• Applied Chemistry for Engineering
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• v.34 no.3
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• pp.264-271
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• 2023

In this study, ASCO^Ⓡ SLES-430 surfactant was synthesized by adducting 3 moles of ethylene oxide and 1 mole of propylene oxide to lauryl alcohol followed by a sulfation process, and the structure of the synthesized ASCO^Ⓡ SLES-430 was elucidated by performing FT-IR, ¹H-NMR and ¹³C-NMR analyses. Interfacial properties such as critical micelle concentration, static surface tension, emulsification index, and contact angle were measured, and environmental compatibility indices such as oral toxicity and skin irritation were also estimated for ASCO^Ⓡ SLES-430. Both results were compared with ASCO^Ⓡ SLES-226 and ASCO^Ⓡ SLES-328 SLES surfactants possessing 2 moles and 3 moles of ethylene oxide, respectively. In particular, both foaming ability and foam stability were evaluated for ASCO^Ⓡ SLES-430 and compared with ASCO^Ⓡ SLES-226 and ASCO^Ⓡ SLES-328, which have been widely used in detergent products, in order to test the potential applicability of ASCO^Ⓡ SLES-430 in detergent product formulation for a small capacity built-in washing machine.

• Journal of Korean Society of Occupational and Environmental Hygiene
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• v.32 no.1
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• pp.10-20
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• 2022

Objectives: The aim of this study is to evaluate exposure levels of the extremely low frequency magnetic fields(ELF-MF) radiated from various electric facilities in Liquid Crystal Display(LCD) manufacturing processes. Methods: This study measured the exposure levels of personal and local ELF-MF for the electronic facilities installed in two LCD manufacturing companies. Samplers were installed around workers' waist during working hours to identify personal exposure levels, and direct reading equipment were located at 3 cm, 10 cm, and 30 cm away from the surface of the electronic facilities to measure local exposure levels. Average and maximum(ceiling) values were calculated for personal and local exposure levels. Results: Average and maximum of personal exposure levels for each worker were 0.56(mean) ± 0.02(SE) µT and 6.31 ± 0.75 µT, respectively. Statistical analyses of the study found that maximum of the personal exposure levels for engineers was significantly higher than that for operators since engineers spend more time near the electronic facilities for repairing. The range of maximum personal exposure levels was 0.50 ~ 43.50 µT and its highest level was equivalent to 4.35 % of ACGIH(American Conference of Governmental Industrial Hygienists) exposure limit value(1 mT). Maximum of local exposure levels was 8.18 ± 0.52 µT and the electronic facilities with higher exposure levels were roof rail and electric panel, which were not related to direct manufacturing. The range of maximum local exposure levels was 0.60 ~ 287.20 µT and its highest level was equivalent to 28.7 % of the ACGIH exposure limit value. Lastly, the local exposure levels significantly decreased as the measurement distance from the electronic facilities increased. Conclusions: Maximum of personal and local exposure levels did not exceed the exposure limit value of ACGIH. However, it is recommended to keep the workers as far as possible from the sources of ELF-MF.

• Journal of Korean Tunnelling and Underground Space Association
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• v.11 no.3
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• pp.303-314
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• 2009

Image analyses for sheared joint specimens are performed to study asperity degradation characteristics with respect to the roughness mobilization of rock joints. Four different types of joint specimens, which are made of high-strength gypsum materials, are prepared by replicating the three-dimensional roughness of rock joints. About twenty jointed rock shear tests are performed at various normal stress levels. The characteristic and scale of asperity degradation on the sheared joint specimens are analyzed using the digital image analysis technique. The results show that the asperity degradation characteristic mainly depends on the normal stress level and can be defined by asperity failure and wear. The asperity degradation develops significantly around the peak shear displacement and the average amount of degraded asperities remains constant with further displacement because of new degradation of small scale asperities. The shear strength results using high-strength gypsum materials can not fully represent physical properties of each mineral particles of asperities on the natural rock joint surface. However the results of this quantitative estimation for the relationship between the peak shear displacement and the asperity degradation suggest that the characterization of asperity degradation provides an important insight into mechanical characteristics and shear models of rock joints.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.26 no.6D
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• pp.951-960
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• 2006

Structural pavement analysis considering lateral loads of moving vehicle was carried out in order to simulate passing vehicle loads under various interface conditions. To verify of existing multi-layer elastic analysis of layer interface effect parameters, this study compared outputs by using ABAQUS, a three dimensional finite element program and KENLAYER, multi-layer elastic analysis as vertical load was applied to the surface of asphalt pavements. Pavement performance depending on interface conditions was quantitatively evaluated and fundamental study of layer interface effect parameters was performed in this study. As results of the study, if only vertical loads of moving vehicle is applied, subdivision of either fully bonded or fully unbonded is enough to indicate interface effect parameters. On the other hand, when lateral loads are applied with vertical loads, pavement behavior and performance are greatly changed with respect to layer interface conditions. The thinner thickness of the asphalt layer is and the smaller elastic moduli of the asphalt layer is, the more pavement behavior is influenced by interface conditions. In addition, regression analysis equation analytically computing tensile strain which was considered thicknesses and elastic moduli of the asphalt layer and layer interface effect parameters at the bottom of the asphalt layer was presented using database from numerical analyses on national pavement model sections.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.29 no.1B
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• pp.97-103
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• 2009

The decompostion characteristics of NAPL TCE in cement/slag/Fe(II) system were studied with various TCE concentration and amounts of binders (cement/slag) For analyses of the TCE degradation by cement/slag/Fe(II), TCE solution injected using gas-tight syringe after TCE solution dissolved a methanol. Initial concentrations of TCE are 0.42 mM, NAPL condition 11.7 mM and saturated condition 16.8 mM respectively. The result showed that the cases of 8.4 mM and 4.2 mM are decreased 88% of total TCE concentration within 18 days. NAPL condition 11.7 mM was decreased 84% within 50 days and saturated condition 16.8 mM was decreased 60% of total TCE concentration within 60 days respectively. This showed that degradations of TCE in various concentrations were in one kind reaction as pseudo-first-order. TCE was dissolved as aqueous solution before degraded. The reaction rate was increased $0.12day^{-1}$, $0.24day^{-1}$, $0.31day^{-1}$ when the mass of media 0.1, 0.2, 0.3 S/L rate was increased. TCE reaction speed is affected by cement/slag surface ares in this system. When HDTMA, experimental facter, was added, TCE decomposition rate was high despite the high concentration of NAPL. and The decompostion characteristics of NAPL TCE in cement/slag/Fe(II) system were studied by using modeling.

• Journal of Korean Tunnelling and Underground Space Association
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• v.11 no.1
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• pp.71-83
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• 2009

Shotcrete is an important primary support for tunnelling in rock. The quality control of shotcrete is a core issue in the safe construction and maintenance of tunnels. Although shotcrete may be applied well initially onto excavated rock surfaces, it is affected by blasting, rock deformation and shrinkage and can debond from the excavated surface, causing problems such as corrosion, buckling, fracturing and the creation of internal voids. This study suggests an effective non-destructive evaluation method of the tunnel shotcrete bonding state applied onto hard rocks using the impact-echo (IE) method and ground penetration radar (GPR). To verify previous numerical simulation results, experimental study carried out. Generally, the bonding state of shotcrete can be classified into void, debonded, and fully bonded. In the laboratory, three different bonding conditions were modeled. The signals obtained from the experimental IE tests were analyzed at the time domain, frequency domain, and time-frequency domain (i.e., the Short- Time Fourier transform). For all cases in the analyses, the experimental test results were in good agreement with the previous numerical simulation results, verifying this approach. Both the numerical and experimental results suggest that the bonding state of shotcrete can be evaluated through changes in the resonance frequency and geometric damping ratio in a frequency domain analysis, and through changes in the contour shape and correlation coefficient in a time-frequency analysis: as the bonding state worsens in hard rock condition, the autospectral density increases, the geometric damping ratio decreases, and the contour shape in the time-frequency domain has a long tail parallel to the time axis. The correlation coefficient can be effectively applied for a quantitative evaluation of bonding state of tunnel shotcrete. Finally, the bonding state of shotcrete can be successfully evaluated based on the process suggested in this study.

• Journal of the Microelectronics and Packaging Society
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• v.29 no.4
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• pp.15-20
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• 2022

Aerogel is a material having a nanopore structure based on a high porosity. Due to this high porosity, it has excellent properties not found in conventional materials, but its application has been limited due to low mechanical strength. Therefore, to improve the mechanical strength of the aerogel, polyurea crosslinking was introduced and a precursor having an amine group essential for polyurea polymer formation was selected to synthesize a polyurea crosslinked aerogel composite. In addition, the crosslinking of polyurea was adjusted according to the number of amine groups present in aminosilane. It was confirmed through various analyses that the nanopore structure of the aerogel was maintained to have mesopores. The aerogel thus formed was able to improve the mechanical strength by about two times, and it was confirmed through field emission scanning electron microscope analysis that a one-dimensional polymer was formed on the silica aerogel surface through the introduction of ethylene diamine. The one-dimensional polymer thus formed has improved mechanical properties, resulting in securing an elastic modulus of about 2.66 MPa.

• Applied Chemistry for Engineering
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• v.34 no.6
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• pp.612-618
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• 2023

Modern society spends more than 80% of its daily life indoors, emphasizing the need for attention to indoor air pollution due to the improvement in living standards. In this study, the performance and reaction characteristics of the Pt/TiO₂ catalysts prepared by liquid-phase reduction for the removal of formaldehyde (HCHO), one of the indoor air pollutants, at room temperature without the need for additional light or heat were investigated. As a result, it showed that catalysts prepared by the same method showed approximately 40~80% various activities depending on the type of TiO₂. XRD, BET, and XPS analyses were performed to investigate the particle size, crystal structure, specific surface area, and O/Ti molar ratio of the support material, and it revealed that the correlation between the properties and performance was insignificant. To explore the oxidation reaction pathway of formaldehyde (HCHO), in situ DRIFT analysis using carbon monoxide and H₂-TPR was perfomed. The results revealed that the performance was demonstrated by the oxidation state of the active metal and the adsorption-desorption characteristics of the adsorbate species.

• The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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• v.13 no.3
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• pp.295-301
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• 2008

Bathymetric data collected using a multi-beam echo sounder during marine scientific survey is essential for geologic and oceanographic research works. Accurate measurment of sound velocity profile(SVP) in water-column is important for bathymetric data processing. SVP can vary at different locations during the survey undertaken for wide areas. In addition, an observational error can occur when different equipments(Sound Velocity Profiler, Conductivity Temperature Depth, eXpendable BathyThermograph) are used for measuring SVP at the same water column. In this study, we used an MB-system software to show changes in bathymetry caused by variation of SVP. The analyses showed that the sound velocity(SV) changes due to the depth and thickness of thermocline had more significant effects on the resulting bathymetric data than those of surface mixed layer. The observational errors between SVP measuring instruments did not cause much differneces in the processed bathymetric data. Bathymetric survey line is better to be established to the direction that the change of temperature can be minimize to reduce the variation of SVP during the data acquisition along the survey line.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.44 no.1
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• pp.41-48
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• 2024

In 2017, the Ministry of the Interior and Safety conducted research for the revision of seismic design standards and performed studies on standard design response spectra. As a result, the Common Application Guidelines for Seismic Design Standards were introduced, and these guidelines have been implemented in the national design standards of the Ministry of Land, Infrastructure, and Transport for practical use. However, it should be noted that the research for proposing standard design response spectra during the 2017 revision was conducted before the occurrence of the significant seismic events in South Korea, such as the 2016 Gyeongju Earthquake and the 2017 Pohang Earthquake. To account for these recent major earthquakes, this study adjusted the standard design spectra based on the records of the 2016 Gyeongju Earthquake and the 2017 Pohang Earthquake and conducted ground response analyses accordingly. The results revealed variations in peak ground acceleration (PGA) at the ground surface even within the same ground classification. It was confirmed that this variation can lead to overestimation or underestimation of seismic loads.