• Title/Summary/Keyword: Surface migration

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Differentiation of Sorptive Bindings of Some Radionuclides with Sequential Chemical Extractions in Sandstones (순차적화학추출법을 사용한 방사성핵종의 사암에 대한 수착유형 평가)

  • Park, Chung-Kyun;Hahn, Pil-Soo;Park, Hun-Hwee
    • Nuclear Engineering and Technology
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    • v.26 no.4
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    • pp.461-470
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    • 1994
  • Sorption experiments of $^{60}$ Co, $^{85}$ Sr. and $^{137}$ Cs onto sandstone particles in a batch were carried out to investigate the migration mobility. Sorption kinetics and reversibility as well as sorption mechanisms were examined. Sorption reaction occurred mostly within 10 hours on the outer surface of the sandstone particle but diffusion into the inner surface of the mineral has still occurred after that time. In order to distinguish sorption types of radionuclides, a sequential chemical extraction was introduced. The sorbed radionuclides were then extracted by applying different solutions of synthetic groundwater, CaCl$_2$, KCl and KOX-HA Especially KCl is adopted to extract the ion-exchanged cesium. Sorption types considered are reversible sorption under groundwater condition, ion exchange, association with ferro-manganese oxides or oxyhydroxides, and irreversible fixation. Strontium sorbs onto the sandstone surface mainly by fast and reversible ion exchange reaction. However, cobalt and cesium do not sorb by simple process. The main sorptive binding of cobalt was the association with ferro-manganese oxides and the secondary one was irreversible fixation. Diffusion into the lattice of minerals controlled the sorption rate of cobalt The main sorptin type of cesium was irreversible fixation, while ion exchange reaction was the secondary importance. Hence the oreder of migration mobility for the three radionuclides was Sr$^{2+}$ > Co$^{2+}$ > Cs$^{+}$ in the sandstones.

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The Effect of decalcified Root Surface as PDGF Carrier (PDGF 함유매개체로서 탈회된 치근면의 효과)

  • Woo, Hyo-Sang;Lee, Jae-Mok;Suh, Jo-Young
    • Journal of Periodontal and Implant Science
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    • v.26 no.4
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    • pp.889-905
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    • 1996
  • It is known that growth factors function as potent biologic mediators regulating numerous activities of wound healing via cell proliferation, migration and extracellular matrix formation and they also promote periodontal regeneration. But, method of growth factor application is controversial yet. So purpose of this study is to evaluate the effect of demineralized root surface as one of method of growth factor application. The ginigival fibroblasts were primary cultured and fifth or sixth subpassages were used in these experiments. In first experiment, root surface blocks demineralized with 100mg/ml tetracycline for 5 minutes and pH 1 citric acid for 3 minutes(experimental groups) and nonteminerilized root surface blocks (control groups) were placed in 100ng/ml PDGF-BB for 5 minutes. Then the cells were seeded on each root surface blocks and cultured for 6, 24, 48, 72 hours. In second experiment, root surface blocks deminerilized with tetracycline and citric acid and nondemineralized root surface blocks were placed in 200ng/ml PDGF-BB for 5 minutes and another non-demineralized root surfcae blocks were placed in DMEM without PDGF-BB. At 1, 2, 4, 6, 8 days, the cells were seeded in 24-well plate and using of each eluent, cultured for 72 hours. The results of the four determinants were presented as mean and S.D.. The results were as follows : The attachment and proliferation of human gingival fibroblast on root surface were more increased when PDGF-BB was applicated on root surfrace demineralized with tetracycline or citric acid than non-demineralized root surface. And, in comparision tetracycline with citric acid, there were more attachment and proliferation of human gingival fibroblast on root surface demineralized with tetracycline than citric acid, and proliferation of human gingival fibroblast on demineralized root surface was increased time dependently 1 day to 3 days. In second experiment using eluent, proliferation of human gingival fibroblast was more increased to 6 days when human gingival fibroblast was cultured in eluent that PDGF-BB was applicated on demineralized root surface than two control groups, and degree of proliferation was decreased time dependently 1 day to 6 days. Proliferation of human gingival fibroblast cultured in eluent without PDGF-BB was constant 1 day to 6 days. After 6 days, degree of proliferation of human gingival fibroblast was similar in four groups. This means that release duration of PDGF-BB from demineralized root surface is 6 days. And in comparision tetracycline with citric acid, there was more proliferation of human gingival fibroblast in tetracycline-treated group than citric acid. In conclusion, demineralized root surface as primary site for PDGF-BB application, especially demineralized with tetracycline has important roles in attachment and proliferation of human gingival fibroblast, and may be useful clinical applications in periodontal regenerative procedures.

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The effect of polyethypeneglycol on the electrocrystallization of Zn electrodeposition (아연 전기도금의 전착성에 미치는 폴리에틸렌글리콜(polyethyleneglycol)의 영향)

  • 김현태;김태엽;이재륭;장삼규
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.9 no.6
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    • pp.590-596
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    • 1999
  • The effects of additives on the Zn electrodeposition in chloride-based electrolyte were investigated using circulation cell with three electrodes system. The cathodic polarization increased with the addition of polyethylenglycol (hereafter PEG) in electrolyte. This was attributed to the adsorption of the additives on the electrode and the inhibition of migration of metal ion. The PEG, however, did not have any noticeable effect on the properties of plating solutions at the concentration used. The effect of PEG on the electrocrystallization was related to its molecular weight. With the increase of molecular weight, the cathodic polarization increased, while the surface roughness was improved with the decrease of brightness. Especially, the PEG mixed with different molecular weights was the most effective. The orientation and the type of the deposited grains were changed and refined by PEG, which resulted in the modification of deposited surface roughness and brightness.

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Facet Growth of InGaAs on GaAs(100) by Chemical Beam Epitaxy Using Unprecracked Monoethylarsine (GaAs(100) 기판에 사전 열분해하지 않은 Monoethylarsine을 사용하는 Chemical Beam Epitaxy방법에 의한 InGaAs박막의 Facet 성장에 관한 연구)

  • 김성복;박성주;노정래;이일항
    • Journal of the Korean Vacuum Society
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    • v.5 no.3
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    • pp.199-205
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    • 1996
  • InGaAs eqitaxial layers have been selectively grown on patterned GaAs(100) substrates by chemical beam epitaxy (CBE) using triethylgallium (TEGa), trimethylindium (TMIn), and unprecracked monoethylarsine (MEAs). Facet growth of InGaAs epilayers has also been investigated at the various growth temperatures and Si4N4 dielectric pattern directions. In [011] jirection of mask, the change from (311), (377) and (111) facets to (311) facet with increasing growth temperature was observed. In [011] direction, however, the change from (011) and (111) facets to (111) facet with increasing growth temperature was observed. These results are attributed to the sidewall growth caused by different surface migration lengths of reactants. The formation of U-shaped (100) top surface is also discussed in terms of dangling bond model.

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Influence of Thermal Treatment on Surface Morphology of Tin Dioxide Thin Films (열처리에 따른 SnO2 박막의 표면형상)

  • Park, Kyung-Hee;Ryu, Hyun-Wook;Seo, Yong-Jin;Lee, Woo-Sun;Hong, Kwang-Jun;Park, Jin-Seong
    • Korean Journal of Materials Research
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    • v.13 no.7
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    • pp.442-446
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    • 2003
  • Tin dioxide ($SnO _2$) thin films were deposited at $375^{\circ}C$ on alumina substrate by metal-organic chemical vapor deposition. A few hillocks like a cauliflower were observed and the number of hillock on thin film surface increased with annealing temperature in air atmosphere. The oxygen content and the binding energy during air annealing at$ 500^{\circ}C$ came to close the stoichiometric $SnO_2$. The cauliflower hillocks seem to be the result of the continuous migration of the tiny grains to release the stress of an expanded grain. Sensitivity of CO gas depended on annealing temperature and increased with increasing annealing temperature.

The Quantitative Analysis of SB Latex Contents in Coating Color and Coating Layer of Coated Paper Using FT/Raman Spectroscopy (FT/RAman을 이용한 도공액과 도공지의 도공층 내의 SB Latex 정량분석)

  • 이복진;정순기;윤동호;마금자
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.31 no.4
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    • pp.16-22
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    • 1999
  • The quantitative analysis of SB latex contents in coating color and coated paper was investigated with FT/Raman spectroscopy. From the measured FT/IR and FT/Ramon spectra, the peaks of coating color were compared with those of each compoents . Calibration curves were obtained by the area of latex peaks and PLS method of QuantIR program. The relation of predicted values in PLS method and actual values in coating mixtures and coating layer was examined. The components of coating layer in coated paper were investigated by EDS , X-mapping and SEM, The contents of latex in z-direction were calculated in the coating layer of unknown coated paper. The latex concentration measurements of Top layer and Pre layer in double coated paper show that each layer has different value. In single coated paper, it is clear that the latex concentration is highest at the surface and decreases with an increase of depth. From those results it is indicated that the latex migrates to the coated surface. The result of this study may be applied to the binder migration study and the quality control in paper mill.

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The Experimental Study of the Migration Phenomena of the Radioactive Elements : A Basic Study for the Radioactive Waste Disposal (방사성(放射性) 원소(元素)의 이동현상(移動現象)에 관(關)한 실험적(實驗的) 연구(硏究) : 방사성(放射性) 폐기물(廢棄物) 처리(處理)를 위한 기초연구(基礎硏究))

  • Kim, Oak Bae;Park, Hee Youl
    • Economic and Environmental Geology
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    • v.22 no.3
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    • pp.277-283
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    • 1989
  • For the study of attenuation phenomena of the radioactive elements in solution, the adsorption experiment of thorium, uranium, barium and strontium on kaolinite, gibbsite, quartz, granite and shale as a function of time, pH and the surface area was conducted under the competition condition each other. There are two steps of adsorption kinetics. The first step is faster and completes in hours or a day, and the second step is slower eqiulibrium reaction. The adsorption rate which is considered to be related to CEC differs with adsorbent and decreases in the order of shale, kaolinite, granite, gibbsite and quartz. On the other hand, the adsorption rate for the same adsorbent differs with elements in the order of thorium,uranium, barium and strontium in decreasing rate. It is also affected by pH of the solution and the surface area of adsorbent. In conclusion, we didn't find any different between noncompetition condition and competition condition, and this means that we only have to consider the pH of ground water, the characteristics of the geological materials and the kinds of radioactive element in the case of selection of the places for the radioactive waste disposal.

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Reduction Cleaning and Thermomigration Effects on Micro Polyester SUEDE (극세 폴리에스테르 스웨드의 환원세정과 열이행의 영향)

  • Choi, Kyung-Yeon;Han, Sam-Sook;Lee, Mun-Cheul
    • Textile Coloration and Finishing
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    • v.21 no.6
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    • pp.12-21
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    • 2009
  • The dyeing property of direct-spinning type and seaisland type 0.2D micro polyester nonwoven fabrics was characterized by three disperse dyes (Dorosperse Red KFFB, Blue KGBR, Yellow KRL) at $120^{\circ}C$ and $130^{\circ}C$. Before and after reduction cleaning, dyeing fastness was evaluated and the thermomigaration after heat setting at $180^{\circ}C$ for 60 min were also evaluated. Direct-spinning type fabric showed better dyeing property, wash fastness, and light fastness, but worse rub fastness than seaisland type fabric. The dyeing property and fastness of direct-spinning type fabric increased at higher dyeing temperature, whereas seaisland type fabric exhibited lower dyeing fastness and the increase of thermomigration at higher dyeing temperature. Non-fixed dye in fiber surface was removed by reduction cleaning process, then dyeing fastness was improved and thermomigration decreased. The higher dye uptake of direct-spinning type non-woven fabric caused the increase of dye molecule migration from fiber internal to fiber surface, so this fabric showed larger thermomigration than seaisland type non-woven fabric.

Analysis on particle deposition onto a heated, horizontal free-standing wafer with electrostatic effect (정전효과가 있는 가열 수평웨이퍼로의 입자침착에 관한 해석)

  • Yoo, Kyung-Hoon;Oh, Myung-Do;Myong, Hyon-Kook
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.21 no.10
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    • pp.1284-1293
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    • 1997
  • The electrostatic effect on particle deposition onto a heated, Horizontal free-standing wafer surface was investigated numerically. The deposition mechanisms considered were convection, Brownian and turbulent diffusion, sedimentation, thermophoresis and electrostatic force. The electric charge on particle needed to calculate the electrostatic migration velocity induced by the local electric field was assumed to be the Boltzmann equilibrium charge. The electrostatic forces acted upon the particle included the Coulombic, image, dielectrophoretic and dipole-dipole forces based on the assumption that the particle and wafer surface are conducting. The electric potential distribution needed to calculate the local electric field around the wafer was calculated from the Laplace equation. The averaged and local deposition velocities were obtained for a temperature difference of 0-10 K and an applied voltage of 0-1000 v.The numerical results were then compared with those of the present suggested approximate model and the available experimental data. The comparison showed relatively good agreement between them.

Non-Thermal Atmospheric-Pressure Plasma Possible Application in Wound Healing

  • Haertel, Beate;von Woedtke, Thomas;Weltmann, Klaus-Dieter;Lindequist, Ulrike
    • Biomolecules & Therapeutics
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    • v.22 no.6
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    • pp.477-490
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    • 2014
  • Non-thermal atmospheric-pressure plasma, also named cold plasma, is defined as a partly ionized gas. Therefore, it cannot be equated with plasma from blood; it is not biological in nature. Non-thermal atmospheric-pressure plasma is a new innovative approach in medicine not only for the treatment of wounds, but with a wide-range of other applications, as e.g. topical treatment of other skin diseases with microbial involvement or treatment of cancer diseases. This review emphasizes plasma effects on wound healing. Non-thermal atmospheric-pressure plasma can support wound healing by its antiseptic effects, by stimulation of proliferation and migration of wound relating skin cells, by activation or inhibition of integrin receptors on the cell surface or by its pro-angiogenic effect. We summarize the effects of plasma on eukaryotic cells, especially on keratinocytes in terms of viability, proliferation, DNA, adhesion molecules and angiogenesis together with the role of reactive oxygen species and other components of plasma. The outcome of first clinical trials regarding wound healing is pointed out.