• Title/Summary/Keyword: Surface impedance

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Corrosion Behaviors of Dental Implant Alloy after Micro-sized Surface Modification in Electrolytes Containing Mn Ion

  • Kang, Jung-In;Son, Mee-Kyoung;Choe, Han-Cheol
    • Journal of Korean Dental Science
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    • v.11 no.2
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    • pp.71-81
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    • 2018
  • Purpose: The purpose of this study was to investigate the corrosion behaviors of dental implant alloy after microsized surface modification in electrolytes containing Mn ion. Materials and Methods: $Mn-TiO_2$ coatings were prepared on the Ti-6Al-4V alloy for dental implants using a plasma electrolytic oxidation (PEO) method carried out in electrolytes containing different concentrations of Mn, namely, 0%, 5%, and 20%. Potentiodynamic method was employed to examine the corrosion behaviors, and the alternatingcurrent (AC) impedance behaviors were examined in 0.9% NaCl solution at $36.5^{\circ}C{\pm}1.0^{\circ}C$ using a potentiostat and an electrochemical impedance spectroscope. The potentiodynamic test was performed with a scanning rate of $1.667mV\;s^{-1}$ from -1,500 to 2,000 mV. A frequency range of $10^{-1}$ to $10^5Hz$ was used for the electrochemical impedance spectroscopy (EIS) measurements. The amplitude of the AC signal was 10 mV, and 5 points per decade were used. The morphology and structure of the samples were examined using field-emission scanning electron microscopy and thin-film X-ray diffraction. The elemental analysis was performed using energy-dispersive X-ray spectroscopy. Result: The PEO-treated surface exhibited an irregular pore shape, and the pore size and number of the pores increased with an increase in the Mn concentration. For the PEO-treated surface, a higher corrosion current density ($I_{corr}$) and a lower corrosion potential ($E_{corr}$) was obtained as compared to that of the bulk surface. However, the current density in the passive regions ($I_{pass}$) was found to be more stable for the PEO-treated surface than that of the bulk surface. As the Mn concentration increased, the capacitance values of the outer porous layer and the barrier layer decreased, and the polarization resistance of the barrier layers increased. In the case of the Mn/Ca-P coatings, the corroded surface was found to be covered with corrosion products. Conclusion: It is confirmed that corrosion resistance and polarization resistance of PEO-treated alloy increased as Mn content increased, and PEO-treated surface showed lower current density in the passive region.

Performance of Air Electrodes with a Surface-Polished Yttria-Stabilized Zircona Electrolyte for Thin-Film Solid Oxide Fuel Cells (박막 고체산화물 연료전지용 이트리아 안정화 지르코니아 전해질 연마표면상의 공기극 성능)

  • Lee, Yu-Gi
    • Korean Journal of Materials Research
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    • v.11 no.4
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    • pp.283-289
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    • 2001
  • Composite cathodes of 50/50 vol% LSM- YSZ (La$_{1-x}$Sr$_{x}$MnO$_3$-yttria stabilized zirconia) were deposited onto surface- Polished YSZ electrolytes by colloidal deposition technique. The cathode characteristics were then examined by scanning electron microscopy (SEM) and X-ray diffraction (XRD) and studied by ac impedance spectroscopy (IS). The typical impedance spectra measured for an air/LSM- YSZ/YSZ/Pt/air cell at $700^{\circ}C$ were composed of two depressed arcs. Addition of YSZ to the LSM electrode significantly enlarged the triple-phase boundaries (TPB) length inside the electrode, which led to a pronounced decrease in cathodic resistivity of LSM-YSZ composite electrodes. Polishing the electrolyte surface to eliminate the influences of surface impurities and to enlarge the TPB length can further reduce cathode resistivity. The cathodic resistivity of the LSM- YSZ electrodes was a strong function of operation temperature, composition and particle size of cathode materials, applied current, and electrolyte surface roughness.

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Investigation of Electrical Resistance Properties in Surface-Coated Lightweight Aggregate (표면코팅 경량골재의 전기저항 특성)

  • Kim, Ho-Jin;Kim, Chang-Hyun;Choi, Jung-Wook;Park, Sun-Gyu
    • Journal of the Korea Institute of Building Construction
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    • v.23 no.6
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    • pp.727-738
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    • 2023
  • In concrete, the interface between the aggregate and cement paste is often the most critical factor in determining strength, representing the weakest zone. Lightweight aggregate, produced through expansion and firing of raw materials, features numerous surface pores and benefits from low density; however, its overall aggregate strength is compromised. Within concrete, diminished aggregate strength can lead to aggregate fracture. When applying lightweight aggregate to concrete, the interface strength becomes critical due to the potential for aggregate fracture. This study involved coating the surface of the aggregate with blast furnace slag fine powder to enhance the interfacial strength of lightweight aggregate. The impedance of test specimens was measured to analyze interface changes resulting from this surface modification. Experimental results revealed a 4% increase in compressive strength following the coating of the lightweight aggregate surface, accompanied by an increase in resistance values within the impedance measurements corresponding with strength enhancement.

The Limit and Application of Two-microphone Impedance Tube Method to the Sound Transmission Loss Measurement of Sound Isolation Materials (차음재의 음향투과손실 측정에 Two-Microphone Impedance Tube Method의 적용과 한계)

  • Lee, Seung;Ahn, Min-Hong;Lee, Dong-Hoon
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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    • 2002.05a
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    • pp.883-888
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    • 2002
  • This study describes the limit and application of the two-microphone impedance tube method to the sound transmission loss measurement of several sound isolation materials with different physical properties. For the sound isolation materials having small flexural rigidity, it is shown that the two-microphone impedance tube method is validated to practically measure the sound transmission loss. For the sound isolation materials having large flexural rigidity, on the other hand, it is found that the two-microphone impedance tube method is no longer valid to measure the sound transmission loss because the regions of resonance and mass law are moved into the higher frequencies. In addition, in order to accurately measure the sound transmission loss of sound isolation materials, their size should be decided based on the consideration of the effect of acoustic excitation on their vibration response.

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Impedance-based health monitoring and mechanical testing of structures

  • Palomino, Lizeth Vargas;de Moura, Jose Dos Reis Vieira Jr.;Tsuruta, Karina Mayumi;Rade, Domingos Alves;Steffen, Valder Jr.
    • Smart Structures and Systems
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    • v.7 no.1
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    • pp.15-25
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    • 2011
  • The mechanical properties obtained from mechanical tests, such as tensile, buckling, impact and fatigue tests, are largely applied to several materials and are used today for preliminary studies for the investigation of a desired element in a structure and prediction of its behavior in use. This contribution focus on two widely used different tests: tensile and fatigue tests. Small PZT (Lead Titanate Zirconate) patches are bonded on the surface of test samples for impedance-based health monitoring purposes. Together with these two tests, the electromechanical impedance technique was performed by using aluminum test samples similar to those used in the aeronautical industry. The results obtained both from tensile and fatigue tests were compared with the impedance signatures. Finally, statistical meta-models were built to investigate the possibility of determining the state of the structure from the impedance signatures.

Analytical Studies for Estimating Soil Properties from the SPT Dynamic Signals (SPT 동적신호를 이용한 지반정보 추정에 관한 해석적 연구)

  • 이병식;김영수;김범상
    • Proceedings of the Korean Geotechical Society Conference
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    • 2002.03a
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    • pp.423-430
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    • 2002
  • A feasibility of a trial test method was evaluated analytically, in which the elastic modulus of a soil deposit was tried to estimate by analyzing dynamic signals measured during conducting the SPT. If there existed a reliable relationship between the impedance ratio of a rod to a soil and the amplitude ratio of a reflected to an incident wave signal at the tip of steel rod contacting the soil surface, it was expected that one could determine the impedance of soil, and then roughly estimate the elastic modulus from the impedance. For a simple rod-soil system, the existence of the relevant relationship was verified in this study by analyzing computed wave signals propagating up and down through the rod. On the basis of these results, thus, a potential of the test method to practical applications could be seen. However, apparent theoretical shortcomings possessed in this approach were also realized since the soil part had an unconfined contact area where contacted with the rod. Therefore, it was concluded that further studies needed to be conducted, in which the reliable theoretical relationship between the impedance and the amplitude ratio as well as the effective contacting soil area contributing to wave reflection should be justified.

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Thermal Model for Power Converters Based on Thermal Impedance

  • Xu, Yang;Chen, Hao;Lv, Sen;Huang, Feifei;Hu, Zhentao
    • Journal of Power Electronics
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    • v.13 no.6
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    • pp.1080-1089
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    • 2013
  • In this paper, the superposition principle of a heat sink temperature rise is verified based on the mathematical model of a plate-fin heat sink with two mounted heat sources. According to this, the distributed coupling thermal impedance matrix for a heat sink with multiple devices is present, and the equations for calculating the device transient junction temperatures are given. Then methods to extract the heat sink thermal impedance matrix and to measure the Epoxy Molding Compound (EMC) surface temperature of the power Metal Oxide Semiconductor Field Effect Transistor (MOSFET) instead of the junction temperature or device case temperature are proposed. The new thermal impedance model for the power converters in Switched Reluctance Motor (SRM) drivers is implemented in MATLAB/Simulink. The obtained simulation results are validated with experimental results. Compared with the Finite Element Method (FEM) thermal model and the traditional thermal impedance model, the proposed thermal model can provide a high simulation speed with a high accuracy. Finally, the temperature rise distributions of a power converter with two control strategies, the maximum junction temperature rise, the transient temperature rise characteristics, and the thermal coupling effect are discussed.