• Title/Summary/Keyword: Surface coverage

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원자층증착법을 이용한 Y2O3 박막 형성 및 저항 스위칭 특성

  • Jeong, Yong-Chan;Seong, Se-Jong;Lee, Myeong-Wan;Park, In-Seong;An, Jin-Ho;Rao, Venkateswara P.;Dussarrat, Christian;Noh, Wontae
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.08a
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    • pp.229.2-229.2
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    • 2013
  • Yttrium oxide (Y2O3)는 band gap이 5.5 eV 정도로 상대적으로 넓고, 굴절상수가 1.8, 유전율이 10~15, Silicon 과의 격자 불일치가 작은 특성을 가지고 있다. 또한 녹는점이 높아 열적으로 안정하기 때문에 전자소자 및 광학소자에 다양하게 응용되는 물질이다. Y2O3 박막은 다양한 방법으로 증착할 수 있는데, 그 방법에는 e-beam evaporation, laser ablation, sputtering, thermal oxidation, metal-organic chemical vapor deposition, and atomic layer deposition (ALD) 등이 있다. ALD는 기판 표면에 흡착된 원자들의 자기 제한적 반응에 의하여 박막이 증착되기 때문에 박막 두께조절이 용이하고 step coverage와 uniformity 측면에서 큰 장점이 있다. 이전에는 Y(thd)3 and Y(CH3Cp)3 와 같은 금속 전구체를 이용하여 ALD를 진행하여, 증착 속도가 낮고 defect이 많아 non-stoichiometric한 조성의 박막이 증착되는 문제점이 있었다. 이번 연구에서는, (iPrCp)2Y(iPr-amd)와 탈이온수를 사용하여 Y2O3 박막을 증착하였다. Y2O3 박막 증착에 사용한 Y 전구체는 상온에서 액체이고 $192^{\circ}C$ 에서 1 Torr의 높은 증기압을 갖는다. Y2O3 박막 증착을 위하여 Y 전구체는 $150^{\circ}C$ 로 가열하여 N2 gas를 이용하여 bubbling 방식으로 공정 챔버 내로 공급하였다. Y2O3 박막의 ALD window는 $250{\sim}350^{\circ}C$ 였으며, Y 전구체의 공급시간이 5초에 다다르자 더 이상 증착 두께가 증가하지 않는 자기 제한적 반응을 확인할 수 있었다. 그리고 증착된 Y2O3 박막의 특성 분석을 위해 Atomic force microscopy (AFM)과 X-ray photoelectron spectroscopy (XPS), Auger electron spectroscopy (AES) 를 진행하였다. 박막의 Surface morphology 는 매끄럽고 uniform 하였으며, 특히 고체 금속 전구체를 사용했을 때와 비교하여 수산화물이 거의 없는 박막을 얻을 수 있었다. 그리고 조성 분석을 통해 증착된 Y2O3 박막이 stoichiometric하다는 것을 알수 있었다. 또한 metal-insulator-metal (MIM) 구조 (Ru/Y2O3/Ru) 의 resistor 소자를 형성하여 저항 스위칭 특성을 확인하였다.

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Improvement of Vegetation Cooling Effects in BioCAS for Better Estimation of Daily Maximum Temperature during Heat Waves - In Case of the Seoul Metropolitan Area - (식생냉각효과 적용을 통한 BioCAS의 폭염기간 일 최고기온 추정 개선 - 서울 및 수도권지역을 중심으로 -)

  • Lee, Hankyung;Yi, Chaeyeon;Kim, Kyu Rang;Cho, Changbum
    • Atmosphere
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    • v.29 no.2
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    • pp.131-147
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    • 2019
  • On the urban scale, Micro-climate analysis models for urban scale have been developed to investigate the atmospheric characteristics in urban surface in detail and to predict the micro-climate change due to the changes in urban structure. BioCAS (Biometeorological Climate Impact Assessment System) is a system that combines such analysis models and has been implemented internally in the Korea Meteorological Administration. One of role in this system is the analysis of the health impact by heat waves in urban area. In this study, the vegetation cooling models A and B were developed and linked with BioCAS and evaluated by the temperature drop at the vegetation areas during ten selected heat-wave days. Smaller prediction errors were found as a result of applying the vegetation cooling models to the heat-wave days. In addition, it was found that the effects of the vegetation cooling models produced different results according to the distribution of vegetation area in land cover near each observation site - the improvement of the model performance on temperature analysis was different according to land use at each location. The model A was better fitted where the surrounding vegetation ratio was 50% or more, whereas the model B was better where the vegetation ratio was less than 50% (higher building and impervious areas). Through this study, it should be possible to select an appropriate vegetation cooling model according to its fraction coverage so that the temperature analysis around built-up areas would be improved.

Skin Dose Comparison of CyberKnife and Helical Tomotherapy for Head-and-Neck Stereotactic Body Radiotherapy

  • Yoon, Jeongmin;Park, Kwangwoo;Kim, Jin Sung;Kim, Yong Bae;Lee, Ho
    • Progress in Medical Physics
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    • v.30 no.1
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    • pp.1-6
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    • 2019
  • Purpose: This study conducts a comparative evaluation of the skin dose in CyberKnife (CK) and Helical Tomotherapy (HT) to predict the accurate dose of radiation and minimize skin burns in head-and-neck stereotactic body radiotherapy. Materials and Methods: Arbitrarily-defined planning target volume (PTV) close to the skin was drawn on the planning computed tomography acquired from a head-and-neck phantom with 19 optically stimulated luminescent dosimeters (OSLDs) attached to the surface (3 OSLDs were positioned at the skin close to PTV and 16 OSLDs were near sideburns and forehead, away from PTV). The calculation doses were obtained from the MultiPlan 5.1.2 treatment planning system using raytracing (RT), finite size pencil beam (FSPB), and Monte Carlo (MC) algorithms for CK. For HT, the skin dose was estimated via convolution superposition (CS) algorithm from the Tomotherapy planning station 5.0.2.5. The prescribed dose was 8 Gy for 95% coverage of the PTV. Results and Conclusions: The mean differences between calculation and measurement values were $-1.2{\pm}3.1%$, $2.5{\pm}7.9%$, $-2.8{\pm}3.8%$, $-6.6{\pm}8.8%$, and $-1.4{\pm}1.8%$ in CS, RT, RT with contour correction (CC), FSPB, and MC, respectively. FSPB showed a dose error comparable to RT. CS and RT with CC led to a small error as compared to FSPB and RT. Considering OSLDs close to PTV, MC minimized the uncertainty of skin dose as compared to other algorithms.

Interrelationship between Paleovegetation in Southern and Central California and Northeast Pacific Atmospheric and Oceanographic Processes over the Last ~30 kyr (과거 3만년 동안 캘리포니아 남부와 중부지역의 고식생 변화와 북동태평양 대기 및 해양순환 변동과의 연관성 연구)

  • Suh, Yeon Jee
    • Ocean and Polar Research
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    • v.41 no.3
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    • pp.159-168
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    • 2019
  • Understanding the interaction between climate and the water cycle is critical especially in a drought sensitive region such as California. This study explored hydrologic changes in central and southern California in relation to the glacial-interglacial climate cycles over the last 30 thousand years. To do this, we reconstructed paleovegetation using plant wax carbon isotopic compositions (${\delta}^{13}C$) preserved in marine sediment cores retrieved from the central California continental shelf (ODP Site 1018) and Santa Barbara Basin (ODP Site 893A). The results were then compared to the existing sea surface temperature (SST) and pollen records from the same cores to understand terrestrial hydrology in relation to oceanographic processes. The Last Glacial was generally dry both in central and southern California, indicated by grassland expansion, confirming the previously suggested notion that the westerly storm track that supplies the majority of the precipitation in California may not have moved southward during the glacial period. Southern California was drier than central California during the Last Glacial Maximum (LGM). This drying trend may have been associated with the weakening of the California Current and northerly winds leading to the early increase in SST in southern California and decline in both offshore and coastal upwelling. The climate was wetter during the Holocene in both regions compared to the glacial period and forest coverage increased accordingly. We attribute this wetter condition to the precipitation contribution increase from the tropics. Overall, we found a clear synchronicity between the terrestrial and marine environment which showed that the terrestrial vegetation composition in California is greatly affected by not only the global climate states but also regional oceanographic and atmospheric conditions that regulate the timing and amount of precipitation over California.

Succession and Stand Dimension Attributes of Pinus thunbergii Coastal Forests after Damage from Diplodia Tip Blight around the Sakurajima Volcano, Southern Kyushu, Japan

  • Teramoto, Yukiyoshi;Shimokawa, Etsuro;Ezaki, Tsugio;Jang, Su-Jin;Kim, Suk-Woo;Lee, Youn-Tae;Chun, Kun-Woo
    • Journal of Forest and Environmental Science
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    • v.34 no.6
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    • pp.481-489
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    • 2018
  • In this study, the succession and stand dimension attributes related to the disaster prevention function of Pinus thunbergii coastal forests were examined after damage from Diplodia tip blight. In 2015, 101 years after the Taisho eruption, field investigations were performed on the vegetation, soil thickness, and pH of surface soil of P. thunbergii coastal forests in western Sakurajima (Hakamagoshi plot) and Taisho lava flows in southeastern Sakurajima (Seto plot). The Hakamagoshi plot had more woody plant species with larger basal areas than that in the Seto plot. The mean age and height, maximal age and height of plant species, and H/D ratio were all larger in the Hakamagoshi plot than in the Seto plot. These results may be explained by the relatively smaller effect of volcanic ash and gas on forests in the Hakamagoshi plot compared to the Seto plot, resulting in a more suitable environment for many plant species. Although P. thunbergii coastal forests in Sakurajima are currently recovering from damages owing to Diplodia tip blight, there has not yet been a sufficient recovery compared to the results from a 1997 study. Furthermore, the results of assessment based on the H/D ratio and abundance of trees in P. thunbergii forests indicate that both regions are not yet effective in disaster prevention. Thus, it is necessary to establish Pinus trees, which can adjust to harsh environments like coastal areas and are resistant to volcanic ash and gas, to enhance the disaster prevention function of P. thunbergii coastal forests in volcanic regions. It may also be helpful to establish coastal forests with ectotrophic mycorrhizal fungi and organic matter coverage. Additionally, it is necessary to ensure the continuous maintenance of stand density and soil quality, and further develop efforts to prevent Diplodia tip blight and promote forest recovery.

Study on Isotherm, Kinetic and Thermodynamic Parameters for Adsorption of Methyl Green Using Activated Carbon (활성탄을 이용한 메틸 그린 흡착에 있어서 등온선, 동력학 및 열역학 파라미터에 대한 연구)

  • Lee, Jong Jib
    • Applied Chemistry for Engineering
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    • v.30 no.2
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    • pp.190-197
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    • 2019
  • The adsorption of methyl green dye using an activated carbon from an aqueous solution was investigated. Adsorption experiments were carried out as a function of the adsorbent dose, initial concentration, contact time and temperature. The Langmuir isotherm model showed a good fit to the equilibrium adsorption data. Based on the estimated Langmuir separation factor, ($R_L=0.02{\sim}0.106$), this process could be employed as the effective treatment (0 < $R_L$ < 1). It was found that the adsorption was a physical process with the adsorption energy (E) value range between 316.869 and 340.049 J/mol obtained using Dubinin-Radushkevich equation. The isothermal saturation capacity obtained from brunauer emmett teller (BET) model increased with increasing the temperature. The kinetics of adsorption followed a pseudo second order model. The free energy and enthalphy values of -5.421~-7.889 and 31.915 kJ/mol, respectively indicated that the adsorption process follows spontaneous endothermic reaction. The isosteric heat of adsorption increased with the increase of equilibrium adsorption amounts, and the total interaction of the adsorbent - adsorbate increased as the surface coverage increased.

Accuracy of Bite Registration Using Intraoral Scanner Based on Data Trimming Strategy for Fremitus Teeth

  • Jeong, Yuwon;Shim, June-Sung;Kim, Jee-Hwan;Kim, Jong-Eun;Lee, Hyeonjong
    • Journal of Korean Dental Science
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    • v.15 no.1
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    • pp.61-67
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    • 2022
  • Purpose: This study aimed to evaluate the accuracy of bite registration using intraoral scanner based on data trimming strategy for fremitus teeth. Materials and Methods: A reference model was designed by Medit Model Builder software (MEDIT Corp., Seoul). Tooth number 24 and 25 were separated as dies and tooth number 26 was prepared for full-coverage crown. Those were printed using a 3D printer (NextDent 5100). The scanning procedure was performed by a single trained operator with one intraoral scanner (i700; MEDIT Corp.). The scanning groups were divided as follows: group 1 (G1), no fremitus; group 2 (G2), 0.5 mm buccal fremitus in the maxillary left first and second premolar; and group 3 (G3), 1.5 mm buccal fremitus in the maxillary left first and second premolar. Each group was scanned 10 times and were analyzed using the reference model data. Surface-based occlusal clearance was analyzed at the prepared tooth to evaluate accuracy. Result: Mean values of control group (G1) were 1.587±0.021 mm. G2 showed similar values to those from the control group (1.580±0.024 mm before trimming strategy and 1.588±0.052 mm after trimming strategy). G3 showed significantly greater values (1.627±0.025 mm before trimming strategy and 1.590±0.024 mm after trimming strategy) and the differences were found between trimming strategy (P=0.004). Conclusion: Bite trimming strategy for fremitus teeth is a reliable technique to reduce inaccuracies caused by the mobility at maximum intercuspation.

Galaxy Group Assembly Histories and the Missing Satellites Problem: A Case for the NGC 4437 Group

  • Kim, Yoo Jung;Lee, Myung Gyoon
    • The Bulletin of The Korean Astronomical Society
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    • v.46 no.1
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    • pp.33.1-33.1
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    • 2021
  • The overprediction of the number of satellite galaxies in the LCDM paradigm compared to that of the Milky Way (MW) and M31 (the "missing satellites" problem) has been a long-standing issue. Recently, a large host-to-host scatter of satellite populations has been recognized both from an observational perspective with a larger sample and from a theoretical perspective including baryons, and it is crucial to collect diverse and complete samples with a large survey coverage to investigate underlying factors contributing to the diversity. In this study, we discuss the diversity in terms of galaxy assembly history, using satellite populations of both observed systems and simulated systems from IllustrisTNG. In addition to previously studied satellite systems, we identify satellite candidates from 25deg2 of Hyper Suprime-Cam Subaru Strategic Program (HSC-SSP) Wide layer around NGC 4437, a spiral galaxy of about one-fourth of the MW mass, paired with a ~2 magnitude fainter dwarf spiral galaxy NGC 4592. Using the surface brightness fluctuations (SBF) method, we confirm five dwarf galaxies as members of the NGC 4437 group, resulting in a total of seven members. The group consists of two distinct subgroups, the NGC 4437 subgroup and the NGC 4592 subgroup, which resembles the relationship between the MW and M31. The number of satellites is larger than that of other observed and simulated galaxy groups in the same host stellar mass range. However, the discrepancy decreases if compared with galaxy groups with similar magnitude gaps (V12 ~ 2), defined as the V-band magnitude difference between the two brightest galaxies in the group. Using simulated galaxy groups in IllustrisTNG, we find that groups with smaller V12 have richer satellite systems, host more massive dark matter halos, and have assembled more recently. These results show that the host-to-host scatter of satellite populations can be attributed to the diversity in galaxy assembly history and be probed by V12 to some degree and that NGC 4437 group is likely a recently assembled galaxy group with a large halo mass compared to galaxy groups of similar luminosity.

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A Study on the Orphism Expression Effect in Contemporary Fashion (현대 패션에 표현된 오르피즘 특성)

  • Jin Kwon
    • Journal of the Korea Fashion and Costume Design Association
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    • v.25 no.3
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    • pp.97-111
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    • 2023
  • Dynamic orphism images expressed with abstraction and construction in color are often found in modern fashion. Orphism stressing color is one of the many art trends that influence fashion. This work aims to examin its expressive effects and characteristics that appear in fashion and provide basic materials for fashion design study. This study proceeds with the following steps. First, the study takes on a theoretical examination of the orphism trend using a literature review. Second, based on its results, modern fashion's expressive features influenced by orphism are analyzed. Third, the study draws expression effects in modern fashion from these characteristics. The study coverage is confined to domestic and foreign collections released in the 21st century. The study contents come from an Internet-base domestic and international database and published material, including dissertations and books. Orphism expression effects are found in the following ways in modern fashion. First, it lies in the abstraction effect of color. This feature arrays flat geometric figure on the clothing surface and applies a strong sense of color inside it, as if color has an abstractive structured design. Second, it gives a dynamic sense visually to the clothes all at once by stressing the relation among and between the colors with powerful contrast. Third, it has a collage effect of color. This effect develops into an organic combination composed of geometric plane figures with intense complementary colors in a single piece of clothing. Expression types that presents the orphism effect in fashion are divided into clothing showing traditional orphism characteristics faithfully and clothing expressing conventional orphism characteristics mixed with modern trends. Further developed orphism fashion can be classified by the playful type, with graffiti added onto an orphism color structure, and the destructive type, where traditional orphism color orders are taken apart and reformed into a new color order.

Quantifying the 2022 Extreme Drought Using Global Grid-Based Satellite Rainfall Products (전지구 강수관측위성 기반 격자형 강우자료를 활용한 2022년 국내 가뭄 분석)

  • Mun, Young-Sik;Nam, Won-Ho;Jeon, Min-Gi;Lee, Kwang-Ya;Do, Jong-Won;Isaya Kisekka
    • Journal of The Korean Society of Agricultural Engineers
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    • v.66 no.4
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    • pp.41-50
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    • 2024
  • Precipitation is an important component of the hydrological cycle and a key input parameter for many applications in hydrology, climatology, meteorology, and weather forecasting research. Grid-based satellite rainfall products with wide spatial coverage and easy accessibility are well recognized as a supplement to ground-based observations for various hydrological applications. The error properties of satellite rainfall products vary as a function of rainfall intensity, climate region, altitude, and land surface conditions. Therefore, this study aims to evaluate the commonly used new global grid-based satellite rainfall product, Climate Hazards Group InfraRed Precipitation with Station data (CHIRPS), using data collected at different spatial and temporal scales. Additionally, in this study, grid-based CHIRPS satellite precipitation data were used to evaluate the 2022 extreme drought. CHIRPS provides high-resolution precipitation data at 5 km and offers reliable global data through the correction of ground-based observations. A frequency analysis was performed to determine the precipitation deficit in 2022. As a result of comparing droughts in 2015, 2017, and 2022, it was found that May 2022 had a drought frequency of more than 500 years. The 1-month SPI in May 2022 indicated a severe drought with an average value of -1.8, while the 3-month SPI showed a moderate drought with an average value of 0.6. The extreme drought experienced in South Korea in 2022 was evident in the 1-month SPI. Both CHIRPS precipitation data and observations from weather stations depicted similar trends. Based on these results, it is concluded that CHIRPS can be used as fundamental data for drought evaluation and monitoring in unmeasured areas of precipitation.