• Macromolecular Research
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• 제9권1호
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• pp.51-65
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• 2001

Two-stage emulsion polymerizations of hydrophobic monomers on hydrophilic seed polymer particles were carried out to make core-shell composite particles. It was found that the loci of polymerization in the second stage were the surface layer of the hydrophilic seed latex particles, and that it has resulted in the formation of either eccentric core-shell particles with the core exposed to the aqueous phase or aggregated nonspherical composite particles with the shell attached on the seed surface as many small separated particles. The driving force of these phenomena is related to the gain in free energy of the system in going from the hydrophobic polymer-water interface to hydrophilic polymer-water interface. Thermodynamic analysis of the present polymerization system, which was based on spreading coefficients, supported the likely occurrence of such nonspherical particles due to the combined effects of interfacial free energies and phase separation between the two polymer phases. A hypothetical pathway was proposed to prepare hydrophilic core-hydrophobic shell composite latex particles, which is based on the concept of opposing driving and resistance forces for the phase migration. It was found that the viscosity of the monomer-swollen polymer phase played important role in the formation of particle morphology.

• 한국염색가공학회지
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• 제13권6호
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• pp.428-434
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• 2001

This study surveys the fiber behavior in yam formation and the Physical properties of Solo-spun yarn. The specimens were made by six types of Solo-spun rollers with fixed twist multiplier In the previous part, the physical properties such as yarn count, evenness, strength, and breaking elongation of these yams were compared with the properties of ring shun yarns and analysed with the mechanism of Solo-spun yarn formation. In the second part of this report, the abrasion resistance and hairiness were discussed wish respect to the micro yarn structures. The narrower the groove width of Solo-spun roller is, the more active the bulk fibers migration is. The Solo-spun film structure has two groups. One is shorter than the others one in longitudinal direction of yarn and has the same structure as ring-spun yarn, which is derided from the smooth zone on the surface of Solo-spun roller. The other one is longer than the former and there are the wrapping fibers. This part is derived from the conflicted grooves on the surface of Solo-spun troller.

• 한국염색가공학회지
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• 제13권6호
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• pp.70-70
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• 2001

This study surveys the fiber behavior in yarn formation and the Physical properties of Solo-spun yarn. The specimens were made by six types of Solo-spun rollers with fixed twist multiplier In the previous part, the physical properties such as yarn count, evenness, strength, and breaking elongation of these yarns were compared with the properties of ring spun yarns and analysed with the mechanism of Solo-spun yarn formation. In the second part of this report, the abrasion resistance and hairiness were discussed with respect to the micro yarn structures. The narrower the groove width of Solo-spun roller is, the more active the bulk fiber migration is. The Solo-spun yarn structure has two groups. One is shorter than the other one in longitudinal direction of yarn and has the same structure as ring-spun yarn, which is derived from the smooth zone on the surface of Solo-spun roller. The other one is longer than the former and there are the wrapping fibers. This part is derived from the conflicted grooves on the surface of Solo-spun roller.

• 지구물리와물리탐사
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• 제2권1호
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• pp.54-62
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• 1999

본 논문은 파동장의 심도방향으로의 외삽(extrapolation)을 사용한 중합전 데이터밍 기법을 소개한다. 데이터밍 알고리즘의 유도를 위해, 우선 평면에 정의되어 있는 파동장을 임의의 굴곡을 갖는 면으로 외삽을 수행하는 모델링 연산자를 대수학적으로 구한 후, 이러한 모델링 연산자와 어드조인트(adjoint)관계에 있는 연산자를 대수학적으로 구하여 데이터밍 연산자를 얻게된다. 본 논문에서 사용된 취합전 모델링 연산자는 이미 널리 쓰이고 있는 중합전 마이그레이션(prestack migration) 중의 하나인 survey sinking 방법의 모델링에 해당하는 double square root(DSR)식이 사용되었다.

• 접착 및 계면
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• 제7권4호
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• pp.53-59
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• 2006

The paper highlights technical advances and introduces recent innovations such as smart curing laminating adhesives for flexible packaging with low migration rates of aromatic isocyanates and amines. Latent reactive one-part systems on the basis of surface deactivated solid isocyanates open up new dimensions for heat setting adhesives and waterborne PU dispersions. The new generation of Purmelt Micro Emission adhesives contains less than 0.1% of MDI monomer, thereby drastically reducing the emission of hazardous isocyanate vapors during processing and setting a significantly improved technical standard in occupational safety. Once again, polyurethane adhesives have demonstrated their unique ability to adapt to new process, product, safety and environmental requirements.

• 한국GIS학회:학술대회논문집
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• 한국GIS학회 2010년도 춘계학술대회
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• pp.277-278
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• 2010

본 연구는 황해 아산만 중앙천퇴(Surface Sediment)에서 최근 대규모 방조제 건설과 연안 준설로 인해 야기된 해저지형변화에 대한 연구이다. 이러한 해저지형변화는 해도상의 수심정보를 왜곡시킴으로써 국제항을 출입하는 대형선박의 안전항해에 위험요소로 작용할 수 있어, 안전한 항해수로 확보 및 해양사고 저감 대책 마련이 시급하다. 이러한 맥락에서 근본적인 중앙천퇴 지형변화의 원인, 해저지형변화의 양상을 파악하는 것이 이 연구의 일차적인 목적이다. 더 나아가 장 단기 해저지형변화 예측을 통해, 궁극적으로 항해 위험요소 저감 대책 및 정책 마련 시 과학적인 핵심기반기술을 제공하는 것이다. 결국 GIS 기반의 해저지형 공간 분석을 토대로 기존의 미시적인 데이터에 의거한 퇴적환경 연구결과를 객관화하고 정량적인 근거를 제시하는 도구로 활용할 것이다.

• Fibers and Polymers
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• 제6권4호
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• pp.277-283
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• 2005

In order to prepare high molecular weight poly(methyl methacrylate) (PMMA)/silver nanocomposite microspheres, methyl methacrylate was suspension-polymerized in the presence of silver nanoparticles at low temperature with 2,2'-azobis(2,4-dimethylvaleronitrile) as an initiator. The rate of conversion was increased by increasing the initiator concentration. When silver nanoparticles were added, the rate of polymerization decreased slightly. High monomer conversion (about $85\%$) was obtained in spite of low polymerization temperature of $30^{\circ}C$. Under controlled conditions, PMMA/silver microspheres with various number-average degrees of polymerization (6,000-37,000) were prepared. Morphology studies revealed that except for normal suspension microspheres with a smooth surface, a golf ball-like appearance of the microspheres was observed, due to the migration and aggregation of the hydrophilic silver nanoparticles at the sublayer beneath the microsphere's surface.

• 한국표면공학회지
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• 제24권3호
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• pp.137-143
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• 1991

The relation between the ion irradiation induced grain growth and the basic parameters sinvolved in ion beam mixing process was studied. TEM micrographs showed that a significant grain growth has been induced by Ar+ irradiation at room temperature. The grain size increases rapidly in low dose region, while it approaches a saturated value in high dose region, and it has close relationship with nuclear energy deposition and thermodynamic properties such as cohesive energy ( Hc) and heat of mixing ( Hm). A model for the grain growth based on the thermal spike induced atomic migration was developed and applied to interpret experimental results.

• 한국표면공학회:학술대회논문집
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• 한국표면공학회 2013년도 춘계학술대회 논문집
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• pp.38-38
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• 2013

The mechanical cues that adherent cells derive from the extracellular matrix (ECM) can effect dramatic changes in cell migration, proliferation, and differentiation. Using a thin film of Type I collagen fibrils comprised of 100 nm to 200 nm collagen fibrils overlaying a bed of smaller fibrils, changes in cellular response to systematically controlled changes in mechanical properties of collagen was investigated. Further, an experimental and modeling approaches to calculate the elastic modulus of individual collagen fibrils, and thereby the effective stiffness of the entire collagen thin film matrix, from atomic force microscopy force spectroscopy data was performed. These results demonstrate an approach to analysis of fundamental properties of thin, heterogeneous, organic films, and add further insights into the mechanical properties of collagen fibrils that are of relevance to cell response to the ECM.

• Journal of Electrochemical Science and Technology
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• 제13권3호
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• pp.347-353
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• 2022

Agarose hydrogel, a solid electrolyte, was investigated voltammetrically in terms of transport properties and natural convection effects using a ferrocenyl compound as a redox probe. To confirm the diffusion properties of solute on the agarose interface, the diffusion coefficients (D) of ferrocenemethanol in agarose hydrogel were determined by cyclic voltammetry (CV) according to the concentration of agarose hydrogel. While the value of D on the agarose interface is smaller than that in the bulk solution, the square root of the scan rate-dependent peak current reveals that the mass transport behavior of the solute on the agarose surface shows negligible convection or migration effects. In order to confirm the reduced natural convection on the gel interface, scan rate-dependent CV was performed in the solution phase and on the agarose surface, respectively. Slow scan voltammetry at the gel interface can determine a conventional and reproducible diffusion-controlled current down to a scan rate of 0.3 mV/s without any complicated equipment.