• Title/Summary/Keyword: Surface contact

Search Result 4,575, Processing Time 0.025 seconds

Surface Modification of PET Irradiated by Ultra-Violet (Part I) -Transformation of Chemical Structure and Surface Properties- (UV조사를 통한 PET의 표면개질 (제1보) -화학구조 변화 및 표면특성 변화-)

  • Choi Hae Young;Lee Jung Soon
    • Journal of the Korean Society of Clothing and Textiles
    • /
    • v.29 no.3_4 s.141
    • /
    • pp.561-568
    • /
    • 2005
  • The irradiation of Ultra-Violet (UV) is an efficient treatment for polymer to improve hydrophilic properties. 4-Channel PET knit fabrics were treated with UVA and UVC to develop functional and environment-friendly fabric. The fabric was treated with various treatment times and distances from UV lamps having different wavelength. FT-IR and XPS investigated the chemical changes. To confirm the change of surface properties, contact angle, surface energy and SEM were examined. The study of UV as a treatment for PET knit fabric shows significant changes in chemical and surface properties, which is proved by analyses. FT-IR and XPS analyses prove the augmentation of carboxylic, Hydrophilic groups on the surfaces treated by UV. The increase of water contact angle and surface energy means more water wettable and surface energy of PET film was substantially increased by UV irradiation time. The ageing after surface treatment had little influence on the surface energy of the irradiated PET film. SEM proves the surface modification of PET such as etching, bubble and crack. The negative effects are increased in accordance with increasing treatment time.

Effects of Water Treating on Surface Properties of Epoxy Insulation Materials (Epoxy 절연재료이 표면특성에 미치는 수분처리의 영향)

  • Lim, Kyung-Bum;Lee, Duck-Chool
    • The Transactions of the Korean Institute of Electrical Engineers C
    • /
    • v.49 no.10
    • /
    • pp.553-558
    • /
    • 2000
  • This paper deals with change of contact angle, surface potential decay, surface resistivity and XPS of water-treated epoxy insulator. From the experimental results on the contact angle was reduced from $74^{\circ}$to $24^{\circ}$ due to the formation of polar hydroxyl groups on surface which was associated with intermolecular reaction between epoxy chains of three-dimensional network structure and water molecules. From the experimental results in the surface potential decay of water treated-samples, it was found that the accumulation of charge is decreased and the surface potential decay time is shortened by the interaction of polar hydroxyl groups induced on the treated surface as the increment of treatment time. The positive charging on the treated surface compared with negative charging is relatively lowered by the induction of polar hydroxyl groups. The surface resistivity was changed from $10^{15}[{\Omega}/cm^2$] to $10^{12}[{\Omega}/cm^2$] caused by water treatment. From XPS, it was found that the changes affected by the surface degradation of epoxy were caused by the generation of carboxyl groups through the chain decomposition and recombination with oxygen molecules in the air.

  • PDF

Bleaching Observation of Cosmetic Color Lenses According to Multipurpose Contact Lens Solutions (다목적 콘택트렌즈 용액에 대한 미용 칼라렌즈의 탈색 관찰)

  • Kim, Hyojin
    • Journal of Korean Ophthalmic Optics Society
    • /
    • v.19 no.3
    • /
    • pp.295-303
    • /
    • 2014
  • Purpose: This study aims to observe bleaching resulted from multipurpose contact lens solutions used to manage lenses with the subjects of colored contact lenses being distributed in Korea. Methods: The lenses have been worn for six months, and their refraction is 0.00D. Three types of colored contact lenses of which margin has been colored with a different manufacturing method have been adopted (type 1: pigment application method, type 2: chemical bonding process, type 3: sandwich method), and multipurpose solutions used were two types containing different components. Each of the colored contact lenses was stored in the multipurpose solutions for 20 days and went through vortexing for 15 seconds per day. Their fluorescence absorbance, surface roughness, brightness index, and color coordinate index were measured before and after the vortexing to see the degree of bleaching. Results: In the two types of multipurpose solutions, every type of the color contact lenses showed no statistically significant difference in their fluorescence absorbance value before and after the vortexing. Regarding surface image, the front surface of the lenses was smooth in every type, and about the back surface, type 3 indicated less protrusion than type 1 and 2. About the difference of color on the lens surface before and after the vortexing, type 3 showed significantly less difference than type 1 and 2; however, all fell into the permissible error. Conclusions: About the bleaching of colored contact lenses resulted from multipurpose solutions for soft contact lenses, there was no difference observed in terms of fluorescence absorbance and color. According to the methods of manufacturing dyes, however, there was difference in the protrusion of the posterior surface image.

Determination of Surface Energy by Means of Home-Made Goniometer and Image Analyzing Software for Contact Angle Measurement (수제 접촉각 측정기와 영상 분석 프로그램을 이용한 표면에너지의 측정)

  • Cho, Seo-Rin;Cho, Han-Gook
    • Journal of the Korean Chemical Society
    • /
    • v.57 no.4
    • /
    • pp.432-438
    • /
    • 2013
  • We report a contact angle goniometer that can be easily assembled and used in high school and general chemistry experiments. It consists of an LED flash, a sample stand, and a camera fixed on an optical bread board, and the sample area is covered to block light from outside with a box with holes on both sides. ImageJ, free image analyzing software and a JAVA plugin (Drop_analysis) were used to determine the contact angle of liquid drop resting on solid surface. The contact angles of various liquids were successfully measured on various surfaces. The solid surface energies have also been determined using the Owen-Wendt method from the contact angles of $H_2O$ and $CH_2I_2$. The results reasonably agree with the previously reported values, showing the surface characteristics and modification as well as the dispersive and polar contributions. These contact angle goniometer and method for determination of the contact angle and surface energy can be applied to observation of various surface properties including wettability, hydrophilicity, and water repelling. Students can learn how the surface properties are related to the intermolecular interactions and gain experience about the equilibrium between the related forces, optics, and mathematical derivations.

FE Analysis on Stress and Deformation Behaviors of Elastomeric Contact Seals for a Pipe (배관용 탄성접촉시일의 응력 및 변형거동에 관한 유한요소해석)

  • Kim, Chung-Kyun;Kim, Tae-Hwan
    • Journal of the Korean Institute of Gas
    • /
    • v.15 no.6
    • /
    • pp.34-37
    • /
    • 2011
  • This paper presents sealing contact stress and deformation behaviors of an elastomeric contact seal for a pipe connection. In this study, a pipe connection is used by a joint nut and an elastomeric contact seal with a sealing interference of 0.2~0.5mm. A sealing interference in which compresses an elastomeric contact seal is generated by fastening a joint nut between two pipes. The FEM computed results show that the contact normal stress of contact model 1 with an inclined sealing surface is 1.5~1.75 times high in compared with that of contact model 2 with a parallel sealing surface. This indicates that the sealing contact surface recommends a wedge contact mode between two pipe connections for a high sealing compression stress.

The Scanning Electron Microscopic study on the effect during subgingival calculus removal using Nd:YAG laser (치은연하치석제거술시 Nd : YAG 레이저를 이용한 효과에 관한 주사전자현미경적 연구)

  • Jeon, Yong-Seon;Choi, Byung-Son;Lee, Seok-Cho;Kim, Hyung-Seop
    • Journal of Periodontal and Implant Science
    • /
    • v.27 no.2
    • /
    • pp.411-424
    • /
    • 1997
  • The purpose of this study was to evaluate in vitro the effects during subgingival calculus removal using Nd:YAG laser. The study group was consisted of 30 teeth with advanced periodontal disease extracted before the start of periodontal therapy. The specimens were divided into 8 different groups : 1) untreated control 2) scaling and root planing only 3) laser treated using 150mJ/pulse, 1sec, 5sec, contact mode 4) laser treated using 200mJ/pulse, 5sec, contact mode 5) laser treated using 150mJ/pulse, 1sec, non-contact mode 6) laser treated using 200mJ/pulse, 5sec, non-contact mode 7) laser treated using l5OmJ/pulse, 1sec, contact mode with water irrigation 8) laser treated using 200mJ/pulse, 5sec, contact mode with water irrigation. All specimens were prepared for evaluation by scanning electron microscopy(SEM). Specimens from Group 2 exhibited a smear layer of scale like texture with parallel instrument tracks resulting from curet use. Specimens treated by contact mode, Group 3 and 4 featured surface changes not observed· in controls such as charring, randomly distributed pitting and crater formation, and melting down of the tooth material and calculus. Specimens treated by noncontact mode, Group 5 and 6 featured similar surface changes observed in contact mode. However, the differences between contact and non-contact groups not significant. Specimens treated by contact mode with water irrigation, Group 7 and 8 featured slight surface change compared to other groups. The results suggested that Nd: YAG laser did not completely remove the subgingival calculus but was possible the application as adjunctive method.

  • PDF

Understanding of Protein Adsorption to Contact Lens Hydrogels with Varying Surface Energy (콘택트렌즈용 하이드로젤 계면에너지에 따른 단백질 흡착현상의 이해)

  • Jeon, So-Ha;Noh, Hye-Ran
    • Polymer(Korea)
    • /
    • v.36 no.3
    • /
    • pp.338-343
    • /
    • 2012
  • Interfacial properties of commercially available soft contact lens hydrogels were studied to understand thermodynamic phenomena of protein adsorption. Hydrogel particles ($1{\times}1mm^2$) with varying water wettability were exposed to bovine serum albumin solutions for an hour. The remained albumin solutions were analyzed with Bradford assay method. The amount of protein adsorbed to hydrogels increased with protein solution concentrations following Langmuir isotherm. The partition coefficient ($P$) and Gibbs free energy cost of dehydrating the surface region by protein displacement upon adsorption increased with increasing hydrophilicity of contact lens. Understanding of physical chemistry in protein adsorption to contact lens materials enabled elucidating relationships between surface energy and albumin adsorption capacity.

Forming Characteristics for the Bundle Extrusion of Cu-Ti Bimetal Wires (구리-타이타늄 복합선재의 번들압출 성형특성)

  • Lee, Y.S.;Kim, J.S.;Yoon, S.H.;Lee, H.Y.
    • Transactions of Materials Processing
    • /
    • v.18 no.4
    • /
    • pp.342-346
    • /
    • 2009
  • Forming characteristics for the bundle extrusion of Cu-Ti bimetal wires are investigated, which can identify the process conditions for weak mechanical bonding at the contact surface during the direct extrusion of a Cu-Ti bimetal wire bundle. Bonding mechanism between Cu and Ti is assumed as a cold pressure welding. Then, the plastic deformation at the contact zone causes mechanical bonding and a new bonding criterion for pressure welding is developed as a function of the principal stretch ratio and normal pressure at the contact surface by analyzing micro local extrusion at the contact zone. The averaged deformation behavior of Cu-Ti bimetal wire is adopted as a constitutive behavior at a material point in the finite element analysis of Cu-Ti wire bundle extrusion. Various process conditions for bundle extrusions are examined. The deformation histories at the three points, near the surface, in the middle and near the center, in the cross section of a bundle are traced and the proposed new bonding criterion is applied to predict whether the mechanical bonding at the Cu-Ti contact surface happens. Finally, a process map for the direct extrusion of Cu-Ti bimetal wire bundle is proposed.

Characterization of Fluorocarbon Thin Films by Contact Angle Measurements and AFM/LFM (접촉각 측정과 AFM/LFM을 이용한 불화 유기박막의 특성 평가)

  • 김준성;차남구;이강국;박진구;신형재
    • Journal of the Microelectronics and Packaging Society
    • /
    • v.7 no.1
    • /
    • pp.35-40
    • /
    • 2000
  • Teflon-like fluorocarbon thin film was deposited on various substrates by vapor deposition using PFDA (perfluorodecanoic acid). The fluorocarbon films were characterized by static/dynamic contact angle analysis, VASE (Variable-angle Spectroscopic Ellipsometry) and AFM/LFM (Atomic/Lateral Force Microscopy). Based on Lewis Acid/Base theory, the surface energy ($S_{E}$) of the films was calculated by the static contact angle measurement. The work of adhesion (WA) between de-ionized water and substrates was calculated by using the static contact data. The fluorocarbon films showed very similar values of the surface energy and work of adhesion to Teflon. All films showed larger hysteresis than that of Teflon. The roughness and relative friction force of films were measured by AFM and LFM. Even though the small reduction of surface roughness was found on film on $SiO_2$surface, the large reduction of relative friction farce was observed on all films. Especially the relative friction force on TEOS was decreased a quarter after film deposition. LFM images showed the formation of "strand-like"spheres on films that might be the reason far the large contact angle hysteresis.

  • PDF

Development of A Process Map for Bundle Extrusion of Cu- Ti Bimetal Wires (구리-타이타늄 이중미세선재 번들압출의 공정지도 개발)

  • Kim J. S.;Lee Y. S.;Yoon S. H.
    • Proceedings of the Korean Society for Technology of Plasticity Conference
    • /
    • 2005.10a
    • /
    • pp.393-397
    • /
    • 2005
  • A process map has been developed, which can identify the process conditions for weak mechanical bonding at the contact surface during the direct extrusion of a Cu-Ti bimetal wire bundle. Bonding mechanism between Cu and Ti is assumed as a cold pressure welding. Then, the plastic deformation at the contact zone causes mechanical bonding and a new bonding criterion fur pressure welding is developed as a function of the principal stretch ratio and normal pressure at the contact surface by analyzing micro local extrusion at the contact zone. The averaged deformation behavior of Cu-Ti bimetal wire is adopted as a constitutive behavior at a material point in the finite element analysis of Cu-Ti wire bundle extrusion. Various process conditions for bundle extrusions are examined. The deformation histories at the three points, near the surface, in the middle and near the center, in the cross section of a bundle are traced and the proposed new bonding criterion is applied to predict whether the mechanical bonding at the Cu-Ti contact surface happens. Finally, a process map for the direct extrusion of Cu-Ti bimetal wire bundle is proposed.

  • PDF