• Journal of Conservation Science
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• v.27 no.1
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• pp.101-114
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• 2011

The rock-carved Buddha statue at Dosolam (Korea Treasure No. 1200) of the Seonunsa temple in Gochang is unique style sculptured on natural rock cliff of 13.0m height. The Buddha statue is composed of volcanic complex with tuff, dacitic tuff breccia, tuff bereccia and lithic tuff. Especially, the Buddha statue is characterized by hydrothermal alteration and fragmentation on the upper and lower part. As a result of damage diagnosis, exfoliation and detachment of physical weathering are high of 11.3% and 9.3%, respectively. Infrared thermography analysis, exfoliation and micro-cracks occurred in the measuring parts that have not been confirmed by naked eyes. Chemical index of alteration and weathering potential index of host rock for the Buddha statue are 55.16 to 64.01 and 6.14 to 9.92 which are represented within highly weathering degree. In surface, dark black, reddish brown and white discoloration are observed prominently in the lower. Brown discoloration 6.9% is highest. According to the P-XRF measurements, high concentration of Fe in common, in part of dark black discoloration was Mn, white and brown discoloration in part of S and Ca content were higher. Biological weathering that yellowish brown and dark gray crustoes lichenes appeared by 20.8% and 13.3%, respectively. Therefore, comprehensive deterioration rate of Buddha statue show physical damage by 21.2%, discoloration for inorganic contaminants by 10.8% and biological damage by 39.4%. Ultrasonic velocity measurement carried out of Buddha statue on the surface by 555 points. Measured value of ultrasonic velocity was about 2,273m/s(1,067 to 3,215m/s, and weathering coefficient is 0.5(0.4 to 0.8) that progress on MW(moderately weathered) to HW(highly weathered) grade of rocks.

• Journal of Korean Tunnelling and Underground Space Association
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• v.16 no.3
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• pp.311-320
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• 2014

High strength concrete is not only vulnerable to the occurrence of spalling which generates the loss of cross-section in concrete structures but produces faster degradation in its mechanical properties than normal strength concrete in the event of fire. This study aims to evaluate fire resistance of high strength segment concrete with PET fibers mixed to prevent spalling under ISO834 (2hr) and RABT fire curve. As results, the samples without PET fibers show the concrete loss up to the depth of about 8 cm and 9.5 cm from the surface exposed to fire under ISO834 and RABT fire curve respectively. The samples mixed with PET fiber of 0.1% show no spalling under ISO834 fire curve and the spalled thickness of 6.5 cm under RABT fire curve after the fire tests. Finally, the sample mixed with PET fiber of 0.2% shows no spalling under RABT fire curve. The results indicate that the suitable amounts of PET fiber for securing fire resistance performance of this high strength segment concrete are 0.1% under ISO834 fire curve and 0.2% under RABT fire curve. However, even though spalling does not occur, it is necessary to repair the deterioration of concrete up to 4 cm from the surface exposed to fire after fire.

• Proceedings of the Korean Vacuum Society Conference
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• 2016.02a
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• pp.417-417
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• 2016

Global environmental deterioration has become more serious year by year and thus scientific interests in the renewable energy as environmental technology and replacement of fossil fuels have grown exponentially. Photoelectrochemical (PEC) cell consisting of semiconductor photoelectrodes that can harvest light and use this energy directly to split water, also known as photoelectrolysis or solar water splitting, is a promising renewable energy technology to produce hydrogen for uses in the future hydrogen economy. A major advantage of PEC systems is that they involve relatively simple processes steps as compared to many other H2 production systems. Until now, a number of materials including TiO2, WO3, Fe2O3, and BiVO4 were exploited as the photoelectrode. However, the PEC performance of these single absorber materials is limited due to their large charge recombinations in bulk, interface and surface, leading low charge separation/transport efficiencies. Recently, coupling of two materials, e.g., BiVO4/WO3, Fe2O3/WO3 and CuWO4/WO3, to form a type II heterojunction has been demonstrated to be a viable means to improve the PEC performance by enhancing the charge separation and transport efficiencies. In this study, we have prepared a triple-layer heterojunction BiVO4/WO3/SnO2 photoelectrode that shows a comparable PEC performance with previously reported best-performing nanostructured BiVO4/WO3 heterojunction photoelectrode via a facile solution method. Interestingly, we found that the incorporation of SnO2 nanoparticles layer in between WO3 and FTO largely promotes electron transport and thus minimizes interfacial recombination. The impact of the SnO2 interfacial layer was investigated in detail by TEM, hall measurement and electrochemical impedance spectroscopy (EIS) techniques. In addition, our planar-structured triple-layer photoelectrode shows a relatively high transmittance due to its low thickness (~300 nm), which benefits to couple with a solar cell to form a tandem PEC device. The overall PEC performance, especially the photocurrent onset potential (Vonset), were further improved by a reactive-ion etching (RIE) surface etching and electrocatalyst (CoOx) deposition.

• Journal of Korean Society of Steel Construction
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• v.28 no.5
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• pp.373-382
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• 2016

Painting or thermally sprayed metal coating is often used in corrosion protection of steel structures. In recently, duplex coating system which combines thermally sprayed metals with paint is selected as a new generic type of coatings on steel structures under the highly corrosive environments. In this study, the structural steel specimens were surface treated, thermally sprayed with zinc, zinc-15%aluminum alloy, aluminum and aluminum-5%magnesium alloy, and finally sealing or painted with acrylic urethane. And as a reference specimens, steel specimens were painted with acrylic urethane after surface treatment. Circular defects with 1.0, 3.0 and 5.0 mm in diameters and line defect with 2.0 mm width, which reach the steel substrate were created on all specimens. The specimens were exposed into an environmental testing chamber controlled by the ISO 20340, which is a laboratory cyclic accelerated exposure test condition of spraying/UV/low temperature, for up to 175 days. Based on the corrosion tests, corrosion deterioration from the initial defects were evaluated and weathering performance of the specimens are compared.

• Proceedings of the Korean Institute Of Construction Engineering and Management
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• autumn
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• pp.539-542
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• 2002

Crack sealing is a maintenance procedure that is commonly used to reduce pavement degradation. If cracks in pavements are not sealed, surface water penetration can reduce the strength of the sub-base layers, which can result in increased deflections of the pavement. Reduced strength of the sub-base also accelerates the deterioration of the surface, due to development of greater cracking and potholes. Crack sealing is performed to reduce water and debris penetration, thereby helping to maintain pavement structural capacity and limiting future degradation. The process of sealing cracks in pavements is however dangerous, costly, and labor-intensive operation. Labor turnover and training are increasing problems related to crack sealing crews, and as traffic volumes increase. Automating crack sealing can reduce labor and road user costs, improve work quality, and decrease worker exposure to roadway hazards. The main objective of this research is to develop an automated system for sealing cracks in pavement. Extension of the algorithms and tools presented in this research is also recommended for future study.

• Journal of the Korean Ceramic Society
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• v.41 no.10 s.269
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• pp.742-748
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• 2004

Isopropanol of low boiling point was used as a solvent to prepare Al-doped ZnO(AZO) thin films. A homogeneous and stable sol was made from Zn acetate a solute whose mole concentration was 0.7mol/$\iota$ and Al chloride as a dopant. Al-doped ZnO thin films were prepared by sol-gel method as a function of post-heating temperature from 500 to $700^{\circ}C$ and the optical and electrical properties were investigated. The c-axis orientation along (002) plane was enhanced with the increasing of post-heating temperature and the surface morphology of the films showed a homogeneous and nano-sized microstructure. The optical transmittance of the films post-heated below $650^{\circ}C$ was over $86\%$, but decreased at $700^{\circ}C$. The electrical resistivity of the thin films decreased from 73 to 22 $\Omega$-cm as the post-heating temperature increased up to $650^{\circ}C$, but increased greatly to 580 $\Omega$-cm at $700^{\circ}C$. XPS analysis indicated that the deterioration of electrical and optical properties was attributed to the precipitation of $Al_2O_3$ phase on the surface of AZO thin film. This result suggests that the optimum post-heating temperature to improve electrical and optical properties is $600^{\circ}C$.

• 한국신재생에너지학회:학술대회논문집
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• 2006.11a
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• pp.348-351
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• 2006

Bipolar plate, which forms about 50% of the stack cost, is an important core part with polymer electrolyte membrane in PEMFC. Bipolar plates have been commonly fabricated from graphite meterial having high electrical conductivity and corrosion resistance. Lately, many researchers have concentrated their efforts on the development of metallic bipolar plate and stainless steel has been considered as a potential material for metallic bipolar plate because of its high strength, chemical stability, low gas permeability and applicability to mass production. However, it has been reported that its inadequate corrosion behavior under PEMFC environment lead to a deterioration of membrane by dissolved metal ions and an increase in contact resistance by the growth of passive film therefore, its corrosion resistance as well as contact resistance must be improved for bipolar plate application. In this work, several types of coating were applied to 316L and their electrical conductivity and corrosion resistance were evaluated In the simulated PEMFC environment. Application of coating gave rise to low interfacial contact resistances below $19m{\Omega}cm^2$ under the compress force of $150N/cm^2$. It also made the corrosion potential to shift in the posit ive direct ion by 0.3V or above and decreased the corrosion current from ca. $9{\mu}A/cm^2$ to ca. $0.5{\mu}A/cm^2$ in the mixed solution of $0.1N\;N_2SO_4$ and 2ppm HF A coat ing layer under potentiostatic control of 0.6V and $0.75V_{SCE}$ for 500 hours or longer showed some instabilities, however, no significant change in coat Ing layer were observed from Impedance data. In addition, the corrosion current maintained less than $1{\mu}A/cm^2$ for most of time for potentiostatic tests. It indicates that high electrical conductivity and corrosion resistance can be obtained by application of coatings in the present work.

• Journal of Conservation Science
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• v.17 s.17
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• pp.39-56
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• 2005

The Gwangtonggyo(bridge) on the Cheonggyecheon(river) is mainly composed of biotite granite with coarse grain. The rock consists mainly of quartz, plagioclase, microcline, orthoclase and biotite with lesser amount of muscovite, sericite and chlorite. Muscovite and sericite may be formed from feldspars and chlorite from biotite by alteration(including weathering). These rocks are relatively deteriorated by weathering, polluted water running the river and heavy traffic. The main phenomena of damages are surface exfoliation, grain separation, deceleration, pollution of organic and heavy chemical elements, cracks and breakage. These phenomena have been analyzed by polarized microscope, XRD and SEM/EDX. The analyzed results show organic pollution and secondarily formed gypsum and apatite on the rock surface and micro-pores. NaCl and $CaCO_3$ as rock salt and calcite probably may be formed secondarily in some points. Also heavy chemical elements such as Cr, Pb, Pd, W, La, Zn and Nd are polluted in some samples. The contacts between rocks are generally breakdown in small scale or cracks are developed due to mainly load and vibration shock of heavy traffic.

• Journal of Korean Society of Forest Science
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• v.101 no.3
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• pp.412-425
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• 2012

Concrete Soil Erosion Control Dam, which blocks flow of debris flow in torrential stream, are reported to lose expected functions due to structural failure and collapses, caused by poor construction, material deterioration and external impacts. In this paper, an integrity assessment technique for debris barriers was proposed, which allows preliminary detection of problems inherent in debris barriers. The proposed integrity assessment technique is a non-destructive method based on SASW method, one of surface-wave tests. In this paper, a practical procedure and analysis guidelines in applying the SASW technique to debris barrier was proposed and its validity was verified using five decrepit debris barriers older than 20-year old. As a result, the SASW method was validated for the reliable grade evaluation method for concrete soil erosion control dam, and the resulting grades turned out to agree with the results determined by Sabang Associations.

• Journal of Conservation Science
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• v.27 no.4
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• pp.357-369
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• 2011

The Bongamsa Jeongjindaesa Wonotap Pagoda (Treasure No. 171) constructed in the 10th century composed mainly of leucocratic granite with feldspar phenocryst. The major rock-forming minerals are quartz, orthoclase, plagioclase and some biotite. This pogoda is highly damaged physical weathering which are break-out, flakes, exfoliation and cracks. As a result of the infrared thermography on the surface of the pagoda, internal exfoliations occurred to cracks. Also, P-XRF analysis showed that Fe, S, Ca and Mn of concentration were so high in the discoloration parts. The coated part of red pigment has a high five times in Fe content than the fresh rock surface. This result suggests that material of red pigment is hematite. Ultrasonic velocity of the stone properties were from 831 to 2,457 m/s, but it measured velocity of less than 1,000m/s in part of damaged area. Therefore, we suggest for safety conservation for weathered parts of the pagoda, that is in want of rejoin and consolidation treatment about serious damage parts.