• Title/Summary/Keyword: Surface and Internal Defects

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Interface structure and anisotropic strain relaxation of nonpolar a-GaN on r-sapphire

  • 공보현;조형균;송근만;윤대호
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2010년도 하계학술대회 논문집
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    • pp.31-31
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    • 2010
  • The growth of the high-quality GaN epilayers is of significant technological importance because of their commercializedoptoelectronic applications as high-brightness light-emitting diodes (LEDs) and laser diodes (LDs) in the visible and ultraviolet spectral range. The GaN-based heterostructural epilayers have the polar c-axis of the hexagonal structure perpendicular to the interfaces of the active layers. The Ga and N atoms in the c-GaN are alternatively stacked along the polar [0001] crystallographic direction, which leads to spontaneous polarization. In addition, in the InGaN/GaN MQWs, the stress applied along the same axis contributes topiezoelectric polarization, and thus the total polarization is determined as the sum of spontaneous and piezoelectric polarizations. The total polarization in the c-GaN heterolayers, which can generate internal fields and spatial separation of the electron and hole wave functions and consequently a decrease of efficiency and peak shift. One of the possible solutions to eliminate these undesirable effects is to grow GaN-based epilayers in nonpolar orientations. The polarization effects in the GaN are eliminated by growing the films along the nonpolar [$11\bar{2}0$] ($\alpha$-GaN) or [$1\bar{1}00$] (m-GaN) orientation. Although the use of the nonpolar epilayers in wurtzite structure clearly removes the polarization matters, however, it induces another problem related to the formation of a high density of planar defects. The large lattice mismatch between sapphiresubstrates and GaN layers leads to a high density of defects (dislocations and stacking faults). The dominant defects observed in the GaN epilayers with wurtzite structure are one-dimensional (1D) dislocations and two-dimensional (2D) stacking faults. In particular, the 1D threading dislocations in the c-GaN are generated from the film/substrate interface due to their large lattice and thermal coefficient mismatch. However, because the c-GaN epilayers were grown along the normal direction to the basal slip planes, the generation of basal stacking faults (BSFs) is localized on the c-plane and the generated BSFs did not propagate into the surface during the growth. Thus, the primary defects in the c-GaN epilayers are 1D threading dislocations. Occasionally, the particular planar defects such as prismatic stacking faults (PSFs) and inversion domain boundaries are observed. However, since the basal slip planes in the $\alpha$-GaN are parallel to the growth direction unlike c-GaN, the BSFs with lower formation energy can be easily formed along the growth direction, where the BSFs propagate straightly into the surface. Consequently, the lattice mismatch between film and substrate in $\alpha$-GaN epilayers is mainly relaxed through the formation of BSFs. These 2D planar defects are placed along only one direction in the cross-sectional view. Thus, the nonpolar $\alpha$-GaN films have different atomic arrangements along the two orthogonal directions ($[0001]_{GaN}$ and $[\bar{1}100]_{GaN}$ axes) on the $\alpha$-plane, which are expected to induce anisotropic biaxial strain. In this study, the anisotropic strain relaxation behaviors in the nonpolar $\alpha$-GaN epilayers grown on ($1\bar{1}02$) r-plane sapphire substrates by metalorganic chemical vapor deposition (MOCVO) were investigated, and the formation mechanism of the abnormal zigzag shape PSFs was discussed using high-resolution transmission electron microscope (HRTEM).

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콘크리트 발수제용 Silane의 유화 (The Emulsification of Silane as Water REpellent for Concrete)

  • 황인동;염희남;정윤중
    • 한국세라믹학회지
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    • 제37권8호
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    • pp.760-767
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    • 2000
  • Recently, the protection of construction is demanded with environmental pollution. These protect modes are use of concrete admixture, coat of protective polymer and impregnate of surface with chemicals etc. The most widely used impregnation is economical and effective. The define of Impregnation for construction protect is reacted in and consolidated substrate after absorbed. The impregnation agents are Polyesters, Acrylic monomers, Epoxy and Silicone derivatives. Commonly, because the Silane has good water repellency and environmental advantages that it widely used to water proofing agents, dampproofing agents and absorption reducer for concrete of bridges. When application of Silane, it occurs pollution and harmfulness as included organic solvent. The manufactures have tired to emulsification of Silane for the reducing of the defects. The Silane emulsion is vary unstable and does not stored long periods, and it is diminished in good properties with internal reaction. In this study we tried to emulsification of Silane for effectiveness improvement and reduce pollution and hazard and discussed properties variation of emulsion. The Silane emulsions are achieved emulsifying with W/O and O/W type surfactants. It used 0.24% PVA as protective colloid and stable phase is creamy. The creamy Silane emulsion performance as the penetration depth and water absorption rate are above 4 mm and below 0.1. It stable about 6 month at room temperature.

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쌍롤 박판주조법으로 제조된 Al-5.5Mg-0.02Ti합금의 미세조직 및 기계적 특성 (Microstructure and Mechanical Properties of Twin-Roll Strip-Cast Al-5.5Mg-0.02Ti Alloy Sheet)

  • 천부현;한준현;김형욱;이재철
    • 대한금속재료학회지
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    • 제48권5호
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    • pp.387-393
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    • 2010
  • High-strength aluminum alloy sheets with high magnesium contents were fabricated by a strip caster equipped with an asymmetric nozzle, which has been proven to be effective for reducing surface defects and internal segregation. 4 mm thick as-cast sheets consisting of fine dendrites and minor $Al_{8}Mg_{5}$ segregation were hot-rolled successfully to 1 mm sheets and subsequently annealed at various temperatures. The sheet revealed the tensile strength and elongation of 306 MPa and 34%, respectively, when it was rolled at 250${^{\circ}C}$ and subsequently annealed at 475${^{\circ}C}$, which exhibits the feasibility of the practical application for autobodies. The observed mechanical properties were explained on the basis of the microstructural characteristics of the alloy sheets.

베어링메탈 제조공정에 따른 결함발생 및 피로균열 전파특성 (Properties of Defect Initiation and Fatigue Crack Growth in Manufacturing Process of Bearing Metal)

  • 김민건
    • 산업기술연구
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    • 제35권
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    • pp.3-8
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    • 2015
  • A study has been made on defects which are formed in manufacturing processes of engine bearing and also on fatigue crack growth behavior in each step of bearing metal manufacturing. After the first step(sinter brass powder on steel plate ; Series A) many voids are made on brass surface and its size is decreased by the second step(rolling process of sintered plate ; Series B). After the third step(re-sintering step of brass powder and rolling ; Series C) the number of voids is decreased and its type shows line. The time of fatigue crack initiation and the growth rate of fatigue crack are in order of Series A, Series B, Series C. These reasons are that void fosters the crack initiation and growth, and residual stress made by rolling process effects on the crack growth rate in Series B, C. In forming and machining processes by use of final bearing metal, crack was observed at internal corner of flange and peeling off was observed at junction between steel and brass. Owing to the above crack and peeling off, it is considered that there is a possibility of fatigue fracture during the application time.

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제조 공정에 따른 베어링메탈의 결함발생 및 피로파괴거동 (Defect Genesis and Fatigue Failure Behaviour of Bearing Metal in Manufacturing Processes)

  • 김민건
    • 산업기술연구
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    • 제31권A호
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    • pp.45-51
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    • 2011
  • A study has been made on defects which are formed in manufacturing processes of engine bearing and also on fatigue crack growth behavior in each step of bearing metal manufacturing. After the first step (sinter brass powder on steel plate ; Series A) many voids are made on brass surface and its size is decreased at the second step (rolling process of sintered plate ; Series B). After the third step (re-sintering step of brass powder and rolling ; Series C) the number of voids is decreased and its type shows line. The time of fatigue crack initiation and the growth rate of fatigue crack are in order of Series A, Series B, Series C. These reasons are that void fosters the crack initiation and growth, and residual stress made by rolling process affects on the crack growth rate in Series B, C. In forming and machining processes by use of final bearing metal, crack was observed at internal corner of flange and peeling off was observed at interface between steel and brass. Owing to the above crack and peeling off, it is considered that there is a possibility of fatigue fracture during the application time.

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차체 제작을 위한 레이저용접 마그네슘 TWB 판넬 (MAGNESIUM TWB PANEL WITH LASER WELDING FOR AUTO BODY ASSEMBLY)

  • 이목영;장웅성;윤병현
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2007년도 춘계학술대회A
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    • pp.1312-1316
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    • 2007
  • Strip casted and rolled magnesium sheet is become exiting material for car manufacturer, due to its better formability and specific strength compare with conventional extruded sheet. TWB technology was attractive for car body designer, because it saves the weight of the car without strength loss. In this study, the laser welding performance of magnesium sheet was investigated for Mg TWB panel manufacturing. The material was strip casted and rolled magnesium alloy sheet contains 3 wt% Al and 1 wt% Zn (AZ31). Lamp pumped Nd:YAG laser of 2kW was used and its laser light was delivered by optical fiber of 0.6mm core diameter to material surface with focusing optics of 200mm focal length for TWB welding. The microstructure of weld bead was investigated to check internal defects such as inclusion, porosity and cracks. Also mechanical properties and formability were evaluated for press forming of car body. For the results, there was no crack but inclusion or porosity on weld at some conditions.The tensile strength of weld was over 95% of base metal. Inner and outer panel of engine hood were press formed and assembled at elevated temperature.

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PD Occurrence Characteristics according to Voltage and Time in Solid Insulator

  • Park, Sung-Hee;Shin, Dal-Woo;Lim, Kee-Joe;Park, Young-Guk;Kang, Sung-Hwa
    • KIEE International Transactions on Electrophysics and Applications
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    • 제3C권1호
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    • pp.10-14
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    • 2003
  • The occurrence of partial discharge (PD) in solid dielectrics is very harmful because it leads to the deterioration of insulation by electrical, chemical, and thermal reactions as a combined action of the discharged ions bombarding the surface and by the action of chemical compounds that are formed by the discharge. Consequently, if any defects are present in the solid insulation system, performance decreases until the system breaks down. Therefore, removing or suppressing the defect is very important. Voids are a typical defect in the solid insulation system and are very harmful because they deteriorate insulation. As a basic step, studying the properties of PD in voids is important because an accurate knowledge of these properties is required to estimate the deterioration of voids. In this paper, the correlation between the size of voids and internal PD is discussed as a function of the time of the applied voltage and its magnitude. Magnitude, repetition rate, average discharge power, and average discharge current of PD in specimens with large voids were found to be larger than the others in this experiment. The smaller specimens had voids when the magnitude and number of PDs were reduced.

고압전동기 고정자 권선의 PRPD 부분방전 결함신호 해석 (Analysis on Partial Discharge Fault Signals of PRPD for High Voltage Motor Stator Winding)

  • 박재준;이성룡;문대철
    • 한국전기전자재료학회논문지
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    • 제19권10호
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    • pp.942-946
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    • 2006
  • We simulated insulation defects of stator winding wire on high voltage generator by 5 types. 4 types have one discharge source and other one has multi discharge source by simulation. For accurate decision, measurements used to PRPD pattern to occurred partial discharge source of various types. In this research, when PRPD pattern carried out or analyzed pattern recognition of discharge source, it used to powerful tools. In this result, PRPD Pattern defined to have single discharge source of 4 types by insulation defect. When insulation defect simulated, all the defected winding have not the same result. Errors for a little different can make mistakes from a subtle distinction. The difference between internal and void discharge have magnitude of pulse amplitude of inner discharge bigger than void discharge and have a shape of bisymmetry. But void discharge has a shape of bisymmetry against maximum value on polarity respectively. In cases of slot and surface discharge, we confirmed to show similar results those other researchers. In case of multi-discharge, as a result of we could classify not perfect match with occurred patterns in single discharge eachother. In the future, we will have to recognize and classify with results of multi-discharge.

구조물의 안전진단을 위한 충격파의 주파수 영역 탐사에 관한 연구 (A study about frequency domain analysis of impact-wave for detecting of structural defects in the concrete structure)

  • 서백수;김훈;김형준;이상철
    • 한국지구물리탐사학회:학술대회논문집
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    • 한국지구물리탐사학회 2005년도 공동학술대회 논문집
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    • pp.165-180
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    • 2005
  • 충격탄성파 검사법은 콘크리트 구조물 내부의 결함과 외부 표면 사이에서 반사되어 전파되는 응력파를 이용한 비파괴 시험 방법이다. 본 연구에서 토목 구조물의 안전진단을 위하여 충격탄성파 검사법을 이용한 비파괴 시험을 수행하였다. 이를 위해서 토모그래피 방식을 이용한 투과법, 크로스 홀 방식을 이용한 투과법 그리고 일반적으로 터널라이닝과 같은 1차원 면에서 사용되는 반사법을 적용해 그 결과를 비교${\cdot}$분석하였다.

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전단간섭계와 적외선열화상을 이용한 감육 직관의 결함검출 (Defect Detection of Wall Thinned Straight Pipe using Shearography and Lock-in Infrared Thermography)

  • 김경석;정현철;장호섭;김하식;나성원
    • 한국정밀공학회지
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    • 제26권11호
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    • pp.55-61
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    • 2009
  • The wall thinning defect of nuclear power pipe is mainly occurred by the affect of the flow accelerated corrosion (FAC) of fluid. This type of defect becomes the cause of damage or destruction of in carbon steel pipes. Therefore, it is very important to measure defect which is existed not only on the welding part but also on the whole field of pipe. This study use dual-beam Shearography, which can measure the out-of-plane deformation and the in-plane deformation by using another illuminated laser beam and simple image processing technique. And this study proposes Infrared thermography, which is a two-dimensional non-contact nondestructive evaluation that can detect internal defects from the thermal distribution by the inspection of infrared light radiated from the object surface. In this paper, defect of nuclear power pipe were, measured using dual-beam shearography and infrared thermography, quantitatively evaluated by the analysis of phase map and thermal image pattern.