• Title/Summary/Keyword: Surface modifier

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Effects of heat-moisture treatment of rice flour on the properties in tofu

  • An, Shu;Lee, Kwang Yeon;Lee, Hyeon Gyu
    • Korean Journal of Food Science and Technology
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    • v.53 no.1
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    • pp.92-98
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    • 2021
  • The effects of heat-moisture treatment (HMT) on rice flour (RF) have been investigated for possibility of texture modifier in protein-based foods matrix, tofu. The optimum condition for preparation of tofu with maximum textural parameters was investigated by using response surface methodology (RSM). Rice flour was subjected to moisture content (10-30%) and heating temperature (100-140℃). Based on the response surface and superimposed plots, the optimized conditions of hydrothermally treated rice flour was as followed: moisture content, 22%; temperature, 130℃, which showed lower swelling power as compared to native RF and became more stable during continuous heating and agitation than native one. Tofu, prepared with HMT-RF, showed a denser network structure than that with RF, thereby inducing an increase in textural parameters. From the above results, the addition of HMT-RF could preserve the quality of tofu and be useful for developing an acceptable protein-based food product.

Surface Modification Silica Nanoparticles by Aerosol Self Assembly (에어로졸 자기조립에 의한 실리카 나노분말의 표면개질)

  • Kil, Dae-Sup;Jang, Hee-Dong;Chang, Han-Kwon;Cho, Kuk;Kim, Sun-Kyung;Oh, Kyoung-Joon;Choi, Jin-Hoon
    • Korean Journal of Materials Research
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    • v.20 no.2
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    • pp.78-81
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    • 2010
  • Surface modification of silica nanoparticles was investigated using an aerosol self assembly. Stearic acid was used as surface treating agent. A two-fluid jet nozzle was employed to generate an aerosol of the colloidal suspension, which contained 20 nm of silica nanoparticles, surface modifier, and ethyl alcohol. Powder properties such as morphology, specific surface area and pore size distribution were analyzed by SEM, BET and BJH methods, respectively. Surface properties of the silica power were analyzed by FT-IR. The OH bond of the $SiO_2$ surface was converted to a C-H bond. It was revealed that the hydrophilic surface changed to a hydrophobic one due to the aerosol self assembly. Morphology of the surface treated powder was nanostructured with lots of pores having an average diameter of around $2\;{\mu}m$. Depending on the stearic acid concentration (0.25 to 1.0 wt%), the pore size distribution of the particles and the degree of hydrophobicity ranged from 1.5 nm to 180 nm and 29.6% to 50.2%, respectively.

Development and Performance Evaluation of Positively Charged Porous Filter media for Water Purification System (정수 설비를 위한 양전하가 부가된 다공성 수처리 필터 개발과 성능평가)

  • Lee, Chang-Gun;Joo, Ho-Young;Lee, Jae-Keun;Ahn, Young-Chull;Park, Seong-En
    • Proceedings of the SAREK Conference
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    • 2006.06a
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    • pp.95-98
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    • 2006
  • Filtration by fibrous filter is one of the Principle methods used for removing pollutant particles in the liquid. Because of the increasing need to protect both human health and valuable devices from exposure to fine particles, filtration has become more important. Filters have been developed with modified surface charge characteristics to capture and adsorb particles by electrokinetic interaction between the filter surface and particles contained in water. The main purposes of this study are to develop and evaluate the performance evaluation of the apparatus for making a positively charged porous filter media and to analyze the surface characteristics of the filter media for capturing negavitely charged contaminants mainly bacteria and virus from water. The experimental apparatus consists of a mixing tank, a vacuum pumping system, a injection nozzle, a roller press and a controller. The filter media is composed of glass fiber(50-750 nm), cellulose($10-20{\mu}m$) and colloidal charge modifier. The characteristics of filter media is analyzed by SEM(Scanning Electron Microscopy), AFM(Atomic Force Microscopy) and quantified by measuring the zeta potential values.

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Study on the Improvement of the Electrochemical Characteristics of Surface-modified V-Ti-Cr alloy by Ball-milling

  • Kim, Jin-Ho;Lee, Sang-Min;Lee, Ho;Lee, Paul S.;Lee, Jai-Young
    • Transactions of the Korean hydrogen and new energy society
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    • v.12 no.1
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    • pp.39-50
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    • 2001
  • Vanadium based solid solution alloys have been studied as a potential negative electrode of Ni/MH battery due to their high hydrogen storage capacity. In order to improve the kinetic property of V-Ti alloy in KOH electrolyte, the ball-milling process with Ni, which has a catalytic effect of hydrogen absorption/desorption, was carried out to modify the surface properties of V-Ti-Cr alloys with high hydrogen storage capacity. Moreover, to overcome the problem of poor cycle life, V-Ti alloy substituted by Cr, V0.68 Ti0.20 Cr0.12, has been developed showing a good cycle performance (keeping about 80 % of initial discharge capacity after 200 cycles). The cycle life of surface-modified V0.68 Ti0.20 Cr0.12 alloy was improved by suppressing the formation of TiO2 layer on the alloy surface while decreasing the amount of dissolved vanadium in the KOH electrolyte. In order to promote the effect of Ni coating on the surface property of V0.68 Ti 0.20 Cr 0.12 alloy by ball-milling, filamentary-typed Ni, which has higher surface coverage area than sphere-typed Ni was used as a surface modifier. Consequently, the surface-modified V0.68 Ti0.20 Cr0.12 alloy electrode showed a improved discharge capacity of 460 mAh/g.

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Development of fiber reinforced self-compacting concrete (FRSCC): Towards an efficient utilization of quaternary composite binders and fibers

  • Fediuk, Roman;Mosaberpanah, Mohammad A.;Lesovik, Valery
    • Advances in concrete construction
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    • v.9 no.4
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    • pp.387-395
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    • 2020
  • This study has been carried out in two-phases to develop Fiber Reinforced Self-Compacting Concrete (FRSCC) performance. In the first phase, the composition of the quaternary composite binder compromised CEM I 42.5N (58-70%), Rice Husk Ash (25-37%), quartz sand (2.5-7.5%) and limestone crushing waste (2.5-7.5%) were optimized. And in the second phase, the effect of two fiber types (steel brass-plated and basalt) was investigated on the SCC optimized with the optimum CB as disperse reinforcement at 6 different ratios of 1, 1.2, 1.4, 1.6, 1.8, and 2.0% by weight of mix for each type. In this study, the theoretical principles of the synthesis of self-compacting dispersion-reinforced concrete have been developed which consists of optimizing structure-formation processes through the use of a mineral modifier, together with ground crushed cement in a vario-planetary mill to a specific surface area of 550 m2 / kg. The amorphous silica in the modifier composition intensifies the binding of calcium hydroxide formed during the hydration of C3S, helps reduce the basicity of the cement-composite, while reducing the growth of portlandite crystals. Limestone particles contribute to the formation of calcium hydrocarbonate and, together with fine ground quartz sand; act as microfiller, clogging the pores of the cement. Furthermore, the results revealed that the effect of fiber addition improves the mechanical properties of FRSCC. It was found that the steel fiber performed better than basalt fiber on tensile strength and modulus of elasticity; however, both fibers have the same performance on the first crack strength and sample destruction of FRSCC. It also illustrates that there will be an optimum percentage of fiber addition.

A New Organic Modifiers for Anti-Stiction (부착방지를 위한 새로운 표면 개질 물질)

  • Kim, Bong-Hwan;Chun, Kuk-Jin;Lee, Yoon-Sik
    • Journal of Sensor Science and Technology
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    • v.11 no.2
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    • pp.102-110
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    • 2002
  • The chemical and mechanical characteristics of a new surface modifier, dichlorodimethysilane (DDMS, $(CH_3)_3SiCl_2$), for stiction-free polysilicon surfaces are reported. The main strategy is to replace the conventional monoalkyltrichlorosilane(MTS, $RSiCl_3$) such as octadecyltrichlorosilane (ODTS) or 1H,1H,2H,2H-perfluorodecyltrichlorosilane (FDTS) with dialkyldichlorosilane (DDS, $R_2SiCl_2$) with twit short chains, especially DDMS. DDMS, with shorter chains in aprotic media, rapidly deposits on the chemically oxidized polysilicon surface at room temperature and successfully prevents long cantilevers of 3 mm in length from in-use as well as release stiction. DDMS-modified polysilicon surfaces exhibit satisfactory hydrophobicity, long term stability and thermal stability, which are comparable to those of FDTS. DDMS as an alternative to FDTS and ODTS provides a few valuable advantages; ease in handling and long-term storage in solution, low temperature-dependence and low cost. In addition to the new modifier molecule, the simplified process of direct release right after washing the modified surface with isooctane was proposed to cut the processing time.

Effect of fiber-matrix adhesion on the fracture behavior of a carbon fiber reinforced thermoplastic-modified epoxy matrix

  • Carrillo-Escalante, H.J.;Alvarez-Castillo, A.;Valadez-Gonzalez, A.;Herrera-Franco, P. J.
    • Carbon letters
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    • v.19
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    • pp.47-56
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    • 2016
  • In this study, the fracture behavior of a thermoplastic-modified epoxy resin reinforced with continuous carbon fibers for two levels of fiber-matrix adhesion was performed. A carbon fiber with commercial sizing was used and also treated with a known silane, (3-glycidoxy propyl trimethoxysilane) coupling agent. Toughness was determined using the double cantilever test, together with surface analysis after failure using scanning electron microscope. The presence of polysulfone particles improved the fracture behavior of the composite, but fiber-matrix adhesion seemed to play a very important role in the performance of the composite material. There appeared to be a synergy between the matrix modifier and the fiber-matrix adhesion coupling agent.

A Study on the Partial Discharge Resistance Properties of Epoxy/Micro/Nano Alumina Composites (에폭시/마이크로/나노알루미나 콤포지트의 부분방전 저항성특성)

  • Park, Jae-Jun
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.65 no.6
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    • pp.1026-1031
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    • 2016
  • Neat Epoxy, nano alumina composites, micro alumina composites and multi-nano alumina composites were prepared and experiment were performed to measure their partial discharge resistant characteristics. The partial discharge resistance obtained for the microcomposites, nanocomposites and multi-nanocomposites are compared with those of unfilled epoxy and with GDE amount for surface modifier. It was observed that compare multi-nano alumina composites to micro alumina composites, the partial discharge resistance to degradation gets improved considerably. The improvement in the degradation resistance is attributed to the interface intension between the nano alumina composites and GDE, micro alumina and epoxy neat.

The Effects of Additional Factors on the Engine Friction Characteristics (엔진 마찰 특성에 미치는 부수적 인자의 영향)

  • Cho, Myung-Rae;Kim, Joong-Soo;Oh, Dae-Yoon;Han, Dong-Chul
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.26 no.10
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    • pp.2159-2164
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    • 2002
  • This paper reports on the effects of additional factors on the engine friction characteristics. The total friction loss of engine is composed of pumping and mechanical friction loss. The pumping loss was calculated from the cylinder pressure, and the mechanical friction loss was measured by strip-down method under the motoring condition. The various parameters were tested. The engine friction loss was much affected by oil and coolant temperature. The low viscosity oil was very effective to reduce the friction loss, and friction modifier was very useful to reduce the friction loss at lower engine speed. The engine friction loss was varied with engine running time because of surface roughness decreasing and oil degradation. To prevent oil-churning effect, it was very important to maintain the proper oil level. The presented results will be very useful to understand friction characteristics of engine.

Development and Characterization of the Asphalt Binder with Low-heat and Crosslink Structured Additive

  • Eun Kyoung Lee;You Kyoung Kim
    • Elastomers and Composites
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    • v.57 no.4
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    • pp.222-230
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    • 2022
  • In this study, a low-heat additive with a crosslink structure was dispersed in asphalt to simultaneously lower the production temperature of, and to modify the asphalt binder. This low-heat additive was prepared by different feeding ratios of styrene-butadiene-styrene (SBS) and polyvinylchloride (PVC) as polymer modifiers, and ZnO as a crosslinking agent. In order to confirm the crosslinking density and compatibility of the crosslink structured low-heat additive with asphalt, surface free energy, swelling ratio, differential scanning calorimetry (DSC), and scanning electron microscope (SEM) parameters were carefully investigated to examine this relationship, and the role of the crosslink structured low-heat additive. In addition, by measuring the penetration and softening point of the asphalt binder, it was confirmed that it corresponds to PG 64-22. With increasing ZnO in the crosslink structured low-heat additive, the swelling ratio decreased, leading to an increase in crosslinking density. The crosslink structured low-heat additive and the asphalt binder were found to be compatible with each other by DSC and SEM analysis.