• Title/Summary/Keyword: Surface modification

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Surface modification of polymeric membranes for low protein binding

  • Higuchi, Akon;Tamai, Miho;Tagawa, Yoh-Ichi;Chang, Yung;Ling, Qing-Dong
    • Membrane and Water Treatment
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    • v.1 no.2
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    • pp.103-120
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    • 2010
  • Surface modification of microfiltration and ultrafiltration membranes has been widely used to improve the protein adsorption resistance and permeation properties of hydrophobic membranes. Several surface modification methods for converting conventional membranes into low-protein-binding membranes are reviewed. They are categorized as either physical modification or chemical modification of the membrane surface. Physical modification of the membrane surface can be achieved by coating it with hydrophilic polymers, hydrophilic-hydrophobic copolymers, surfactants or proteins. Another method of physical modification is plasma treatment with gases. A hydrophilic membrane surface can be also generated during phase-inverted micro-separation during membrane formation, by blending hydrophilic or hydrophilic-hydrophobic polymers with a hydrophobic base membrane polymer. The most widely used method of chemical modification is surface grafting of a hydrophilic polymer by UV polymerization because it is the easiest method; the membranes are dipped into monomers with and without photo-initiators, then irradiated with UV. Plasma-induced polymerization of hydrophilic monomers on the surface is another popular method, and surface chemical reactions have also been developed by several researchers. Several important examples of physical and chemical modifications of membrane surfaces for low-protein-binding are summarized in this article.

Effect of Surface Modification Process Conditions on Properties of Aramid Paper (아라미드 종이의 특성에 대한 표면 개질 과정 조건의 영향)

  • Sha, Lizheng;Zhao, Huifang
    • Polymer(Korea)
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    • v.37 no.2
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    • pp.196-203
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    • 2013
  • Surface modification of meta-aramid fibers was performed by phosphoric acid treatment. Surface morphology and element composition of untreated and treated fibers were analyzed by scanning electron microscope (SEM) and X-ray photoelectron spectroscopy (XPS). Effects of surface modification on the mechanical strength of aramid papers made from meta-aramid fibers and fibrid were investigated. Surface modification conditions were optimized by response surface analysis (RSA). Results show that phosphoric acid treatment increases the surface roughness and oxygen content of aramid fibers. They improve the interface bonding strength between aramid fibers and fibrid, which improves the tensile strength of aramid papers. The results of response surface analysis indicate that the tensile strength of aramid papers increases by 47.5% and reaches the maximum when meta-aramid fibers are treated with 21.1wt% phosphoric acid solution at $39.3^{\circ}C$ for 36.7 min.

Advanced Surface Modification Techniques for Enhancing Osseointegration of Titanium Implant (임상가를 위한 특집 1 - 티타늄 임플란트의 골융합 증진을 위한 최신 표면처리 기술)

  • Song, Ho-Jun
    • The Journal of the Korean dental association
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    • v.48 no.2
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    • pp.96-105
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    • 2010
  • Titanium implant is used as the most popular dental material for replacement of missing teeth recently. A lot of studies on the surface modification of titanium implant have been carried out for enhancing osseointegration. The surface modification techniques could be classified as follows; topographic modifications which provide roughness and porosity, chemical surface modificationss or deposition of osseoconductive materials, and biochemical modifications to immobilize bone growth factors on titanium surface. In this study, the current and ongoing surface modification techniques and its typical characteristics used in clinics were reviewed. In the future, study and implication about biochemical modifications including patient' s individual characteristics will be important.

A Rapid Local Modification Algorithm for NURBS surface (NURBS 곡면의 고속 부분 수정 알고리듬 개발)

  • 김호찬;최홍태;김준안;이석희
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2004.10a
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    • pp.1402-1405
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    • 2004
  • Algorithms on modification of NURBS surface requires modeling history to change its boundary conditions. The history is stored when the surface is modeled and saved in the corresponding model file. But when the model is transferred to other systems the history generally cannot be recognized. So modification algorithms without history is highly required. Previous works on the field is concentrated in the point based modification without any restriction condition. Therefore this study is intended to develope a curved based modification algorithm with restriction conditions. A rapid modification algorithm is suggested, implemented and tested.

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Surface modification of materials by thermal plasma (열플라즈마를 이용한 재료의 표면개질)

  • Kang, Seong-Pyo;Lee, Han Jun;Kim, Tae-Hee
    • Journal of the Korean institute of surface engineering
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    • v.55 no.6
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    • pp.308-318
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    • 2022
  • The surface modification and treatment using thermal plasma were reviewed in academic fields. In general, thermal plasma is generated by direct current (DC) and radiofrequency (RF) power sources. Thermal spray coating, a typical commercial process using thermal plasma, is performed by DC thermal plasma, whereas other promising surface modifications have been reported and developed using RF thermal plasma. Beyond the thermal spray coating, physical and chemical surface modifications were attempted widely. Superhydrophobic surface treatment has a very high industrial demand particularly. Besides, RF thermal plasma system for large-area film surface treatment is being developed. Thermal plasma is especially suitable for the surface modification of low-dimensional nanomaterial (e.g., nanotubes) by utilizing high temperature and rapid quenching. It is able to synthesize and modify nanomaterials simultaneously in a one-pot process.

Surface modification of Aluminum for mold by nitrogen ion implantation (질소이온주입에 의한 금형용 알루미늄의 표면개질특성)

  • 강혁진;안성훈;김경동;이재상;이재형
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2004.10a
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    • pp.254-259
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    • 2004
  • The research on surface modification technology has been advanced to change the properties of engineering material. Ion implantation is a novel surface modification technology to enhance the mechanical, chemical and electronic properties of mechanical parts. In this research, nitrogen ions are implanted into aluminum for mold to improve endurance and life span. To analyze modification of surface properties, micro hardness, friction coefficient, wear resistance, contact angle, and surface roughness were measured. Hardness of ion implanted specimens was higher than untreated specimen and friction coefficient was also improved. In this experiment, it can be expected that nitrogen ion implantation can contribute to enhance the mechanical properties of material and ion implantation technology may also be applied to other materials.

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Modification methods of polyethersulfone membranes for minimizing fouling - Review

  • Sathish Kumar, R.;Arthanareeswaran, G.;Paul, Diby;Kweon, Ji Hyang
    • Membrane and Water Treatment
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    • v.6 no.4
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    • pp.323-337
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    • 2015
  • Membrane Fouling was considered as major drawback in various industrial applications. Thus, this paper reviews the surface modification of polyethersulfone (PES) membranes for antifouling performance. Various modification techniques clearly indicate that hydrophilicity has to improve on the PES membrane surface. Moreover, the mechanism of fouling reduction with corresponds to various modification methods is widely discussed. Incorporation of hydrophilic functional groups on PES membrane surface enhances the surface free energy thereby which reduces the fouling. Characterization techniques adopted for the surface modified membranes was also discussed. These studies might be useful for the other researchers to utilize the modification technique for the applications of waste water treatment, chemical process industry and food industry.

A Study on the Ultrasonic Nano Crystal Surface Modification(UNSM) Technology and It's Application (초음파 나노표면개질기술의 특성과 활용방안 연구)

  • Pyoun, Young-Sik;Park, Jeong-Hyeon;Cho, In-Ho;Kim, Chang-Sik;Suh, Chang-Min
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.33 no.3
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    • pp.190-195
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    • 2009
  • All the failure in fatigue of torsion, bending and rolling contact, and in sliding wear begins mostly from surface. So much efforts have been invested to the surface technology which deal these problems during past decades, but the industrial demand keeps growing and more significant requirements are added to researchers and engineers. Nano crystal surface modification technology which makes the surface layers into nano crystalline, induces big and deep compressive residual stress, increases surface hardness, improves surface hardness, and make micro dimples structure on surface is an emerging technology which can break limits of current surface technology and relieve the burden of researchers and engineers. In this study, a nano crystal surface modification technology which is calling UNSM(Ultrasonic nano crystal surface modification) technology, is introduced and how it has been applied to industry to solve these failure problems is explained.

Surface Modification of Polymethyl methacrylate(PMMA) by Laser Surface Treatment for Microfluidic Chip (유체소자 성능향상을 위한 Polymethyl methacrylate(PMMA)의 레이저 표면처리)

  • Shin, Sung-Kwon;Lee, Sang-Don;Lee, Cheon
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.56 no.2
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    • pp.334-337
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    • 2007
  • After the advent of micro-Total Analysis Systems(${\mu}-TAS$) based on silicon various polymer for microfluidic chip has been studied. Polymer materials for microfluidic compared with silicon and glass which were traditional materials of a microfluidic chip, have the advantages of economical efficiency simple manufacturing process and wide materials selectivity corresponding to fluids. Surface energy of polymers we, however lower than silicon or glass. To overcome this problem, various surface modification methods have been investigated. The surface modification using laser has the advantage of the simple experiment that only directly irradiated laser beam on the material surface in the air. This work discuss the surface modification of polymethly methacrylate(PMMA) by 4th harmonic Nd:YAG laser (${\lambda}266nm$, pulse) treatment. After the laser treatment, the PMMA surface was investigated using a contact angle measuring instrument. The contact angle was decreased with a increase of the surface oxygen content. This result means the surface energy of PMMA was increased by the laser treatment without changing of its bulk characteristics.

Surface Modification Method of Stainless Steel using Electrochemical Etching (전기화학적 에칭을 이용한 스테인리스 스틸의 표면 개질)

  • Lee, Chan;Kim, Joonwon
    • Journal of the Korean Society for Precision Engineering
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    • v.31 no.4
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    • pp.353-358
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    • 2014
  • This paper reports a simple, yet effective 1-step surface modification method for stainless steel. Electrochemical etching in dilute Aqua Regia forms hierarchical micro and nanoscale structure on the surface. The surface becomes highly hydrophobic (${\sim}150^{\circ}$) as a result of the etching in terms of static contact angle (CA). However the liquid drops easily pinned on the surface because of high contact angle hysteresis (CAH), which is called a "petal effect": The petal effect occur because of gap between surface microstructures, despite of intrinsic hydrophobicity of the base material. The pore size and period of surface structure can be controlled by applied voltage during the etching. This method can be applied to wide variety of industrial demand for surface modification, while maintaining the advantageous anti-corrosion property of stainless steel.