, we investigated the effect of pressure and other parameters on the etch rate and the selectivity. We selected $BCl_3$ as an etch ant because $BCl_3$ plasmas are widely used in etching process of oxide materials. In plasma, the $BCl_3$ molecule can be dissociated into B radical, $B^+$ ion, Cl radical and $Cl^+$ ion. However, the $BCl_3$ molecule can be dissociated into B radical or $B^+$ ion easier than Cl radical or $Cl^+$ ion. First, we evaluated the etch behaviors of sapphire wafer in $BCl_3$/additive gases (Ar, $N_2,Cl_2$) gases. The behavior of etch rate of sapphire substrate was monitored as a function of additive gas ratio to $BCl_3$ based plasma, total flow rate, r.f. power, d.c. bias under different pressures of 5 mTorr, 10 mTorr, 20 mTorr and 30 mTorr. The etch rates of sapphire wafer, $SiO_2$ and PR were measured with using alpha step surface profiler. In order to understand the changes of radicals, volume density of Cl, B radical and BCl molecule were investigated with optical emission spectroscopy (OES). The chemical states of $Al_2O_3$ thin films were studied with energy dispersive X-ray (EDX) and depth profile anlysis of auger electron spectroscopy (AES). The enhancement of sapphire substrate can be explained by the reactive ion etching mechanism with the competition of the formation of volatile $AlCl_3$, $Al_2Cl_6$ or $BOCl_3$ and the sputter effect by energetic ions.

• Korean Chemical Engineering Research
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• v.52 no.1
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• pp.133-140
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• 2014

The experiment was designed to compare the char combustion kinetics of pulverized Indonesia coals commonly utilized in Korea power plants. The reaction rate of coal char has been formulated using the external and internal effectiveness factors to describe the diffusion effect quantitatively. The Random Pore Model (RPM) was used for applying internal specific surface area as a function of carbon conversion ratio. Reaction rate was obtained from reaction time using the Wire Heating Reactor (WHR) which can heat and measure the char particle temperature at the same time. BET and TGA were used to obtain physical properties such as internal specific surface area and structural parameter. Three kinds of Indonesia Sub-bituminous coals "BARAMULTI, ENERGYMAN, AGM" were used in order to derive the activation energy and pre-exponential factor. The results of this study showed that the effect of internal diffusion than that of external diffusion is the dominant as comparison of kinetics was reflected in external and internal effectiveness factors. For three kinds of coal char, finally, activation energy of intrinsic kinetics indicates 110~118 kJ/mol.

• The Journal of Engineering Geology
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• v.29 no.2
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• pp.137-151
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• 2019

Geophysical exploration techniques are effective for monitoring changes in the ground condition around the excavation project to prevent subsidence risks during excavation work, therefore, improving analysis techniques is required for applying and supplementing various geophysical exploration technologies. In this study, a field-scale on-site test was conducted to detect possible ground subsidence hazards and areas of relaxation zone that may occur during excavation work and due to underground water level changes. In order to carry out the field test, a real-scale excavation test bed was constructed and the geophysical exploration methods, such as electrical resistivity survey and multi-channel analysis of surface wave (MASW) survey for urban sites condition, have researched for optimal geophysical exploration parameter, design and correlation analysis between the results by reviewing the validity of each individual geophysical exploration and modeling. The results of this study showed the impact of each geophysical exploration on the relaxation zone and, in particular, the location of the underground water surface and the effects of excavation were identified using electrical resistivity survey. Further research on modeling will be required, taking into account the effects of excavation and groundwater.

• Journal of Korean Society of Forest Science
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• v.102 no.4
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• pp.467-476
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• 2013

Site index information given from forest site map only exist in the sampled locations. In this study, site index for unsampled locations were estimated using kriging interpolation method which can interpolate values between point samples to generate a continuous surface. Site index of Pinus densiplora in Danyang area were calculated using Chapman-Richards model by plot unit. Then site index for unsampled locations were interpolated by theoretical variogram models and ordinary kriging. Also in order to assess parameter selection, cross-validation was performed by calculating mean error (ME), average standard error (ASE) and root mean square error (RMSE). In result, gaussian model was excluded because of the biggest relative nugget (37.40%). Then spherical model (16.80%) and exponential model (8.77%) were selected. Site index estimates of Pinus densiplora throughout the entire area in Danyang showed 4.39~19.53 based on exponential model, and 4.54~19.23 based on spherical model. By cross-validation, RMSE had almost no difference. But ME and ASE from spherical model were slightly lower than exponential model. Therefore site index prediction map from spherical model were finally selected. Average site index from site prediction map was 10.78. It can be expected that regional variance can be considered by site index prediction map in order to estimate forest biomass which has big spatial variance and eventually it is helpful to improve an accuracy of forest carbon estimation.