• Title/Summary/Keyword: Surface migration

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Fabrication of electro phoresis microchips and effects of channel surface properties (마이크로 전기영동 소자의 제작과 유로 면 특성에 따른 전기삼투 및 전기영동 효과)

  • Kim, Min-Su;Cho, Seung-Il;Lee, Kook-Nyung;Kim, Yong-Kweon
    • Proceedings of the KIEE Conference
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    • 2003.10a
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    • pp.286-289
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    • 2003
  • We investigated the influence of the properties of substrate material on the separation efficiency in microchip electrophoresis. We fabricated the various microchips and studied separation efficiency in microchannels composed of a single material such as quartz, glass, polydimethylsiloxane (PDMS), and polymethylmetha crylate (PMMA), as well as hybrid micro channels composed of different materials. New fabrication process for glass chip was suggested and some treatment is added to improve fabrication process in other chip. Separation efficiency was compared by measuring migration times and bandwidths of EOF and analytes in each microchip. The efficiency is the function of migration time, which is affected by the electroosmotic flow (EOF), and bandwidth of an analyte. EOF is highly dependent upon the characteristics of a microchannel wall surface. Migration time was more reproducible in silica chips than that of PDMS chip and more band broadening was observed in the microchip composed of hybrid material due to non-uniformity of surface charge density at the walls of the channel.

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Effect of Moisture Migration in Concrete with Hating Rate on Concrete Spalling (가열속도에 따른 콘크리트 내부의 수분이동이 폭렬발생에 미치는 영향)

  • Choe, Gyeong-Cheol;Kim, Gyu-Yong;Nam, Jeong-Soo;Kim, Hong-Seop;Yoon, Min-Ho;Hwang, Ui-Chul
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2017.05a
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    • pp.246-247
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    • 2017
  • In this study, it reviewed the effect of moisture migration in concrete with heating rate on concrete spalling. Concrete specimens with compressive strength 30MPa and 110MPa are used and its size is □100×100×h200mm. And, two kinds of heating rate are set such as IS0 834 and 1℃/min. As a result, in the concrete specimen exposed to ISO 834 standard heating condition, moisture could migrate through pore network and surface concrete pieces fall out by generating moisture clog near the surface in 110MPa concrete specimen. Meanwhile, In the case of concrete specimens exposed to 1℃/min. heating condition, it is appeared that moisture could not migrate because temperature is distributed uniformly. Therefore, surface spalling is not occurred with low heating rate. However, in the case of 110MPa concrete specimen is exploded even though it heated by low heating rate.

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Study on the Migration of Fluorescent Whitening Agents Used for Papermaking Process (제지용 형광증백제의 전이현상에 대한 기초연구)

  • Lee, Ji Young;Kim, Chul Hwan;Sung, Yong Joo;Kim, Eun Hea;Kim, Jae Hyung;Park, Tae Ung
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.48 no.3
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    • pp.5-13
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    • 2016
  • This study investigated the effects of different factors on the migration of a fluorescent whitening agent (FWA) from paper treated with FWAs to non-fluorescent papers. FWA migration experiments were carried out in vertical and friction contacts between the papers dyed with FWAs and non-fluorescent papers. During the experiments, we identified the effects of the addition and types of FWAs, contact time, temperature, and relative humidity (RH) on FWA migration. The fluorescence indices of the non-fluorescent papers were measured before and after the migration experiments, and the Student's t test, a statistical tool, was utilized to compare results from different migration experiments. In vertical contact experiments, FWA migration to non-fluorescent paper was observed at $30^{\circ}C$ and 70% RH; this was attributed to the high moisture content of the paper. FWA migration did not occur significantly at $23^{\circ}C$ and 50% RH. In the friction contact experiments, FWA migrations were identified at both temperature conditions and RH percentages. The addition and types of FWAs did not increase the fluorescence index of non-fluorescent papers. Therefore, it was concluded that the moisture content of paper and the friction contact affected FWA migration from the papers containing internal and surface FWAs.

Behavior of Hydroxide Ions at the Water-Ice Surface by Low Energy Sputtering Method

  • Kim, S.Y.;Park, E.H.;Kang, H.
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.02a
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    • pp.338-338
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    • 2011
  • The behavior of hydroxide ions on water-ice films was studied by using $Cs^+$ reactive ion scattering (RIS), low energy sputtering (LES) and temperature-programmed desorption (TPD). A $Cs^+$ beam of a low kinetic energy (<100 eV) from $Cs^+$ ion gun was scattered at the film surface, and then $Cs^+$ projectiles pick up the neutral molecules on the surface as $Cs^+$-molecule clusters form (RIS process). In LES process, the preexisting ions on the surface are desorbed by the $Cs^+$ beam impact. The water-ice films made of a thick (>50 BL) $H_2$O layer and a thin $D_2O$ overlayer were controlled in temperatures 90~140K. We prepared hydroxide ions by using Na atoms which proceeded hydrolysis reaction either on the ice film surface or at the interface of the $H_2O$ and $D_2O$ layers.[1] The migration of hydroxide ions from the $H_2O/D_2O$ interface to the top of the film was examined as afunction of time. From this experiment, we show that hydroxide ions tend to reside at the water-ice surface. We also investigated the H/D exchange reactions of $H_2O$ and $D_2O$ molecules mediated by hydroxide ions to reveal the mechanism of migration of hydroxide to the ice surface.

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Promotion of 3T3 and HDF Cell Migration by Gelatin-modified Fibroin Microspheres

  • Se Change Kwon;Won Hur
    • Applied Chemistry for Engineering
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    • v.34 no.2
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    • pp.186-191
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    • 2023
  • The goal of this study was to use gelatin to modify the surface of fibroin microspheres to enhance their biofunctionality for tissue engineering and regenerative medicine applications. Three different methods were used for the modification: coating, incorporation, and covalent bonding. Wound-healing assays demonstrated that gelatin modification of fibroin microspheres enhances 3T3 and HDF cell migration. Although the level of gelatin coverage varied depending on the method used, there was no significant difference between the modified microspheres. The gelatin-modified microspheres also increased the migration velocity of individual 3T3 cells. The results suggest that gelatin modification of fibroin microspheres is a promising approach for developing functional biomaterials with enhanced biological properties. Further optimization of gelatin modification is necessary to maximize the biofunctionality of fibroin microspheres.

Hydroacoustic Observations on the Diel Distribution and Activity Patterns of Fishes in the East China Sea II - Vertical Speed of Migration and Variation in Scattering Strength - (동중국해에 있어서 어족생물의 일주기적 여영행동특성에 관한 연구 II - 연직이동속도 및 산란강도의 변동 -)

  • 이대재
    • Journal of the Korean Society of Fisheries and Ocean Technology
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    • v.30 no.4
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    • pp.251-262
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    • 1994
  • The speed of vertical migration and the volume backscattering strength of the scattering layers during the evening and morning transitions between day and night were measured in November 1990-1992 in thermally stratified waters of the East China Sea. Acoustical measurements were carried out using a scientific echo-sounder operating at t재 frequencies of 25 and 100kHz, and using an echo-integration system connected with a micro-computer. Biological sampling was accomplished by bottom trawling to identify fish species recorded on the echo sounder, and the species and length compositions were determined. The values of scattering strength were allocated to group of fishes according to the fish traces on the echo recording paper and the species composition of trawl catches. The vertical velocities of migration derived from the changes in the depths and the values of peak scattering strength of the dense layer vertically migrating toward the bottom or toward the surface. The trawl data suggest that snailfish and fishing frog were the most abundant fishes in all research stations. As sunrise approached, the fish formed a strong concentration just above the thermocline. The the highest values of scattering strength in the entire water column appeared in the depth strata above the thermocline just before the begining of downward migration. As soon as the fish began to migrate downwards across the thermocline, the values of the scattering strength in the depth strata above the thermocline rapidly decreased, while the values for the scattering layer moving slowly toward the bottom gradually increased. During the 1992 surveys, the speed of the vertical migration was estimated to be 0.38m/min in the upward migration and 0.32m/min in the downward migration, respectively. That is the rate of vertical migration was slightly higher at dusk than at dawn. Similar migration patterns were observed on different stations and under different weather conditions during the surveys in 1990.

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Electrochemical Migration Characteristics of Sn-3.0Ag-0.5Cu Solder Alloy in NaBr and NaF Solutions (NaBr 및 NaF 용액에 대한 Sn-3.0Ag-0.5Cu 솔더 합금의 Electrochemical Migration 특성)

  • Jung, Ja-Young;Jang, Eun-Jung;Yoo, Young-Ran;Lee, Shin-Bok;Kim, Young-Sik;Joo, Young-Chang;Chung, Tai-Joo;Lee, Kyu-Hwan;Park, Young-Bae
    • Journal of Welding and Joining
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    • v.25 no.3
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    • pp.57-63
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    • 2007
  • Electrochemical migration characteristics of Pb-free solder alloys are quantitatively correlated with corrosion characteristics in harsh environment conditions. In-situ water drop test and corrosion resistance test for Sn-3.0Ag-0.5Cu solder alloys were carried out in NaBr and NaF solutions to obtain the electrochemical migration lifetime and pitting potential, respectively. Sn-3.0Ag-0.5Cu solder alloy shows similar ionization and electrochemical migration behavior with pure Sn because of Ag and Cu do not migrate due to the formation of resistant intermetallic compounds inside solder itself. Electrochemical migration lifetime in NaBr is longer than in NaF, which seems to be closely related to higher pitting potential in NaBr than NaF solution. Therefore, it was revealed that electrochemical migration lifetime of Sn-3.0Ag-0.5Cu solder alloys showed good correlation to the corrosion resistance, and also the initial ionization step at anode side is believed to be the rate-determining step during electrochemical migration of Pb-free solders in these environments.

A Study on the Effect of Metallic Fillers and Plastic for Ionic Migration (이온마이그레이션에 대한 플라스틱과 금속첨가제의 영향 연구)

  • Jeon, Sang Soo;Kim, Ji Jung;Lee, Ho Seung
    • Journal of Auto-vehicle Safety Association
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    • v.13 no.2
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    • pp.30-34
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    • 2021
  • Electrical failures and reliability problems of electronic components by ionic migration between adjacent device terminals have become an issue in automotive electronics. Especially unlike galvanic corrosion, ionic migration is occurred at high temperature and high humidity under applied electric field condition. Until now, although extensive studies of the ionic migrations dealing with PCBs, electrodes, and solders were reported, there is no study on the effect of insulation polymers and metallic fillers for ionic migration. In this research, therefore, ionic migration induced by the types and contents of polymers and metallic fillers, and variety conditions of temperature, humidity, and applied voltage was studied in detail. Ester and amide types of liquid crystal polymer (LCP) and poly (phthalamide) (PPA) were used as base polymers, respectively and compounded with the metallic fillers of Copper iodide (CuI), Zinc stearate (Zn-st), or Calcium stearate (Ca-st) in various compositions. The compounding polymers were fabricated in IPC-B-24 of SIR test coupon according to ISO 9455-17 with Cu electrodes for ionic migration test. While there is no change in LCP-based samples, ionic migration in PPA compounding sample with a high water absorption property was accelerated in the presence of 0.25 wt% or above of CuI at the environmental conditions of 85℃, 85% RH and 48V. The dendritic short-circuit growth of Cu caused by ionic migration between the electrodes on the surface of compounded polymers was systematically observed and analyzed by using optical microscopy and SEM (EDX).

Diel Vertical Distribution of Cyanobacteria in Lake Daecheong (대청호의 남조세균 일주 수직분포)

  • Park, Jong-Geun;Kim, Yeoun-Suk;Lee, Jung-Jun;Jang, Sung-Hyun;Lee, Jung-Ho
    • ALGAE
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    • v.21 no.1
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    • pp.75-82
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    • 2006
  • Cyanobacteria regulate their buoyancy in response to changing environmental conditions. This process is essential for cyanobacterial development and can account for their dominance in eutrophic waters in summer. The present investigation was conducted to understand the 24-hour vertical distribution of cyanobacteria and water quality characteristics in Lake Daecheong. Water samples were collected and analyzed at depth intervals of 2 or 3 m and at an interval of three hours for a day on August 28, 2001 and September 24, 2002. In 2001 the accumulated standing crop of Microcystis spp. from surface to a depth of 6 m was 94.9%. Microcystis spp. showed no vertical migration below the thermocline. Microcystis spp. had maximum density near the surface, but shifted to 2 m depth at 2 p.m. A dense population of Anabaena spp. accumulated near the surface from 2 to 5 p.m. in 2002.

Anodizing science of valve metals

  • Moon, Sungmo
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2017.05a
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    • pp.96.1-96.1
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    • 2017
  • This presentation introduces anodizing science of typical valve metals of Al, Mg and Ti, based on the ionic transport through the andic oxide films in various electrolyte compositions. Depending on the electrolyte composition, metal ions and anions can migrate through the andic oxide film without its dielectric breakdown when point defects are present within the anodic oxide films under high applied electric field. On the other hand, if anodic oxide films are broken by local joule heating due to ionic migration, metal ions and anions can migrate through the broken sites and meet together to form new anodic films, known as plasma electrolytic oxidation (PEO) treatment. In this presentation, basics of conventional anodizing and PEO methods are introduced in detail, based on the ionic migration and movement mechanism through anodic oxide films by point defects and by local dielectric breakdown of anodic oxide films.

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