• Title/Summary/Keyword: Surface hydration

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A Experimental Study on the Seawater Attack Resistance of Grouting Mixtures (내해수성 주입재 배합에 관한 실험적 연구)

  • Chun, Byungsik;Choi, Dongchan;Kim, Younghun;Kim, Jinchun
    • Journal of the Korean GEO-environmental Society
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    • v.11 no.1
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    • pp.53-59
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    • 2010
  • In seawater deposition condition, the corrosion and chemical attack of grouts are similar to those of concrete structure. Used in domestic MSG (Micro Silica Grouting) mixtured large amounts of silicate materials containing as cement powder is $8,000cm^2/g$ of the specific surface area or more due to the high hydration activity and high-strength, high durability, and features, $C_3A$ content of less than 5% to meet the standards chemical attack of seawater was evaluated as a cement material. Therefore, in this paper, with excellent seawater attack resistant MSG in combination with rapid hardening mineral was used, those of seawater characteristics were evaluated experimentally. Typically, sodium-silicate minerals or rapid hardening cements are used in domestic. About the homogel specimens with combination of MSG and rapid hardening agents for compressive strength, weight and length change characteristics were evaluated experimentally, and so we could present the excellent seawater resistant grouts combination.

THE ANALYSIS OF THE FT-NIR SPECTRA OF WATER ON THE BASIS OF TWO-STATE MODEL

  • Boguslawa, Czarnik-Matusewicz
    • Proceedings of the Korean Society of Near Infrared Spectroscopy Conference
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    • 2001.06a
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    • pp.1181-1181
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    • 2001
  • Robinson with ${coworkers}^{1}$ have introduced two-state outer-neighbor bonding model to explain the anomalies of water. The studies on the properties of water as a function of temperature and pressure revealed that, unlike other ideas, all $H_2O$ molecules in liquid are tetrabonded. On the average they are forming two different bonding types. One type is the regular tetrahedral water-water bonding similar to that found in the ordinary ice Ih, whereas the other is a more dense nonregular tetrahedral bonding similar to that appearing in the ice II. The transformation between these two bonding forms is evidenced by FT-NIR experiment. The FT-NIR measurements were done for liquid water in the temperature range from $20^{\circ}C$ up to $80^{\circ}C$ in a wide extent of frequencies: 12 000 - 4000 $cm^{-1}$ /. Temperature dependent variations in the volume fraction of these two structures are directly related to the spectral changes. The absorbance variations are explored by means of the two-dimensional correlation spectroscopy (2DCOS), principal component analysis (PCA), curve fitting and second derivatives. The presence of the isosbestic points in a range of the combination and overtone transitions indicates that the experimental spectra are a superposition of two temperature independent components. One component of diminishing intensity with temperature increase, is assigned to a stronger hydrogen bonds occurred in the Ih type, whereas the second component showing an opposite behavior, one can attribute to a weaker H-bonds characteristic for the II type. The understanding of the hydrogen bonding network in the liquid water is very important in interpretation of the interaction between water and protein chain. The two-state model of water surrounding the protein surface could advance an understanding of the hydration process.

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The Range of Physicochemical Parameters for the Active Ingredients of Fungicides and Insecticides as Crop Protection Agents (작물 보호제로서 살균제와 살충제의 활성 성분에 대한 물리-화학 파라미터의 범위)

  • Song, Sun-Sup;Sung, Nack-Do
    • Applied Biological Chemistry
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    • v.46 no.4
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    • pp.280-284
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    • 2003
  • To develope of diagnosis and estimation system for utility of fungicides and insecticides as crop protection agents, various 10 physicochemical parameters, hydrophobicity (LogP), dipole moment (DM), HOMO energy, LUMO energy, molar refractivity $(MR:\;cm^3/mol)$, polarizability $(Pol:\;A^3)$, van der Waals molecular surface area $(A^2)$, van der Waals molecular volume $(Vol:\;cm^3)$, molecular weight (amu), hydration energy (Kcal/mol) for the active ingredients of 133 fungicides and 152 insecticides were calculated. And then the distribution ranges for each of the physicochemical parameters in fungicides, sterol biosynthesis inhibitors (DMI: demethylation inhibitor), insecticides and acetylcholine esterase inhibitors (AChE) were confirmed. It is suggested that the various compounds based on the range of the physicochemical parametes could be predicted for possibilities as fungicides and insecticides.

Evaluation of the Performance on Coating on Roller Compacted Concrete Pavement for Bike Roads (자전거도로용 롤러 전압 콘크리트 포장의 코팅에 따른 성능 평가)

  • Lee, Chang-Ho;Lee, Seung-Woo;Kim, Seong-Kil
    • International Journal of Highway Engineering
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    • v.13 no.1
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    • pp.79-86
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    • 2011
  • Recently, usage bicycle is encouraged to reduce fuel consumption and air pollution. For this purpose, bike road constructions are actively performed. However, types of pavement used in bike roads have high construction cost and performance comparing the required capacity of bike roads. Thus, an economical pavement type for construction is necessary for the effective development. Roller compacted concrete pavement have good requirements, such as easy construction and low costs, high structural performance of hydration and internal communication aggregation on compaction for bicycle roads. However, the pool landscape surface and resistance to deicer damage cannot be applied to the construction of bicycle roads. Thus, for solving this problem used coating which may have effect of improving the landscape and environmental resistance. To examine this effect were evaluated performance of roller compacted concrete pavement on the coating.

Development of fiber reinforced self-compacting concrete (FRSCC): Towards an efficient utilization of quaternary composite binders and fibers

  • Fediuk, Roman;Mosaberpanah, Mohammad A.;Lesovik, Valery
    • Advances in concrete construction
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    • v.9 no.4
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    • pp.387-395
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    • 2020
  • This study has been carried out in two-phases to develop Fiber Reinforced Self-Compacting Concrete (FRSCC) performance. In the first phase, the composition of the quaternary composite binder compromised CEM I 42.5N (58-70%), Rice Husk Ash (25-37%), quartz sand (2.5-7.5%) and limestone crushing waste (2.5-7.5%) were optimized. And in the second phase, the effect of two fiber types (steel brass-plated and basalt) was investigated on the SCC optimized with the optimum CB as disperse reinforcement at 6 different ratios of 1, 1.2, 1.4, 1.6, 1.8, and 2.0% by weight of mix for each type. In this study, the theoretical principles of the synthesis of self-compacting dispersion-reinforced concrete have been developed which consists of optimizing structure-formation processes through the use of a mineral modifier, together with ground crushed cement in a vario-planetary mill to a specific surface area of 550 m2 / kg. The amorphous silica in the modifier composition intensifies the binding of calcium hydroxide formed during the hydration of C3S, helps reduce the basicity of the cement-composite, while reducing the growth of portlandite crystals. Limestone particles contribute to the formation of calcium hydrocarbonate and, together with fine ground quartz sand; act as microfiller, clogging the pores of the cement. Furthermore, the results revealed that the effect of fiber addition improves the mechanical properties of FRSCC. It was found that the steel fiber performed better than basalt fiber on tensile strength and modulus of elasticity; however, both fibers have the same performance on the first crack strength and sample destruction of FRSCC. It also illustrates that there will be an optimum percentage of fiber addition.

Characteristics on Spawning-Host Selection and Early Life History of Sarcocheilichthys nigripinis morii (Pisces, Cyprinidae) (중고기(Sarcocheilichthys nigripinis morii)의 산란숙주 선택 및 초기 생활사 특성)

  • Kang, Eon-Jong;Yang, Hyun;Lee, Heung-Heon;Kim, Eong-Oh;Kim, Chi-Hong
    • Korean Journal of Environmental Biology
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    • v.25 no.4
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    • pp.370-377
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    • 2007
  • The spawning host selection and adaptive characteristics in life history were investigated for Sarcocheilichthys nigripinnis morii which has similar habit of spawning with acheilognathine fishes. The fertilized eggs of the species were found in the mantle cavity of Corbicula papyracea and C. fluminea among the bivalves collected from same locality, meaning the species specific host selection for the spawning. We considered that the differences in the status of expanding egg membrane after hydration, fewer number of eggs settled into the mantle cavity and having eleutheroembryo with developed organ would be some evidences of specific reproductive strategy for this species. But the status of developed surface blood circulation was thought to be a compensation for the parasitism. The pigmentation of melanopore delayed to late embryo and the spot on the caudal region was a characteristics of this species appeared in the early life history.

Study on Cracking Causes and Patterns in Median Barrier and Guardrail Concrete in RC Bridge (콘크리트 교량 방호벽의 균열원인 및 패턴 분석에 대한 연구)

  • Choi, Se-Jin;Choi, Jung-Wook;Kwon, Seung-Jun
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.18 no.5
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    • pp.19-26
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    • 2014
  • Concrete guide rail and median barrier are an attached RC member, however they are vulnerable to cracking due to slip form construction and large surface of member. In this study, causes and pattern of cracking are analyzed through assessment and NDT (Non-Destructive Technique) evaluation for concrete guide rail and median barrier on highway structure. For this work, analysis on drying shrinkage and hydration heat are performed considering installation period, and plastic shrinkage is also analyzed considering their environmental conditions. From the evaluation, plastic settlement around steel location, drying/ plastic shrinkage, and aggregate segregation are inferred to be the main causes of cracking in the structures. The crack causes and patterns are schematized and techniques of crack-control are suggested. Furthermore concrete guide rail/ median barrier in the bridge on the sea are vulnerable to cracking at early age so that special attentions should be paid at the stages of material selection and construction.

Influence of Micro-Structural Characteristics of Concrete on Electrical Resistivity (콘크리트의 미세구조 특성이 전기저항에 미치는 영향)

  • Yoon, In-Seok
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.17 no.6
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    • pp.122-129
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    • 2013
  • Since electrical resistivity of concrete can be measured in a more rapid and simple way than chloride diffusivity, it should be primarily regular quality control of the electrical resistivity of concrete which provides the basis for indirect of quality control of chloride diffusivity during concrete construction. If this is realized, the electrical resistivity of concrete can be a crucial parameter to establish maintenance strategy for marine concrete structures. The purpose of this study is to develop, design and test a surface electrical resistivity measurement protocol. Microstructural affecting factors such as capillary water, porosity, tourtousity, and so on, on the electrical resistivity of concrete were examined taking into account for mixing proportion properties, and hydration stage. This study can provide a non-destructive approach for durability design of marine concrete. From the relationship between electrical resistivity and chloride diffusivity, it is expected that the result is subsequently used as a calibration curve for an indirect control of the chloride diffusivity based on regular measurements of the electrical resistivity during concrete construction.

Optimization of the Preparation of Rice-based Infant Foods Using Freeze Drying Process (냉동건조를 이용한 쌀기본 이유식 제조에 있어서 건조조건의 최적화)

  • Kim, Kwang-Ok;Choi, Ho-Jung
    • Korean Journal of Food Science and Technology
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    • v.27 no.5
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    • pp.680-689
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    • 1995
  • Rice based infant foods of carrot, of beef, and of egg for 4-6 month old infants were prepared using freeze drying (FD) process. The optimum moisture content prior to FD and the plate temperature in the drier were determined with the use of response surface methodology. For all the infant foods under this study, FD time was longer as the initial moisture content was higher and the plate temperature was lower. Brittleness of the dried infant foods increased as the moisture content decreased and the plate temperature increased. Among the sensory attributes, hydration rate, uniformity, and smoothness were greater with increased moisture content and with decreased plate temperature. Ease to spoon increased as moisture content increased and mouthcoating increased as both the moisture content and the plate temperature increased. Optimum moisture content and plate temperature for the FD of carrot, beef and egg foods were 88.5% and $34^{\circ}C$, 88.5% and $28^{\circ}C$, and 87.3% and $39^{\circ}C$, respectively.

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Aggravating and Mitigating Patient Factors Affecting Mild to Moderate Atopic Dermatitis (중등도 이하 아토피 피부염에 영향을 미치는 환자 요인)

  • Kang, Dong-Won;Kim, Yoon-Bum
    • The Journal of Korean Medicine Ophthalmology and Otolaryngology and Dermatology
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    • v.33 no.4
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    • pp.1-15
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    • 2020
  • Objectives : To investigate aggravating and mitigating factors of atopic dermatitis and to utilize the outcome in treatment planning. Methods : The research has a cross-sectional study design. Patients' SCORing Atopic Dermatitis (SCORAD) Index, demographic, physical characteristics, social history, serologic index and skin related instrumental measurements were analyzed with correlation and regression analysis method. Results : 48 patients in total were enrolled in the study. Skin Surface Hydration (SSH) and sex were found to be statistically significant aggravating and mitigating factors. As SSH increased, Total SCORAD (tSCORAD) and Objective SCORAD (oSCORAD) increased as well. As SSH decreased, tSCORAD and oSCORAD decreased as well. Female patient had a higher probability of suffering from severer subjective symptoms than that of male. Age, body mass index (BMI), alcohol consumption and smoking, transepidermal water loss (TEWL), IgE, IL-4, IL-5, IL-6, IFN-γ were found not to be statistically significant. There was no correlation between Subjective SCORAD (sSCORAD) and oSCORAD neither with Eczema Area and Severity Index (EASI). Conclusions : Increasing cutaneous moisture should be included in the treatment plan of atopic dermatitis. More emphasis should be put on alleviating subjective discomforts of female patients than that of male. Establishing separate strategies of managing objective eczema status and subjective discomforts respectively should be considered.