• 제목/요약/키워드: Surface anchoring energy

검색결과 37건 처리시간 0.023초

반사형 TN 액정 셀의 In-Plane스위칭 (In-Plane Switiching of a Twisted-Nematic Reflective LC Cell)

  • 정미준;곽진석;이기동;김재창;윤태훈
    • 한국광학회:학술대회논문집
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    • 한국광학회 2004년도 제15회 정기총회 및 동계학술발표회
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    • pp.138-139
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    • 2004
  • In this paper, we propose a reflective In-Plane Switching twisted nematic mode with negative liquid crystal and weak surface anchoring energy (10$^{-6}$ J/m) in order to enhance reflectance and cellgap margin.

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Director gliding on photoaligning surfaces

  • Reznikov, Yuri;Buluy, Olexander;Kurioz, Yuriy;lljin, Andery;Ouskova, Elena;Antonova, K.;Nobili, Maurizio
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2005년도 International Meeting on Information Displayvol.I
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    • pp.764-767
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    • 2005
  • Photoaligning polymers usually possess "sofe" surface, containing flexible groups and provide relatively small anchoring energy($W<10^{-2}$ erg $cm^{-2}$). In this case field-induced reorientation of director on the aligning surface is essential. We have shown that surface director reorientation can modify the aligning surface and result in gliding of the axis of easy orientation of LC. this phenomena together with adsorption/desorption of ions in electric field cause strong sticking effect in LCDs photoaligning materials. We proposed a method of decreasing of the sticking effect based on irradiation of the photoaligning surface by an unpolarized light.

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Surface sliding effect of nematic liquid crystals on soft- polymer

  • Lee, Chang-Hoon;Gwag, Jin-Seog;Lee, You-Jin;Jin, Min-Young;Kim, Jae-Hoon
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2008년도 International Meeting on Information Display
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    • pp.310-313
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    • 2008
  • Recently, study on the weak interaction energy between the soft polymer surface and liquid crystals has been a primary topic for new LC device applications. In this paper, to understand the switching property of nematic liquid crystals (LCs) at the interface with a weak anchoring boundary, we investigate experimentally the rotation property of surface nematic director by electric field on non-treated Poly-Methylmethacrylate (PMMA, $T_g=110^{\circ}C$, Sigma Aldrich) film observed under various temperatures including the glass transition temperature ($T_g$) of the polymer layer.

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Structure and Dynamics in Surfaces of Polymers and Organic Electronic Materials

  • Yoon, Do-Y.;Lee, Sang-Hun;Jung, Young-Suk;Jo, Jung-Ho;Jeong, Won-Hee;Chang, Jae-Eon;Luning, Jan
    • 한국고분자학회:학술대회논문집
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    • 한국고분자학회 2006년도 IUPAC International Symposium on Advanced Polymers for Emerging Technologies
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    • pp.112-112
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    • 2006
  • Detailed surface characteristics of polymer films have been investigated by atomistic molecular dynamics simulations and NEXAFS spectroscopy experiments. The geometric confinement of the surfaces and the necessity to minimize the surface energy lead to the significant molecular organization and orientation in polymer surfaces, with their properties strongly depending upon the atomistic monomer structures. As compared with polymers, oligomeric electronic materials are much more readily aligned by employing various surface anchoring forces, rendering them highly attractive as polarized-light emitting materials and active semiconducting materials in thin film transistors.

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Thermodynamic Control in Competitive Anchoring of N719 Sensitizer on Nanocrystalline $TiO_2$ for Improving Photoinduced Electrons

  • Lim, Jong-Chul;Kwon, Young-Soo;Song, In-Young;Park, Sung-Hae;Park, Tai-Ho
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2011년도 제41회 하계 정기 학술대회 초록집
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    • pp.68-69
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    • 2011
  • The process of charge transfer at the interface between two semiconductors or between a metal and a semiconductor plays an important role in many areas of technology. The optimization of such devices requires a good theoretical description of the interfaces involved. This, in turn, has motivated detailed mechanistic studies of interfacial charge-transfer reactions at metal/organic, organic/organic, and organic/inorganic semiconductor heterojunctions. Charge recombination of photo-induced electron with redox species such as oxidized dyes or triiodide or cationic HTM (hole transporting materials) at the heterogeneous interface of $TiO_2$ is one of main loss factors in liquid junction DSSCs or solid-state DSSCs, respectively. Among the attempts to prevent recombination reactions such as insulating thin layer and lithium ions-doped hole transport materials and introduction of co-adsorbents, although co-adsorbents retard the recombination reactions as hydrophobic energy barriers, little attention has been focused on the anchoring processes. Molecular engineering of heterogeneous interfaces by employing several co-adsorbents with different properties altered the surface properties of $TiO_2$ electrodes, resulting to the improved power conversion efficiency and long-term stability of the DSSCs. In this talk, advantages of the coadsorbent-assisted sensitization of N719 in preparation of DSSCs will be discussed.

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하이브리드 필름을 이용한 비틀린 네마틱 액정 모드의 필름보상 연구 (Film Compensation of Twisted Nematic LC mode using Hybrid Film)

  • 김성수;황성한;강훈;이명훈;이승희
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2007년도 하계학술대회 논문집 Vol.8
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    • pp.390-391
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    • 2007
  • We have studied improvement of light leakage of twisted nematic liquid crystal display (TN-LCD) in dark state using the hybrid aligned compensation film made of rod-like LC. When the voltage is applied properly to the TN-LCD, the director tilts up but LC director on the substrate don't tilts up due to surface anchoring energy of the LC cell. Accordingly, LC director from surface to middle LC of TN -LCD become hybrid state such as hybrid aligned film. Consequently, in this paper we achieve wide viewing angle performances of TN mode using developed hybrid aligned film which especially decreases light leakage at vertical direction in dark state.

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고속 화염 용사를 통하여 형성된 다중벽 탄소 나노튜브 알루미늄 복합소재 코팅의 특성 평가 (Property Evaluation of HVOF Sprayed Multi-walled Carbon Nanotube Aluminum Composite Coatings)

  • 강기철;박형권;이창희
    • 한국표면공학회지
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    • 제45권1호
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    • pp.1-7
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    • 2012
  • Multi-walled carbon nanotube (MWCNT) aluminum composite powders were deposited to form coatings using a high velocity oxygen fuel (HVOF) spraying process. High thermal energy and contact with atmospheric oxygen were supplied as the MWCNT aluminum composite particles were exposed to a gas flow field at high temperature (${\sim}3.0{\times}10^3$ K) during HVOF spraying. As a result, the particles underwent full or partial melting and rapid solidification due to the high thermal energy, and the exposure to oxygen induced the interfacial reaction of MWCNTs within the particle. The electrical and mechanical properties of MWCNT aluminum composite coatings were evaluated based on microstructure analysis. Electrical resistivity, elastic modulus, and micro-hardness, of the MWCNT aluminum composite coatings were higher than those of pure aluminum coating. The contribution of MWCNTs to the aluminum matrix can be attributed to their high electrical conductivity, dispersion hardening and anchoring effects. The relationship among the properties and the interaction of the MWCNTs with the aluminum matrix is discussed.

가용성 폴리이미드 표면을 이용한 광배향 TN-LCD의 전기광학 특성 (EO Characteristics of photo-aligned TN-LCD on Soluble Polyimide Surface)

  • 박태규;이정호;서대식
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 1999년도 하계학술대회 논문집 D
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    • pp.1759-1761
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    • 1999
  • The generation of pretilt in nematic liquid crystal(NLC)and electro-optical(EO) characteristics of photo-aligned twisted nematic (TN)-LCD with oblique p-polarized ultraviolet (UV) light irradiation on the two kinds of the soluble polyimide (PI) surfaces containing trifluoromethyl moieties were investigated. The generated pretilt angle of NLC is about $2.5^{\circ}$ with p-polarized UV light irradiation of $20^{\circ}$ on PI-3 surface at 20 min.; However pretilt angle of about $0.5^{\circ}$ are observed on PI-1 and PI-2 surfaces. The generated pretilt angle of NLC on PI-3 surface may be attributed to the trifluoromethyl moieties attached to the lateral benzene rings. The voltage-transmittance and response time characteristics of photo-aligned TN-LCD with p-polarized UV light irradiation of $20^{\circ}$ on PI-1 surfaceat at 20 min were almost same in comparison with the rubbing-aligned TN-LCD. However, the high threshold voltage and slow response are observed on PI-3 surface. Also, the decay time $\tau_d$ of photo-aligned TN-LCD is attributed to the anchoring energy of NLC.

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광분해법을 이용한 액정 배향 및 광배향 TN-LCD의 전기광학 특성 (Electro-optical characteristics of photo-aligned TN-LCD and LC alignment by using photo-depolymerization method)

  • 박태규;서대식
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1998년도 추계학술대회 논문집
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    • pp.343-346
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    • 1998
  • The generation of pretilt angle in nematic liquid crystal (NLC) and electro-optical (EO) characteristics of photo-aligned twisted nematic (TN)-LCD with oblique P-polarized ultraviolet (UV) light irradiation on the two kinds of the soluble polyimide (PI) surfaces containing trifluoromethyl moieties were investigated. The generated pretilt angle of NLC is about 2.5$^{\circ}$with P-polarized UV light irradiation of 20$^{\circ}$on PI-3 surface at 20 min.; However pretilt angle of about 0.5$^{\circ}$are observed on PI-1 and PI-2 surfaces. The generated pretilt angle of NLC on PI-3 surface may be attributed to the trifluoromethyl moieties attached to the lateral benzene rings. The voltage-transmittance and response time characteristics of photo-aligned TN-LCD with P-polarized UV light irradiation of 20$^{\circ}$on PI-1 surface at 20 min were almost same in comparison with the rubbing-aligned TN-LCD. However, the high threshold voltage and slow response are observed on PI-3 surface. Also, the decay time $\tau$$\sub$d/ of photo-aligned TN-LCD is attributed to the anchoring energy of NLC.

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Comparison of the Organophosphorus Hydrolase Surface Display Using InaVN and Lpp-OmpA Systems in Escherichia coli

  • Karami, Ali;Latifi, Ali Mohamad;Khodi, Samaneh
    • Journal of Microbiology and Biotechnology
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    • 제24권3호
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    • pp.379-385
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    • 2014
  • The purpose of this study was to compare the ability of an engineered Escherichia coli to degrade chlorpyrifos (Cp) using an organophosphorus hydrolase enzyme, encoded in both Flavobacterium sp. ATCC 27551 or Pseudomonas diminuta, by employing the Lpp-OmpA chimera and the N-terminal domain of the ice nucleation protein as anchoring motifs. Tracing of the expression location of the recombinant protein using SDS-PAGE showed the presentation of OPH by both anchors on the outer membrane. This is the first report on the presentation of OPH on the cell surface by Lpp-OmpA under the control of the T7 promoter. The results showed cell growth in the presence of Cp as the sole source of energy, without growth inhibition, and with higher whole-cell activity for both cells harboring plasmids pENVO and pELMO, at approximately 10,342.85 and 10,857.14 U/mg, respectively. Noticeably, the protein displayed by pELMO was lower than the protein displayed by pENVO. It can be concluded that Lpp-OmpA can display less protein, but more functional OPH protein. These results highlight the high potential, of both engineered bacteria, for use in the bioremediation of pesticide-contaminated sources in the environment.