• Title/Summary/Keyword: Surface activation

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Responses of Chloramphenicol Immunosensor to Analyte Types

  • PARK , IN-SEON;KIM, DONG-KYUNG;KIM, NAM-SOO
    • Journal of Microbiology and Biotechnology
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    • v.14 no.6
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    • pp.1157-1162
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    • 2004
  • A well-holder type piezoelectric chloramphenicol (CAP) immunosensor which was prepared by binding an anti­CAP antibody to the chemisorbed monolayers of various thiol or sulfide compounds over the gold electrode surface of quartz crystals through a carboxyl-amine coupling procedure, using the activation with l-ethyl- 3-(3-dimethylarninopropyl)carbodiimide­HCl and N-hydroxysulfosuccinimide, was determined for its responses to CAP, CAP succinate, and water-soluble CAP. The reaction phase used in the well holder was 0.01 M phosphate buffer (pH 7.4), and the solvent for analyte dissolution varied according to the solubility of the individual analyte. The analyte detection which was indicated by a steady-state frequency shift was finished within 10 min, except for CAP dissolved in methanol. The responses of CAP succinate and water-soluble CAP in the reaction phase were very stable, while a minute fluctuation was found with CAP.

Synthesis of Spinel Phase Manganese Oxide and Its Activation by Hydrogen Reduction (망간산화물의 합성과 수소환원에 의한 활성화)

  • Yang, Chun-Mo;Kim, Soon-Tae;Rim, Byung-O
    • Journal of the Korean Applied Science and Technology
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    • v.17 no.1
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    • pp.49-53
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    • 2000
  • For decompose carbon dioxide, manganese oxide was synthesized with $0.25M-MnSO_{4}{\cdot}nH_{2}O$ and 0.5M-NaOH by coprecipitation. We made magnetite deoxidized manganese oxide by hydrogen reduction for 1hour at $330^{\circ}C$. We investigated characteristics of catalyst, hydrogen reduction degree and decomposition rate of carbon dioxide. The structure of the hausmannite certified spinel type. The specific surface area of synthesized hausmannite and deoxidized hausmannite were $22.36m^{2}/g$, $33.56m^{2}/g$ respectively. The decomposition rate of $CO_{2}$ of deoxidized hausmannite was 57%.

TMAH/IPA Anisotropic Etching Characteristics with Addition of Pyrazine (Pyrazine이 첨가된 TMAH/IPA 이방성 식각특성)

  • 박진성;정귀상
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1997.04a
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    • pp.23-26
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    • 1997
  • This work presents the TMAH/IPA anisotropic etching characteristics with addition of Pyrazine. (100) Si etching rate of 0.747 ${\mu}{\textrm}{m}$/min at 8$0^{\circ}C$ was obtained using TMAH 25 wt.% / IPA 17 vol.% / pyrazine 0.1 g. The etching rate of (100) Si is increased about 52% compare to pure TMAH 25 wt.%. But etching rate of (100) Si is decreased with increasing Pyrazine additive. Activation energy of TMAH/IPA/pyrazine is much lower than TMAH and TMAH/IPA solutions. Addition of Pyrazine does not effect on surface flatness and decreases undercutting ratio about 20 %. Therefore, TMAH/IPA/pyrazine is an attractive anisotropic etchant because of alkaline-ion free.

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Nonwoven chitosan fibrous matrix with bioactive agents modified surface and drug release function as tissue engineering scaffold

  • Shim, In-Kyong;Hwang, Jeong-Hyo;Yook, Yeo-Joo;Chung, Chong-Pyoung;Lee, Seung-Jin
    • Proceedings of the PSK Conference
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    • 2003.04a
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    • pp.302.2-303
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    • 2003
  • For polymeric material for tissue engineering. chitosan was selected with benefit of high tissue compatibility attributed and wound healing through its activation of growth factors. And nonwoven chitosan fibrous matrix has well interconnected porosity. But chitosan itself has some of limitations in including rapid bone regeneration at initial states incorpor-ated of bioactive materials such as growth factors and ECM molecules. (omitted)

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Catalytic Incineration Kinetics of Gaseous MEK and Toluene (MEK와 톨루엔의 촉매연소 속도특성)

  • 이재동
    • Journal of environmental and Sanitary engineering
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    • v.14 no.2
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    • pp.113-119
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    • 1999
  • In this study, the incineration of MEK and toluene was studied on a Pt supported alumina catalyst at temperature range from 200 to $350^{\circ}C$. An approach based on the Mars-van Krevelen rate model was used to explain the results. The object of this study was to study the kinetic behavior of the platinum catalyst for deep oxidation. The conversions of MEK and toluene were increased as the inlet concentration was decreased and the reaction temperature was increased. The maximum deep conversion of MEK and toluene were 91.81% and 55.69% at $350^{\circ}C$, respectively. The ${\kappa}_3$ constant increases with temperature faster than the ${\kappa}_1$ constant, that is, the surface concentration of ($VOCs{\cdots}O$) is higher than that of (O) at higher temperature according to the Mars-van Krevelen mechanism. Also the activation energy of toluene was larger than MEK for toluene is aromatic compound which have stronger bonding energy.Therefore, the catalytic incineration kinetics of MEK and toluene with Mars-van Krevelen mechanism could be used as the basic data for industrial processes.

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알루미나 세라믹스의 분위기 변화에 따른 Tribology 특성

  • 진동규;박흥식;전태옥;이광영
    • Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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    • 1997.04a
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    • pp.33-40
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    • 1997
  • This study was undertaken to investigate tribology characteristics of the alumina ceramics($Al_2O_3$) for the vauiation of ambient condition such as air and distilled water. The results obtained were as follows. As the sliding speed increases, the friction coefficient in the air decreased due to the reduction of sheafing stress caused by the heat accumulation of contact interface. And the friction coefficient in the distilled water decreased due to an activation of the tribochemical reaction. As the contact load increases, the friction coefficient is small in the air due to temperature rise of the contact interface. However, at the low speed side in the distilled water, the friction coefficient holds a large value due to decrease of the tribochemical reaction. The friction surface of ceramics can be protected in the air by the influence of the oxides tansfered from STB2 and also in the distilled water by the influence of the corrosive productive hydroxides.

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Formation of $P^+-Layer$ in GaAs Using the Open-Tube Diffusion of Zn (Open-Tube에서 Zn확산을 이용한 GaAs에의 $p^+$층 형성)

  • 심규환;강진영;민석기;한철원;최인훈
    • Journal of the Korean Institute of Telematics and Electronics
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    • v.25 no.8
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    • pp.959-965
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    • 1988
  • Zinc diffusion characteristics and its applicabilities have been studied using an open-tube system. Thermal decomposition of arsenide(As) at gallium arsenide(GaAs) wafer surface was well inhibited by using Ga: poly-GaAs: Zn compositon as a diffusion source. Junction depth was obtained as 4.6x10**7\ulcorner exp)-1.25/kT) where activation energy of diffusion was 1.25eV. From Boltzmann-matano analysis, it could be identified that concentration dependencies of Zn diffusivity well consisted with those of kick-out model. The ideality factor of p+-n junction formed by Zn diffusion was about 1.6 and infrared light intensity was linearly varied in the range of sixty folds. It is concluded frodm these results that Zn diffuses according to kick-out model, and open-tube method is applicable to compound semiconductor devices.

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Electrochemical spike oscillation st the Ni electrode interface (Ni 전극 계면에서 전기화학적 spike 발진)

  • 천장호;손광철;라극환
    • Journal of the Korean Institute of Telematics and Electronics A
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    • v.33A no.12
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    • pp.83-89
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    • 1996
  • The electrochemical spike oscillations at the nickel (Ni) electrode/(0.05M KHC$_{8}$H$_{4}$O$_{4}$) buffer solution (pH 9) interface have been studied using voltammetric and chronoamperometric methods. The nature of the periodic cathodic current spikes is the activation controlled currents due to the hydrogen evolution reaction and depends onthe fractioanl surface coverage of the adsorbed hydrogen intermediate or the cathodic potential. There is two kinds of the waveforms corresponding to two kinds of the cathodic current spike oscillations. The widths, periods, and amplitudes of the cathodic current spikes are 4 ms or 5ms, 151 ms or 302 ms, and < 30 mA or < 275 mA, respectively. The fast discharge and recombination reaction steps are 1.5 times and twice and faster than the slow discharge and recombination reaction steps. The fast and slow discharge and recombination reaction steps are 1.5 times and twice faster than the slow discharge and recombination reaction steps. The fast and slow discharge and recombination reactions corresponding to the fast and slow adsorption sites at the Ni cathode.

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Actin Engine in Immunological Synapse

  • Piragyte, Indre;Jun, Chang-Duk
    • IMMUNE NETWORK
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    • v.12 no.3
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    • pp.71-83
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    • 2012
  • T cell activation and function require physical contact with antigen presenting cells at a specialized junctional structure known as the immunological synapse. Once formed, the immunological synapse leads to sustained T cell receptor-mediated signalling and stabilized adhesion. High resolution microscopy indeed had a great impact in understanding the function and dynamic structure of immunological synapse. Trends of recent research are now moving towards understanding the mechanical part of immune system, expanding our knowledge in mechanosensitivity, force generation, and biophysics of cell-cell interaction. Actin cytoskeleton plays inevitable role in adaptive immune system, allowing it to bear dynamic and precise characteristics at the same time. The regulation of mechanical engine seems very complicated and overlapping, but it enables cells to be very sensitive to external signals such as surface rigidity. In this review, we focus on actin regulators and how immune cells regulate dynamic actin rearrangement process to drive the formation of immunological synapse.