• Proceedings of the Korean Vacuum Society Conference
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• 2013.02a
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• pp.263-263
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• 2013

This work examines the dynamic properties of ice surfaces in vacuum for the temperature range of 140~180 K, which extends over the onset temperatures for ice sublimation and the phase transition from amorphous to crystallization ice. In particular, the study focuses on the transport processes of excess protons and chloride ions in ice and their segregative behavior to the ice surface. These phenomena were studied by conducting experiments with a relatively thick (~100 BL) ice film constructed with a bottom $H_2O$ layer and an upper $D_2O$ layer, with excess hydronium and chloride ions trapped at the $H_2O$/$D_2O$ interface as they were generated by the ionization of hydrogen chloride. The migration of protons, chloride ions, and water molecules to the ice film surface and their H/D exchange reactions were measured as a function of temperature using the methods of low energy sputtering (LES) and Cs+ reactive ion scattering (RIS). Temperature programmed desorption (TPD) experiments monitored the desorption of water and hydrogen chloride from the surface. Our observations indicated that both hydronium and chloride ions migrated from the interfacial layer to segregate to the surface at high temperature. Hydrogen chloride gas desorbs via recombination reaction of hydronium and chloride ions floating on the surface. Surface segregation of these species is driven by thermodynamic potential gradient present near the ice surface, whereas in the bulk, their transport is facilitated by thermal diffusion process. The finding suggests that chlorine activation reactions of hydrogen chloride for polar stratospheric ice particles occur at the surface of ice within a depth of at most a few molecular layers, rather than in the bulk phase.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2002.07a
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• pp.232-235
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• 2002

An 150 kV gas cluster ion accelerator was fabricated and assessed. The change of surface morphology and surface roughness were examined by an atom force microscope (AFM) after irradiation of $CO_2$ gas clusters on Si (100) surfaces at the acceleration voltages of 50 kV. The density of hillocks induced by cluster ion impact was gradually increased with the dosage up to 5$\times$10$^{11}$ ions/$\textrm{cm}^2$. At the boundary of the ion dosage of 10$^{12}$ ions/$\textrm{cm}^2$, the density of the induced hillocks was decreased and RMS (root mean square) surface roughness was not deteriorated further. At the dosage of 5x10$^{13}$ ions/$\textrm{cm}^2$, the induced hillocks completely disappeared and the surface became very flat. In addition, the irradiated region was sputtered. $CO_2$ cluster ions are irradiated at the acceleration voltage of 25 kV to remove hillocks on indium tin oxide (ITO) surface and thus to attain highly smooth surfaces. $CO_2$ monomer ions are also bombarded on the ITO surface at the same acceleration voltage to compare sputtering phenomena. From the AFM results, the irradiation of monomer ions make the hillocks sharper and the surfaces rougher On the other hand, the irradiation of $CO_2$ cluster ions reduces the hight of hillocks and planarize the ITO surfaces. From the experiment of isolated cluster ion impact on the Si surfaces, the induced hillocks m high had the surfaces embossed at the lower ion dosages. The surface roughness was slightly increased with the hillock density and the ion dosage. At higher than a critical ion dosage, the induced hillocks were sputtered and the sputtered particles migrated in order to fill valleys among the hillocks. After prolonged irradiation of cluster ions, the irradiated region was very flat and etched.

• Journal of Korean Society of Rural Planning
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• v.29 no.4
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• pp.117-125
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• 2023

This study aimed to analyze the recent status and changes in impervious surface areas and their ratios across regions in Gyeongsangnam-do, providing fundamental data for regional development and impervious surface management. Based on the 'Guidelines for Calculating Water Cycle Management Indicators for Nonpoint Pollution Source Control(Ministry of Environment)', we processed the land characteristics survey map(shapefile) from 2018 and 2022 to analyze impervious surface area and their rates by administrative boundaries. The impervious surface area in Gyeongsangnam-do increased from 75,652 ha in 2018 to 81,055 ha in 2022, with the rate rising by 0.51% from 7.18% to 7.69%. The average of impervious surface area across 545 eupmyeon units expanded by approximately 9 ha, from 139.8 ha in 2018 to 148.8 ha in 2022, with the rate increasing by 0.71%. Concurrently, the whole population declined by 2.8% while the number of households surged by 6.4%, correlating with the growth in impervious areas. Despite population decreases, factors such as population migration, increased household fragmentation, new residential developments, and industrial facility expansions have consistently contributed to the rise in impervious surface area. Notably, even in areas with high impervious surface area rate, significant disparities existed between urbanized areas and predominantly rural regions. Furthermore, about 333 units(61% of the whole eupmyeons), showed negligible changes in their impervious surface area rate, with an increase of less than 0.5%.

• Korean Journal of Fisheries and Aquatic Sciences
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• v.30 no.1
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• pp.39-45
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• 1997

Subtidal zonation of a cumacean Bodotria biplicata was investigated in the sandy shore surf zone of Dolsando, southern Korea. Three replicate samples were taken with a sledge net at three sites, such as the surface and bottom of 1 m depth and waters edge, at hourly intervals over the neap and spring tide cycles on January 1993 (n=225). B. biplicata, the most dominant cumacean in this area, exhibited peak density at the bottom while about $0.6\%$ of total catch was collected at the surface. Mean density during the neap tide cycle was slightly higher than that during the spring tide cycle. The depth of subtidal zone influenced the total catch of B. biplicata. The changes in density were related to the depth of subtidal zone rather than day-night cycle or ebb-flood tide. The results obtained in this study suggest that the diel vertical migration is not distinct. During both neap and spring tide cycles, B. biplicata attained a density maximum at the same level of about 90 cm below lower low water (LLW). It is likely, therefore, that this species performs shore- and seaward horizontal migration fortnightly. The speed and distance of migration may be directly related to the beach slope and tide range. Ontogenetic differences in subtidal distribution were observed. Juveniles and manca larvae tended to occur lower areas than the adults. Such differences may reduce intraspecific competition for diets.

• Journal of the Mineralogical Society of Korea
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• v.19 no.4 s.50
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• pp.239-246
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• 2006

KAERI Underground Research Tunnel (KURT) was recently constructed through the site investigation from the yea. of 2003 at KAERI site, Dukjin-dong, Yuseong-gu, Daejeon city. The geo-logic setting of the site has been slightly metamorphosed. There are small fractures developed in the rock and several kinds of secondary filling minerals exist in the fractures. We examined mineralogical characteristics of fracture-filling calcite, which is not only largely distributed, but also can significantly affect the radionuclides migration. The calcite is found along fractures like other secondary minerals, forming thick veins in part. Most calcite-filled fractures contain quartz, iron oxides, and dolomite as minor minerals. The calcite crystals show an characteristic appearance with an uniformly oriented growth, coated with goethite on the edge and the etch-pit sites of their surface. Some calcite crystals have been newly formed by the precipitation of elements dissolved from the tunnel shotcrete wall, and their morphology changed according to the chemistry and flow of groundwater. The calcite can modify the groundwater chemistry and significantly affect the sorption behavior of radionuclides. The characteristic crystal structure and surface morphology of the calcite examined in the KURT site will be used as important basic data for the radionuclide migration experiment in the future.

• Journal of Adhesion and Interface
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• v.12 no.4
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• pp.144-150
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• 2011

The effect of low profile agent and release agent on the surface and mechanical properties of bulk mold compound were investigated. Atomic content and contact angle of surface were characterized using X-ray photoelectron spectroscopy and contact anglemeter. Surface morphology and surface roughness were obtained using field emission scanning electron microscope and atomic force microscope, respectively. As increasing the low profile agent from 0 to 9.2 wt%, the volume shrinkage and surface roughness decreased from 0.35% to 0.05%, and from $0.27{\mu}m$ to $0.12{\mu}m$, respectively. The increase of release agent from 1.8 wt% to 3.6 wt% resulted in the migration of release agent to sample surface and it increased the surface roughness. The flexural strength and impact strength were decreased approximately 30% as the low profile agent increasing from 5.0 wt% to 9.0 wt%.

• Journal of the Korean GEO-environmental Society
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• v.15 no.6
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• pp.17-29
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• 2014

A remedial investigation was conducted at five military training ranges in northern Gyeonggi province to collect information necessary for the design of on-site treatment facilities for the abatement of explosive compounds release to the environment. These information includes (i) identification of dominant explosive compounds in each range, (ii) discharge/migration routes, and (iii) contaminant distribution in particle size fraction and settling velocity of the soils. The results of investigation showed that TNT and RDX are the major contaminants but the extent of contamination varied depending on the types of military training practices and topography of the site. RDX was also detected in the subsurface soil and in the nearby stream within the training ranges, suggesting release of contaminants to streams. The median concentrations of explosives in the surface soil were less than 20 mg/kg despite several 'hot spots' in which explosives concentrations often exceeds several hundred mg/kg. The average clay contents in the soil of target area was less than 5 % compared to 12 % in the control, indicating loss of smaller particles by surface runoff during rainfall due to lack of vegetative land cover. Analysis of explosive compounds and particle size distribution showed that the amount of explosive compounds in soil particles smaller than 0.075 mm was less than 10 % of the total. Settling column tests also revealed that the quantity of explosive compounds in the liquid phase of the effluent was greater than that in the solid phase. Therefore, pre-treatment of particulate matter in surface runoff of shooting range with a simple settling basin and subsequent effluent treatment with planted constructed wetlands as polishing stage for explosives in the aqueous phase would provide the shooting ranges with a self-standing, sustainable, green solution.

• Geophysics and Geophysical Exploration
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• v.14 no.3
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• pp.234-241
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• 2011

Recently, exploration and development of oil sands are thriving due to high oil price. Because oil sands reservoir usually exists as a thin layer, multicomponent VSP, which has the advantage of the high-resolution around the borehole, is more effective than surface seismic survey in exploring oil sand reservoir. In addition, prestack phase-screen migration is effective for multicomponent seismic data because it is based on an one-way wave equation. In this study, we examined the applicability of the prestack phase-screen migration for multicomponent RVSP data to image the thin oil sand reservoir. As a preprocessing tool, we presented a method for separating P-wave and PS-wave from multicomponent RVSP data by using incidence angle and rotation matrix. To verify it, we have applied the developed wavefield separation method to synthetic data obtained from the velocity model including a horizontal layer and dipping layers. Also, we compared the migrated image by using P-wave with that by using PS-wave. As a result, the PS-wave migrated image has higher resolution and wide coverage than P-wave migrated image. Finally, we have applied the prestack phase-screen migration to the synthetic data from the velocity model simulating oil sand reservoir in Canada. The results show that the PS-wave migrated image describe the top and bottom boundaries of the thin oil sand reservoir more clearly than the P-wave migrated image.

• Korean Journal of Environmental Agriculture
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• v.16 no.4
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• pp.304-310
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• 1997

In greenhouse, a mixed solution of Mn-54, Co-60, Sr-85 and Cs-137 was applied to the soil of culture boxes 2 days before sowing cucumber and at 4 different times during its growth for measuring their transfer factors (TFs) for fruit and migration in soil. TFs varied with radionuclide, application time and harvest time by factor of up to about 60. Variations in TFs with application time showed different patterns among radionuclides. TFs decreased on the whole in the order of Sr-85 > Mn-54 > Co-60 > Cs-137. TFs of Mn-54, Co-60 and Cs-137 mixed with topsoil before sowing were a little higher than those for the soil-surface application made at an early growth stage while no difference in Sr-85 TF was found. After harvest, soil concentrations of the radionuclides applied at an early growth stage were examined. They decreased with increasing soil depth and 80${\sim}$99% of the radioactivity remained in the top 3cm. Soil pemeation of the radionuclides migration decreased in the order of Sr-85 > Mn-54 > Co-60 > Cs-137. The present data can be utilized in estimating radionuclide concentration in cucumber fruit, taking proper measures for its harvest and consumption and designing the best way of soil decontamination following an radioactive deposition during the cucummber growing season.

• Nuclear Engineering and Technology
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• v.26 no.3
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• pp.401-410
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• 1994

Validation study of two radionuclide migration models for single fracture developed in geologic medium the hydrodynamic dispersion diffusion model(HDDM) and the channeling dispersion diffusion model(CDDM), was studied by migration experiment of tracers through an artificial granite fracture on the labolatory scale. The tracers used were Uranine and Sodium lignosulfonate know as nonsorbing material. The flow rate ranged 0.4 to 1.5 cc/min. Related parameters for the models were estimated by optimization technique. Theoretical breakthrough curves with experimental data were compared. In the experiment, it was deduced that the surface sorption for both tracers did not play an important role while the diffusion of Uranine into the rock matrix turned out to be an important mass transfer mechanism. The parameter characterizing the rock matrix diffusion of each model agreed well The simulated result showed that the amount of flow rate could not tell the CDDM from the HDDM quantitatively. On the other hand, the variation of fracture length gave influence on the two models in a different degree. The dispersivity of breakthrough curve of the CDDM was more amplified than that of the CDDM when the fracture length was increased. A good agreement between the models and experimental data gave a confirmation that both models were very useful in predicting the migration system through a single fracture.