• Title/Summary/Keyword: Surface diffusion

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Characterization of Zn diffusion in TnP Cy $Zn_3P_2$ thin film and rapid thermal annealing (RHP에서의 $Zn_3P_2$ 박막 및 RTA법에 의한 Zn 확산의 특성)

  • 우용득
    • Journal of the Korean Vacuum Society
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    • v.13 no.3
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    • pp.109-113
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    • 2004
  • Zn diffusions in InP have been studied by electrochemical capacitance voltage. The InP layer was grown by metal organic chemical vapor deposition, and $Zn_3P_2$ thin film was deposited on the epitaxial substrates. The samples annealed in a rapid thermal annealing. It is demonstrated that surface hole concentration as high as $1\times10^{19}\textrm{cm}^{-3}$ can be achieved. When the Zn diffusion was carried at $550^{\circ}C$ and 5-20 min., the diffusion depth of hole concentration moves from 1.51$\mu\textrm{m}$ to 3.23 $\mu\textrm{m}$, and the diffusion coeffcient of Zn is $5.4\times10^{-11}\textrm{cm}^2$/sec. After activation, the concentration is two orders higher than that of untreated sample at 0.30 $\mu\textrm{m}$ depth. As the annealing time is increase, the hole concentration remains almost constant, except deep depth. It means that excess Zn interstitials exist in the doped region is rapidly diffusion into the undoped region and convert into substitutional When the thickness of $SiO_2$ thin film is above 1,000$\AA$, the hole concentration becomes stable distribution.

Influence of Water-Cement Ratios and Curing Conditions on the Diffusion Characteristics of Chloride Ion in Concrete (콘크리트의 염소이온 확산특성에 미치는 물-시멘트비 및 양생조건의 영향)

  • Bae, Su-Ho;Lee, Kwang-Myong;Kim, Jee-Sang;Jung, Sang-Hwa
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.26 no.4A
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    • pp.753-759
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    • 2006
  • To predict service life of concrete structures exposed to chloride attack, surface chloride concentration, diffusion coefficient of chloride ion, and chloride corrosion threshold value in concrete, are used as important factors. Of these, as the diffusion coefficient of chloride ion for concrete is strongly influenced by concrete quality and environmental conditions of structures and may significantly change the service life of structures, it is considered as the most important factor for service life prediction. The qualitative factors affecting the penetration and diffusion of chloride ion into concrete are water-cement (W/C) ratio, age, curing conditions, chloride ion concentration of given environment, wet and dry conditions, etc. In this paper the influence of W/C ratio and curing conditions on the diffusion characteristics of chloride ion in concrete was investigated through the chloride ion diffusion test. In the test, the voltages passing through the diffusion cell were measured by accelerated test method using potential difference, and then with the consideration of IR drop ratio the diffusion coefficient of chloride ion for concrete with different W/C ratios were estimated by Andrade's model. Furthermore, under different curing conditions formulas for the estimation of the diffusion coefficient of chloride ion have been proposed by the regression analysis considering the effect of W/C ratio and age.

A Study on the Duplex Treatment of Simultaneous Aluminizing-Chromizing and Plasma Nitriding for Improvement of Surface Properties (Al-Cr의 동시확산과 플라즈마 질화의 복합처리에의한 표면향상에 관한연구)

  • 양준혁;이상률;한전건
    • Journal of the Korean institute of surface engineering
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    • v.31 no.6
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    • pp.325-333
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    • 1998
  • A duplex surface treatment process of simultaneous aluminizing-chromizing process followed by plasma nitriding was performed on AISI HI3 steel and STS 403 steel. The properties of these duplex-treated steels were investigated and were compared with those of steels treated by single process of either simultaneous aluminizing-chromizing or plasma nilriding, in terms of microstructure, microhardness and high temperature wear resistance. Sim~dtaneous alumizing-chromizing process was done using a 2-step coating cycle and plasma nitriding process was done at $530^{\circ}C$ for 1.5 hour. AISI HI3 steel and STS 403 steel showed a FeA1 compound layer of approximately 350$\mu\textrm{m}$ thickness on the surface after simultaneous diffusion coating and nitrided layer of approximately 70-80$\mu\textrm{m}$ formed after the subsequent plasma nitriding process. The microhardness was improved much more by the duplex surface heatment than only by plasma nitriding. In addition the duplex treated specimens showed an improved high temperature wear resistance.

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Development of Free-surface Decomposition Method and Its ApplicationDevelopment of Free-surface Decomposition Method and Its Application

  • Park, Sunho
    • Journal of Advanced Research in Ocean Engineering
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    • v.3 no.2
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    • pp.75-82
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    • 2017
  • With the development of computational fluid dynamics (CFD), studies on shipbuilding and maritime issues including free-surface wave flow have been conducted. Although the volume of fluid (VOF) and level-set methods are widely used to study the free-surface wave flow, disadvantages exist. In particular, it takes a long time to obtain solutions. In this study, a free-surface capturing code is developed for ship and offshore structures. The developed code focuses on accuracy and computation time. Open source CFD libraries, termed OpenFOAM, are used to develop the code. The results obtained using the developed code are compared with those obtained using interFoam. The results show that the developed code could be used to capture the free-surface wave flow without numerical diffusion; moreover, the accuracy of the developed code is largely the same as that of interFoam.

Coupled Heat and Mass Transfer in Absorption of Water Vapor into LiBr-$H_2O$ Solution Flowing over a Finned Inclined Surface (좁은 휜이 달린 경사면을 흐르는 리튬브로마이드 수용액 흡수기에서의 열 및 물질전달)

  • 조은준;서태범
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.13 no.9
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    • pp.860-867
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    • 2001
  • Absorption of water vapor into LiBr-$H_2O$ O solution flowing over a finned inclined surface is numerically investigated. The momentum, energy, and diffusion equation are numerically solved using a finite difference method. The four different shapes of the wall surfaces are considered to find the best surface for absorption assuming that the wall temperature and the surface tension are constant. The effects of the fin interval and Reynolds number are investigated. Based on the numerical results, it is known that the parabolic surface shows better absorption performance than the other surfaces, and that water vapor absorption increases gradually with decreasing the fin interval.

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Analysis of Polymeric Insulators Exposed to In-service Conditions (실 포설 환경에 노출된 송전용 고분자애자의 평가)

  • Lee, Sang-Jin;Youn, Bok-Hee;Bai, Kyoung-Moo;Jeon, Seung-Ik
    • Proceedings of the KIEE Conference
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    • 2004.11a
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    • pp.248-250
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    • 2004
  • We have investigated the surface state of 154kV polymeric insulators exposed to in-service conditions for about five years. In order to evaluate surface aging of silicone rubber exposed to real field environments, we used various analytic methods such as contact angle, ATR-FTIR, SEM-EDS. Although contaminants were accumulated on weathershed surface, polymeric insulator has retained its intrinsic surface hydrophocity. In addition, ATR-FTIR confirmed the diffusion layer of a low molecular weight silicone fluid on surface layer and no surface cracking and chalking were Indicated by SEM. Polymeric insulators have still retained their improved pollution performance over porcelain insulators. That will lead to very low frequency of flashovers throughout their useful life, often under contaminated conditions.

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Surface Modification of a Mild and Stainless Steel by Alumina Spraying (아루미나 용사에 의한 연강 및 스테인레스강의 표면개질)

  • 배종규;박승옥;정인상
    • Journal of the Korean institute of surface engineering
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    • v.22 no.4
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    • pp.185-196
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    • 1989
  • The surface modification of a mild and stainless steel by alumina sprayed coating were studied. The effects of surface roughness and bond coating layer on the adhesive strengthy and durability of sprayed specimens were also investiated. The adhesive strength of ceramic coating was affected by surface roughness and bond coating layer thinkness. That showed excellent undergrit blast time and bond coating layer; 60 sec and 0.15-0.33mm, respectively. The adhesive strength and densification of sprayed coating with air pressure were superior to those of without and fracture was mainly occured at alumina-bond coating interface. Under ambient atmosphere at $800^{\circ}C$, the oxides existed within bond coating layer promote diffusion of oxygen to lower durability of sprayed specimens. In this case, fracure was occured at sudstrate-bond coating interface.

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Ionic-to-Metallic Layer Transition in Cs Adsorption on Si(111)-(7$\times$7). Charge-State Selective Detection of Adsorbate by Cs+ Reactive Ion Scattering.

  • Han, Seung-Jin;Park, Sung-Chan;Kang, Heon
    • Proceedings of the Korean Vacuum Society Conference
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    • 2000.02a
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    • pp.155-155
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    • 2000
  • Adsorption of alkali metals on a silicon surface has attracted much attention due to its importance in metal-semiconductor interface technology, In particular, the bonding nature of alkali metal to silicon substrate has been a focus of fundamental research efforts. We examined the adsorbed layer of Cs on a Si(111)-(7$\times$) surface by reactive ion scattering (RIS) of hyperthermal Cs+ beams. RIS from a Cs-adsorbed surface gives rise to Cs, representing pickup of surface Cs by Cs projectile. The Cs intensity is proportional to surface coverage of Cs at a high substrate temperature (473 K), while it varies anomalously with Cs coverage at low temperatures (130-170 K). This observation indicates that RIS selectively detects metallic Cs on surface, but discriminates ionic Cs. Transition from ionic to metallic Cs adlayer is driven by thermal diffusion of Cs and their clustering process.

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Enhancement of Surface Hardness of Zirconia Ceramics by Hydroxyapatite Powder Bed Sintering (Hydroxyapatite 분위기 소결을 통한 지르코니아 표면 경도 강화)

  • Choi, Min-Geun;Lim, Ji-Ho;Kong, Kyu-Hwan;Jeong, Dae-Yong;Lee, Wonjoo;Li, Long-Hao;Kong, Young-Min
    • Korean Journal of Materials Research
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    • v.24 no.12
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    • pp.677-681
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    • 2014
  • To increase the mechanical property of zirconia, we have investigated the phase change and the resulting hardness of zirconia ceramics by hydroxyapatite (HA) powder bed sintering. It was observed using X-ray diffraction that the cubic zirconia phase, which has a higher hardness value than that of the tetragonal phase, was obtained at the surface of 3 mol% $Y_2O_3$ doped tetragonal zirconia polycrystal (3Y-TZP) ceramics during the sintering process; in our experimental conditions, the phase change at the surface increased as the sintering time increased. We believe that the observed crystalline phase change originated from the decomposition of HA and the diffusion of CaO, as follows. CaO, which was derived from the decomposition of HA at high temperature ($1400^{\circ}C$), diffused into the surface of 3Y-TZP and acted as a stabilizer. As a result, the Vickers hardness value of the treated specimens was higher than that of the non-treated specimen due to the formation of the cubic phase on the surface of 3Y-TZP.

Effect of Boundary Layer Generated on the fin surfaces of a Compact Heat Exchanger on the Heat Transfer and Pressure Drop Characteristics (컴팩트형 열교환기의 핀 표면에서 발생하는 경계층이 열교환기의 전열 및 압력강하 특성의 변화에 미치는 영향에 관한 수치해석적 연구)

  • KIM Chul-Ho;Jung Ji-Yong
    • Journal of computational fluids engineering
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    • v.3 no.1
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    • pp.82-88
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    • 1998
  • As a par of a project related to the development of the design algorithm of a compact heat exchanger for the application of the electronic home appliances, the effect of the discreteness of the airflow boundary generated on the cooling fin surface on the heat transfer and pressure drop characteristics of the heat exchanger was studied numerically. In general, there are two critical design parameters seriously considered in the design of the heat exchanger; heat transfer rate(Q) and pressure drop coefficient(C/sub p/). Even though the higher heat transfer rate with lower pressure drop characteristics is required in a design of the heat exchanger, it is not an easy job to satisfy both conditions at the same time because these two parameters are phenomenally inversely proportional. To control the boundary layer thickness and its length along the streamline, the surface of the flat fin was modified to accelerate the heat transfer rate on the fin surface. To understand the effect of the discreted fin size(S/sub w/) and its location(S/sub h/) on the performance of the heat exchanger in the airflow field, the flat fin was modified as shown in Fig. 1. From this study, it was found that the smaller and more number of slits on the fin surface showed the higher energy diffusion rate. It means that the discreteness of the boundary layer is quite important on the heat transfer rate of the heat exchanger. On the other hand, if the fin surface configuration is very complex than needed, higher static pressure drop occurs than required in a system and it may be a reason of the induced aerodynamic noise in the heat exchanger.

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