• 제목/요약/키워드: Surface modifications

검색결과 239건 처리시간 0.021초

외판 전개를 응용한 무형틀 FRP선박 건조방법 (Production Method of FRP Boat Using Developable Surface without a Mould)

  • 양지만;하윤석;김효철
    • 대한조선학회논문집
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    • 제42권5호
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    • pp.506-515
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    • 2005
  • Novel ships are commonly required iterative hull form modifications until she get reputation for new marine environment. Small FRP boats are manufactured in a identical shape with a mould. It implies that every modification step requires great time and expense which makes it difficult to improve the hull form promptly. Domestic hull form of small fishing boat of force has been evolved from the traditional hull form of developable shape. Utilizing this typical developable characteristics of small boats, ,New mouldless production method for FRP boat has been suggested and it is confirmed that the method is recommendable for a petty order of hull in evolving period of hull form development.

Bimetallic Pd@Ni-mesoporous TiO2 nanocatalyst for highly improved and selective hydrogenation of carbonyl compounds under UV light radiation

  • Bathla, Aadil;Pal, Bonamali
    • Journal of Industrial and Engineering Chemistry
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    • 제67권
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    • pp.486-496
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    • 2018
  • Bimetallic Pd@Ni nanostructure exhibited enhanced co-catalytic activity for the selective hydrogenation of benzaldehyde compare to their monometallic counterparts. Impregnation of these mono/bimetallic nanostructures on mesoporous $TiO_2$ leads to several surface modifications. The bimetallic PNT-3 ($Pd_3@Ni_1/mTiO_2$) exhibited large surface area ($212m^2g^{-1}$), and low recombination rate of the charge carriers ($e^--h^+$). The hydrogenation reaction was analyzed under controlled experiments. It was observed that under UV-light irradiations and saturated hydrogen atmosphere the bimetallic PNT-3 photocatalyst display higher rate constant $k=5.31{\times}10^{-1}h^{-1}$ owing to reduction in the barrier height which leads to efficiently transfer of electron at bimetallic/$mTiO_2$ interface.

디스플레이 기기용 강화유리 절단기의 안정화 설계 (Stability Design of a Laser Cutter for the Strengthened Glass)

  • 노승훈;박유라;류영찬;김영조;이태훈
    • 반도체디스플레이기술학회지
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    • 제14권1호
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    • pp.19-25
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    • 2015
  • Strengthened glass is widely used in the display industry for the smart phone and the tablet PC's, the market of which shows steady growth. The strengthened glass is prone to the fracture due to the machined surface defects such as crack and notch. The surface defects are caused mostly by the vibrations of the laser cutter. In this study, the vibrations of the laser cutter were investigated through the frequency response experiment and the computer simulation. The main reasons of the structural vibrations were analyzed, and further the design alterations were deduced and applied to the machine to check the effects of those alterations and to eventually improve the structural stability. The result shows that simple design modifications without major structural change can substantially suppress the vibrations, and improve the quality of the machined surface.

산소 플라즈마 처리에 의한 반도전-절연 실리콘 고무의 접착 특성 (Adhesion Characteristics of Semiconductive and Insulating Silicone Rubber by Oxygen Plasma Treatment)

  • 이기택;허창수
    • 한국전기전자재료학회논문지
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    • 제19권2호
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    • pp.153-157
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    • 2006
  • In this work, the effects of plasma treatment on surface properties of semiconductive silicone rubber were investigated in terms of X-ray photoelectron spectroscopy (XPS) and contact angles, The adhesion characteristics of semiconductive-insulating interface layer of silicone rubber were studied by measuring the T-peel strengths, The results of the chemical analysis showed that C-H bonds were broken due to plasma discharge and Silica-like bonds(SiOx, x=3${\~}$4) increased, It is thought that semiconductive silicone rubber surfaces treated with plasma discharge led to an increase in oxygen-containing functional groups, resulting in improving the degree of adhesion of the semiconductive-insulating interface layer of silicone rubber. However, the oxygen plama for 20 minute produces a damaged oxidized semiconductive silicone rubber layer, which acts as a weak layer producing a decrease in T-peel strength, These results are probably due to the modifications of surface functional groups or polar component of surface free energy of the semiconductive silicone rubber.

Surface Crystalline Modification for Asymmetric Giant Mngnetoimpedance Profile in Annealed Co-based Amorphous Ribbons

  • Rheem, Y.W;Kim, C.G;Kim, C.O;Choi, Y
    • Journal of Magnetics
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    • 제6권3호
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    • pp.86-89
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    • 2001
  • Microstructure modifications are investigated for annealed Co-based amorphous ribbon in vacuum and open air. X-ray diffraction (XRD) spectra for annealed sample in vacuum indicate atomic arrangements with initial nucleation of hcp-Co crystallite at 38$0^{\circ}C$ annealing temperature. However, the XRD spectra in samples with long annealing times of $t_a\geq300$ min demonstrate sharp and good developed surface crystalline hcp-, fcc- Co and $Co_2$Si phases. The giant magnetoimpedance (GMI) profile at 0.1 MHz displaying one-peak behavior in vacuum annealed samples at T = 38$0^{\circ}C$ irrespective of annealing time $t_a$ from 20 to 480 mim. For the annealed samples in an open air, the GMI profile shows two-peaks for $t_a$ = 20 min annealed sample. However, one of peaks disappears and an asymmetric GMI profile exhibits a drastic step-like change near zero field for $t_a\geq300$min. Such asymmetric GMI characteristics is related to the surface microstructures of fcc-Co, hop-Co and $Co_2$Si crystalline phases.

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광 포획 향상을 위한 다중 아키텍처 식각 기술을 적용한 박막 실리콘 태양전지에 관한 연구 (A Study on Thin-Film Silicon Solar Cells with Multi-Architecture Etching Technique to Improve Light Trapping)

  • 박형기;이준신
    • 한국전기전자재료학회논문지
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    • 제37권3호
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    • pp.337-344
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    • 2024
  • This work focuses on improving the light-harvesting efficiency of thin-film silicon solar cells through innovative multi-architecture surface modifications. To create a regular optical structure, a lithographic process was performed to form it on a glass substrate through various etching processes, from Etch-1 to Etch-3. AZO was deposited on top of the structures and re-etched to create a multi-architectural surface. These surface-modified structures improved the light absorption and overall performance of the solar cell through changes in optical and physical properties, which we will analyze. In addition, we investigated the effect of post-cleaning on the etched glass structures through EDX analysis to understand the mechanism of the etching action. The results of this study are expected to provide important guidelines for the design and fabrication of solar cells and other photovoltaic devices.

Shear bond strength of composite resin to high performance polymer PEKK according to surface treatments and bonding materials

  • Lee, Ki-Sun;Shin, Myoung-Sik;Lee, Jeong-Yol;Ryu, Jae-Jun;Shin, Sang-Wan
    • The Journal of Advanced Prosthodontics
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    • 제9권5호
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    • pp.350-357
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    • 2017
  • PURPOSE. The object of the present study was to evaluate the shear bonding strength of composite to PEKK by applying several methods of surface treatment associated with various bonding materials. MATERIALS AND METHODS. One hundred and fifty PEKK specimens were assigned randomly to fifteen groups (n = 10) with the combination of three different surface treatments (95% sulfuric acid etching, airborne abrasion with $50{\mu}m$ alumina, and airborne abrasion with $110{\mu}m$ silica-coating alumina) and five different bonding materials (Luxatemp Glaze & Bond, Visio.link, All-Bond Universal, Single Bond Universal, and Monobond Plus with Heliobond). After surface treatment, surface roughness and contact angles were examined. Topography modifications after surface treatment were assessed with scanning electron microscopy. Resin composite was mounted on each specimen and then subjected to shear bond strength (SBS) test. SBS data were analyzed statistically using two-way ANOVA, and post-hoc Tukey's test (P<.05). RESULTS. Regardless of bonding materials, mechanical surface treatment groups yielded significantly higher shear bonding strength values than chemical surface treatment groups. Unlike other adhesives, MDP and silane containing self-etching universal adhesive (Single Bond Universal) showed an effective shear bonding strength regardless of surface treatment method. CONCLUSION. Mechanical surface treatment behaves better in terms of PEKK bonding. In addition, self-etching universal adhesive (Single Bond Universal) can be an alternative bonding material to PEKK irrespective of surface treatment method.

Bone-like Apatite Formation on Ultrafine-Structure in Modified Electrolytic Solution

  • Jang, Jae-Myung;Choe, Han-Cheol
    • 한국표면공학회:학술대회논문집
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    • 한국표면공학회 2017년도 춘계학술대회 논문집
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    • pp.155-155
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    • 2017
  • Surface modifications are commonly utilized to adjust the properties of the titanium and its alloy surface to the specific needs of the medical applications, but there are disadvantages such as poor osteoconductive properties and low adhesion of bone cell to implant surface. In order to improve these disadvantages, changes in surface properties have an important effect on osseointegration during implantation. In this paper we applied new technological method for improving a unique surface modification using the characteristic of an electrolytic Solution. Thus, in the electrolyte containing NaF in Na2SO4, TiO2 nanoporous was uniformly formed, and HAp nanoparticles were electrodeposited around the TiO2 nanopores, but in the electrolyte containing NH4F in (NH4)H2PO4, the coarse protrusions including HAp nano particles were regularly deposited onto the TiO2 barrier layer. The surface characteristics and the distributed elements and have been investigated by EDS analysis, and ultra-fine structure of surface are carried out using FE-SEM. To investigate the behavior of the anion, the analysis of chemical states was performed by XPS, and the narrow spectrums for Ti2P, Ca 2p, and P 2p seems to be almost similar depending on the characteristics of the electrolyte solution respectively. In addition, Ca 2p spectrum could be resolved into two peaks for Ca 2p3/2 and 2p1/2 at 347.4 and 351.3 eV, which are related to hydroxyapatite. And, the P peak can also be deconvoluted into two peaks for P1/2 and P3/2 levels with binding energy 134.2 and 133.4 eV, respectively. From the result of soaking test, the apatite morphologys were well-formed onto the modified surface according to the different conditions.

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Size-dependent analysis of functionally graded ultra-thin films

  • Shaat, M.;Mahmoud, F.F.;Alshorbagy, A.E.;Alieldin, S.S.;Meletis, E.I.
    • Structural Engineering and Mechanics
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    • 제44권4호
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    • pp.431-448
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    • 2012
  • In this paper, the first-order shear deformation theory (FSDT) (Mindlin) for continuum incorporating surface energy is exploited to study the static behavior of ultra-thin functionally graded (FG) plates. The size-dependent mechanical response is very important while the plate thickness reduces to micro/nano scales. Bulk stresses on the surfaces are required to satisfy the surface balance conditions involving surface stresses. Unlike the classical continuum plate models, the bulk transverse normal stress is preserved here. By incorporating the surface energies into the principle of minimum potential energy, a series of continuum governing differential equations which include intrinsic length scales are derived. The modifications over the classical continuum stiffness are also obtained. To illustrate the application of the theory, simply supported micro/nano scaled rectangular films subjected to a transverse mechanical load are investigated. Numerical examples are presented to present the effects of surface energies on the behavior of functionally graded (FG) film, whose effective elastic moduli of its bulk material are represented by the simple power law. The proposed model is then used for a comparison between the continuum analysis of FG ultra-thin plates with and without incorporating surface effects. Also, the transverse shear strain effect is studied by a comparison between the FG plate behavior based on Kirchhoff and Mindlin assumptions. In our analysis the residual surface tension under unstrained conditions and the surface Lame constants are expected to be the same for the upper and lower surfaces of the FG plate. The proposed model is verified by previous work.

NDT Determination of Cement Mortar Compressive Strength Using SASW Technique

  • Cho, Young-Sang
    • KCI Concrete Journal
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    • 제13권2호
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    • pp.10-18
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    • 2001
  • The spectral analysis of surface waves (SASW) method, which is an in-situ seismic technique, has mainly been developed and used for many years to determine the stiffness profile of layered media (such as asphalt concrete and layered soils) in an infinite half-space. This paper presents a modified experimental technique for nondestructive evaluation of in-place cement mortar compressive strength in single-layer concrete slabs of rather a finite thickness through a correlation to surface wave velocity. This correlation can be used in the quality control of early age cement mortar structures and in evaluating the integrity of structural members where the infinite half space condition is not met. In the proposed SASW field test, the surface of the structural members is subjected to an impact, using a 12 mm steel ball, to generate surface wave energy at various frequencies. Two accelerometer receivers detect the energy transmitted through the medium. By digitizing the analog receiver outputs, and recording the signals for spectral analysis, surface wave velocities can be identified. Modifications to the SASW method includes the reduction of boundary reflections as adopted on the surface waves before the point where the reflected compression waves reach the receivers. In this study, the correlation between the surface wave velocity and the compressive strength of cement mortar is developed using one 36"x36"x4"(91.44$\times$91.44$\times$91.44 cm) cement mortar slab of 2,000 psi (140 kgf/$\textrm{cm}^2$) and two 36"x36"x4"(91.44$\times$91.44$\times$91.44 cm) cement mortar slabs of 3,000 psi (210 kgf/$\textrm{cm}^2$).

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