• Proceedings of the Korean Institute of Surface Engineering Conference
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• 2007.11a
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• pp.71-74
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• 2007

• Transactions of the Korean Society of Mechanical Engineers B
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• v.40 no.11
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• pp.697-704
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• 2016

Coal modified by acid treatment was investigated to analyze the correlation between the cell performance and electrochemical parameters in a direct carbon fuel cell (DCFC). The fuels were subjected to thermogravimetry analysis, gas adsorption test, and X-ray photoelectron spectroscopy to investigate the fuel properties and surface characteristics. After the treatment of raw coal, the thermal reactivity of the treated fuels increased, and the specific surface area decreased, though the mean pore diameters of three fuels were similar. The coal treated by $HNO_3$ showed the highest ratio of oxygen to carbon, and also an increase in the surface oxygen groups on the fuel surface. Through comparison between the fuel surface properties and electrochemical performance, it was confirmed that the surface oxygen groups have an influence on the improvement in the DCFC performance.

• Fire Science and Engineering
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• v.11 no.4
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• pp.15-23
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• 1997

A series of measurements and visualization to investigate the extingushiment of water sprays with pool fires is presented. Fire source is a small-scale pool burner with methanol, ethanol and gasoline. Measurements of temperature, O2, CO2, and CO concentrations along the plume centerline are carried out to observe pool structures without water sprays. Visualization by the Ar-ion laser sheet flow pattern of droplets of the sprays above the pool fires. It is observed than in the case of methanol and ethanol, water sprays continuously penetrate into the center of fuel surfaces. The gasoline pool fire allows intermittent penetration of water sprays because of pulsating characteristics of the gasoline flame. To evaluate the cooling effect of the fuel surface by the sprays, the temperature was measured at the fuel surface. As soon as the mists reach the fuel surface of methanol and ethanol, the temperatures of the fuel surface decrease rapidly below the boiling point, and then the fires are extinguished. Due to the application of mist upon the gasoline fire, though the fuel temperature decrease abruptly at the time of the injection, such a repid decrease do not continue till the extinction point.

• Proceedings of the Korea Society for Energy Engineering kosee Conference
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• 2004.11a
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• pp.133-138
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• 2004

Proton exchange membrane fuel cell (PEMFC) is considered as a clean and efficient energy conversion det ice for mobile and stationary applications. Anions all the components of the PEMFC, the interface between the electrolyte ,and electrode catalyst plays an important role in determining tile cell performance since the electrochemical reactions take place at the interface in contact with tile reactant gases. Therefore, to increase the interface area and obtain a high-performance PEMFC, surface of the electrolyte membrane was roughened by Ar$^{+}$ beam bombardment. The results imply that by modifying surface of the electrolyte membrane, platinum loading can be reduced significantly without performance loss. To optimize the surface treatment condition, effects of ion dose density on characteristics of the membrane/electrode interface were examined by measuring the cell performance, impedance spectroscopy, and cyclic voltammograms. Surface of the modified membranes were characterized using scanning electron microscopy and FT-IR.R.

• Journal of Radiation Protection and Research
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• v.36 no.4
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• pp.174-182
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• 2011

With the reactor operation conditions - 4.3 wt% $^{235}U$ initial enrichment, burn-up 55,000 MWd/MTU, average power 34 MW/MTU for three periods burned time for 539.2 days per period and cooling time for 100 hours after shut down, to set up the condition to determine the minimum height (depth) of spent fuel storage pool to shut off the radiation out of the spent fuel storage pool and to store spent fuels safely, the dose rate on the specific position directed to the surface of spent fuel storage pool induced by the neutron and gamma-ray from spent fuels are evaluated. The length of spent fuel is 381 cm, and as the result of evaluation on each position from the top of spent fuel to the surface of spent fuel storage pool, it is difficult for neutrons from spent fuels to pass through the water layer of maximum 219 cm (600 cm from the floor of spent fuel storage pool) and 419 cm (800 cm from the floor of spent fuel storage pool) for gamma-ray. Therefore, neutron and gamma-ray from spent fuels can pass through below 419 cm (800 cm from the floor) water layer directed to the surface of spent fuel storage pool.

• Proceedings of the KSME Conference
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• 2008.11b
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• pp.2236-2241
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• 2008

The surface heat flux of nuclear fuel rod is the most important factor which can affect safety of reactor and fuel. If fuel rod surface heat flux exceeds the CHF(${\underline{C}}ritical$ ${\underline{H}}eat$ ${\underline{F}}lux$), fuel can be damaged. In case of double cooled annular fuel, which is under developing, contains two coolant channels. Therefore, a generated heat in the fuel pellet can move to inner or outer channel and heat flow direction is decided by both sides heat resistance which varied by dimension and material property change which caused by temperature and irradiation. The new program(called DUO) was developed. For the calculation of surface heat flux, a both sides convection by inner/outer coolant, s gap temperature jump and conduction in the fuel are modeled. Especially, temperature and time dependent fuel dimension and material property change are considered during the iteration. A sample calculation result shows that the DUO program has sufficient performance for annular fuel thermal hydraulics design.

• Journal of the Korean Society of Propulsion Engineers
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• v.11 no.4
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• pp.46-51
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• 2007

The irregular fuel surface was observed by the visualization of hybrid rocket combustion. Even though the test condition maintained oxidizer rich environment, the irregular dark fuel surface was formed as the result of incomplete combustion. In order to investigate the correlation of the characteristics of oxidizer flow and the irregular fuel surface, various flow conditions were imposed such as swirl flow, induced swirl flow by helical fuel configuration and straight flow. Test results revealed no correlation was found between oxidizer flow condition and irregular fuel surface. And this can be a commonly observed phenomena in the tests with different fuel/oxidizer combination. Thus, the irregular fuel surface can be a result of the interaction of blowing flow of vaporized fuel and the boundary layer of oxidizer flow. A further study will be required to confirm the assumption for the formation of irregular fuel surface.

• Journal of the Korean Society of Propulsion Engineers
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• v.11 no.4
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• pp.52-58
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• 2007

The irregular fuel surface was observed by the visualization of hybrid rocket combustion. Even though the test condition maintained oxidizer rich environment, the irregular dark fuel surface was formed as the result of incomplete combustion. In order to investigate the correlation of the characteristics of oxidizer flow and the irregular fuel surface, various flow conditions were imposed such as swirl flow, induced swirl flow by helical fuel configuration and straight flow. Test results revealed no correlation was found between oxidizer flow condition and irregular fuel surface. And this can be a commonly observed phenomena in the tests with different fuel/oxidizer combination. Thus, the irregular fuel surface can be a result of the interaction of blowing flow of vaporized fuel and the boundary layer of oxidizer flow. A further study will be required to confirm the assumption for the formation of irregular fuel surface.

• Carbon letters
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• v.4 no.3
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• pp.121-125
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• 2003

The Pt-Ru/Carbon as an anode catalyst supported on the commercial activated carbon (AC) having high surface area and micropore was characterized for application of Direct Methanol Fuel Cell (DMFC). The Pt-Ru/AC anode catalyst used in this experiment showed the performance of $600\;mA/cm^2$ current density at 0.3 V. The borohydride reduction process using $NaBH_4$, denoted as a process A, showed much higher current and power densities than process B prepared by changing the reduction and washing process of process A. The particle sizes are strongly affected by the reduction process than the specific surface area of raw active carbon and the sizes are almost constant when the specific surface area of carbon are over than the $1200\;m^2/g$. Smaller particle size of catalyst and more narrow intercrystalite distance increased the performance of DMFC.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2007.04a
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• pp.233-237
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• 2007

Recent experimental data shows that an irregular fuel surface pops up during the combustion test. This may contribute to the agitated boundary layer due to blowing effect of fuel vaporization. Blowing effect can be of significance in determining the combustion characteristics of solid fuel within the oxidizer flow. LES was implemented to investigate the flow behavior on the fuel surface and turbulence evolution due to blowing effect. Simple channel geometry was used for the investigation instead of circular grain configuration without chemical reactions. This may elucidate the main mechanism responsible for the formation of irregular isolated spots during the combustion in terms of turbulence generation. The interaction of turbulent flow with blowing mass flus causes to breakup turbulent coherent structures and to form the small scale isolated eddies near the fuel surface. This mechanism attributes to the formation of irregular isolated sopt on the fuel surface.