• 한국콘크리트학회:학술대회논문집
• /
• 한국콘크리트학회 2006년도 추계 학술발표회 논문집
• /
• pp.537-540
• /
• 2006

Over the past few decades, a considerable number of studies on the durability of concrete have been carried out extensively. A lot of improvements have been achieved especially in modeling of ionic flows. However, the majority of these researches have not dealt with the chloride binding isotherm based on the mechanism, although chloride binding capacity can significantly impact on the total service life of concrete under marine environment. The purpose of this study is to develop the model of chloride binding isotherm based on the individual mechanism. It is well known that chlorides ions in concrete can be present; free chlorides dissolved in the pore solution, chemical bound chlorides reacted with the hydration compounds of cement, and physical bound attracted to the surface of C-S-H grains. First, sub-model for water soluble chloride content is suggested as a function of pore solution and degree of saturation. Second, chemical model is suggested separately to estimate the response of binding capacity due to C-S-H and Friedel's salt. Finally, physical bound chloride content is estimated to consider a surface area of C-S-H nano-grains and the distance limited by the Van der Waals force. The new model of chloride binding isotherm suggested in this study is based on their intrinsic binding mechanisms and hydration reaction of concrete. Accordingly, it is possible to characterize chloride binding isotherm at the arbitrary stage of hydration time and arbitrary location from the surface of concrete. Comparative study with experimental data of published literature is accomplished to validity this model.

• 한국펄프종이공학회:학술대회논문집
• /
• 한국펄프종이공학회 2011년도 추계학술발표회 논문집
• /
• pp.39-41
• /
• 2011

The recycling rate of recovered paper in Korea is the highest in the world, 92%, but remanufacturing yield is low due to the extremely poor quality of the paper. The poor quality, in turn, influences to the reject amount in deinking process. To increase the yield of old newspaper recycling process, hydrophobic degree of inorganic pigments of deinking stock must be reduced. To determine the hydrophobicity, Pitch Potential Deposit Tester (PDT) was newly designed and applied with respect to the SB latex property of various quality used in Korea; its hydrophobic degree according to Tg, gel content, charge and particle size of latex and optimum designing condition of SB latex. And below are the conclusions: 1. The reason of excessive reject from old newspaper deinking process for total amount of printed ink is loss of inorganic pigments. When lipase, a biochemical catalyst, was applied with the purpose of preventing inorganic pigments loss about more than 70% of total reject weight and promoting hydration of pulp for deinking, deinking process yield of pre flotation secondary stage increased remarkably without any changes of deinking efficiency. 2. Lipase improved deinking stock by cutting ester linkage on surface of hydrophobic materials to promote its hydration. From this, it reached the conclusion that hydration degree of stock exercises significant effect on flotation deinking process yield. 3. Inorganic alkali promotes hydration of deinking stock. But there have been needs for more fundamental measures other than inorganic alkali of promoting hydration for yield improvement. For this, this study intended to find out reasons of chemical properties change on surface of hydrophobic material by change of pH. 4. Pitch Deposit Test (PDT) was performed for understanding principle of why surface of coating flake from OMG is hydrophobic and why it becomes hydrophilic when pH of stock is alkaline. As a result of this test, it is determined that swelling property by change of pH of latex film, which were used as coating adhesive is the reason for hydrophobic change. 5. Hydrophilicity of coating flake increased with hydrophilic pigments. And as more of SB Latex adhesive was used and higher of calcium hardness of stock became, its hydrophilicity decreased. SB Latex adhesive film is reformed by mechanical friction. For having hydrophilicity under neutral pH, strong bruising action such as kneading is required. 6. Because swelling of adhesive film decreases as Tg of SB latex gets lower and mean diameter gets smaller, it shows hydrophobicity under neutral pH. This lowers hydrophilicity of coating flake, which leads to easy elimination with flotation reject on DIP process. Therefore, for improving future flotation yield, it is necessary to develop to use eco-friendly clean SB latex by raising Tg and increasing mean diameter for recycling, and as a result, to reduce excessive loss of coating flake as a reject from deinking process.

• 한국건축시공학회:학술대회논문집
• /
• 한국건축시공학회 2004년도 학술.기술논문발표회
• /
• pp.11-14
• /
• 2004

In this paper, field application of mass concrete using setting time difference of super retarding agent is reported to reduce hydration heat of concrete placed at newly constructed apartment house in Busan. Horizontal placing lift is applied. According to test results. slump and air content meets the requirement of target values. For compressive strength, it exceeds the nominal strength ordered by the costumer. Compressive strength of concrete cured in place is achieved more than the values of nominal strength at l4days. For temperature history, maximum temperature of center at top section shows 58.5$^{\circ}C$, and at bottom section, 62.6$^{\circ}C$. According to naked eye's investigation, no hydration heat crack is observed at the surface of concrete.

• 한국건축시공학회:학술대회논문집
• /
• 한국건축시공학회 2005년도 춘계 학술기술논문발표대회 논문집
• /
• pp.21-24
• /
• 2005

In this paper, field application of mass concrete using setting time difference of super retarding agent is reported to reduce hydration heat of concrete placed at newly constructed apartment house in Daejeon. Horizontal placing lift is applied. According to test results,: slump and air content meets the requirement of target values. For compressive strength, it exceeds the nominal strength ordered by the costumer. For temperature history, maximum temperature of center at top section shows $25.6^{\circ}C$, and at bottom section, $35.4^{\circ}C$. According to naked eye's investigation, no hydration heat crack is observed at the surface of concrete.

• 한국콘크리트학회:학술대회논문집
• /
• 한국콘크리트학회 2000년도 가을 학술발표회 논문집(II)
• /
• pp.1151-1156
• /
• 2000

Temperature rise and restraint condition in mass concrete structures may induce the cracks at early ages. The method to prevent the cracks induced by heat of hydration has become the major concern in mass concrete structure. Therefore, the purpose of this study is to propose a method to control heat of hydration in mass concrete structures by using cryogenic liquefied nitrogen. The method in this study was applied to actual mass concrete structure to prevent the occurrence of thermal cracks at early ages. The surface observation of structure during more than one month shows that there are seldom cracks. This represent that the method in the study is effective in the control of heat of hydration.

• 한국건축시공학회:학술대회논문집
• /
• 한국건축시공학회 2022년도 봄 학술논문 발표대회
• /
• pp.158-159
• /
• 2022

This study analyzed the temperature stress through mixtures mass concrete hydration heat analysis according to the replacement rates of FAC and CGS. As a result of the analysis, it was possible to confirm the effect of reducing hydration heat when CGS is substituted for the low heat mixture of mass concrete. However, the stress of the FAC+CGS combination exceeded the tensile stress. It is believed that it is necessary to apply the insulating sheet of the surface part and reduce the unit weight of cement.

• 한국건축시공학회:학술대회논문집
• /
• 한국건축시공학회 2021년도 봄 학술논문 발표대회
• /
• pp.235-236
• /
• 2021

This study evaluated temperature distribution through adiabatic temperature rising test and hydration heat Analysis as a performance verification to utilize CGS as a hydration heat reduction material for mass concrete when replacing it with fine aggregate. According to the analysis, the temperature difference between the center and the surface was the highest at about 30℃, followed by the CGS 50% at 26℃ and the low heat combiner FA 30% at 23℃.

• 한국건축시공학회:학술대회논문집
• /
• 한국건축시공학회 2023년도 봄 학술논문 발표대회
• /
• pp.229-230
• /
• 2023

In this study, the hydration heat differential method was applied to mass concrete structures, and the hydration heat analysis was compared and analyzed with on-site measurement results. The results showed that the temperature history measurements of mass concrete were managed at a difference of 8.4 ℃, and although there was some deviation in thermal stress, a similar trend was observed. Consequently, it was determined that the thermal stress on the surface of mass concrete is less than its tensile strength, which would prevent the occurrence of thermal cracks.

• 박물관보존과학
• /
• 제29권
• /
• pp.65-80
• /
• 2023

본 연구는 통일신라 하대 전돌 유약의 재료학적 특성을 파악하기 위하여 포항 법광사지 출토 납유 전돌 7점을 조사하였다. 유약의 표면과 단면을 현미경으로 관찰하여 다양한 수화양상을 확인하고 이를 표면층·수화층A·수화층B·녹색층으로 분류하였다. 이들 각 층의 화학조성을 주사전자현미분석으로 측정한 결과, 수화의 영향이 가장 적은 녹색층이 원 조성으로 추정된다. 이 녹색층은 주성분이 PbO와 SiO₂가 8 : 2의 비율로 나타나고 주요 발색원소인 CuO를 약 2% 내외로 함유한 저화도 유약이다. 녹색층은 경상도 납유 전돌의 기 분석된 주성분 자료들과 비교 검토하여 법광사지 납유 조성이 사천왕사지, 천룡사지, 부석사지 바닥전과 유사함을 밝혀냈다.

• 한국구조물진단유지관리공학회 논문집
• /
• 제12권6호
• /
• pp.164-172
• /
• 2008

초기 재령의 매스콘크리트는 양생과정에서 높은 온도를 유발한다. 수화열 저감 기법 중 내부구속이 지배적인 구조물에서 단면의 내외부 온도차를 관리하는 방식은 그 활용도가 매우 높다. 그러나 수화 균열을 예방하기위해 열경사를 조절하는 현재의 제한적인 방법은 콘크리트 중심과 표면 사이에 미세하거나 거대한 균열을 유발할 수 있다. 특히 냉각파이프를 이용하는 방법은 온도의 상승시에는 적용될 수 있지만, 내외부 온도차이가 심한 온도하강시의 대책으로는 적합하지 않다. 따라서 이 문제에 대한 해결방안으로 가열파이프를 동시에 사용하는 모델을 제안하여 유한요소법으로 해석하였다. 해석 결과, 제안된 냉각파이프와 가열파이프를 동시에 사용하는 방법이 열경사조절에 가장 효과적이며 이를 통해 온도균열을 효과적으로 제어할 수 있을 것으로 판단된다.