• Journal of the Korea Academia-Industrial cooperation Society
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• v.21 no.1
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• pp.717-724
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• 2020

In general, the factors affecting the heat transfer of asphalt pavement are divided into weather factors and pavement materials. Among them, material factors include the thermophysical and surface properties. An experiment was conducted on the thermal-physical factors of asphalt, which are the basis for the pavement failure model. The thermal conductivity, specific heat capacity, thermal diffusivity, and thermal emissivity were evaluated as the thermo-physical properties of asphalt. The specimens (WC-2 & PA-13) used in the experiment were compacted with a Gyratory Compactor. The experimental results of WC-2 and PA-13 showed a thermal conductivity of 1.18W/m·K and 0.9W/m·K, specific heat capacity of 970.8J/kg·K and 960.1J/kg·K, thermal emissivity of 0.9 and 0.91, and thermal diffusivity of 5.15㎡/s and 4.66㎡/s, respectively. Experiments on the heat transfer characteristics (thermo-physical properties) of asphalt pavement that can be used for thermal failure modeling of asphalt were conducted.

• Korean Journal of Food Science and Technology
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• v.28 no.1
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• pp.1-7
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• 1996

Three formulations were used to prepare the cellulose-based edible films consisting of hydrocolloid and lipids; film A made by coating method, films B and C by emulsion method, which were formed in a thin layer glass plate and then dried. Films A, B and C were all approximately 0.03 mm thick with 1-3% moisture, 59-68% lipid, and almost whitish color. Film A was better in tensile strength, and lipids affected water vapor permeability on three films, in which films A and B did not differ significantly. Water vapor permeability of film A did not change but those of films B and C decreased significantly after storage for 8 weeks at $-15^{\circ}C$. Oxygen transmission rate and oxygen permeability of films A and C did not differ and changed significantly after 8-week storage at $-15^{\circ}C$. Under scanning electron microscope (SEM) observation on the structural characteristics of each film, film A indicated relatively uniform and smooth surface coatings of beeswax, while films B and C had individual lipid crystals and could be discerned. As a result, film A was better than films B and C in respect of physical properties, but the selection of useful film depended upon which physical property was more functional. Moreover, it was desirable in some cases for using films B and C because of their easiness of preparation and cold storage durability. It will be further needed to investigate how to formulate films B and C to have more unique surface characteristics, and to reduce water vapor and oxygen transmission rates.

• Journal of the Korean institute of surface engineering
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• v.45 no.3
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• pp.97-105
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• 2012

The effects of pH, types of applied current, agitation method and time, additive on the amount of co-deposited $TiO_2$ particles in the matrix were investigated. The deposition rates increased with increasing pH values, while the volume fraction of $TiO_2$ particles and the size of agglomerated $TiO_2$ particles in the composite decreased. The volume fraction of $TiO_2$ particles in the composite decreased when pulsed current of 50% duty cycle was used. And the size of agglomerated $TiO_2$ particles in the nickel matrix of pulsed current was smaller than that of DC current specimen. The volume fraction of $TiO_2$ particles in the matrix decreased with longer time by air agitation, but in case of using magnetic bar, volume fraction in the same range of time was relatively constant. The volume fraction of the electrodeposited Ni-$TiO_2$ composite in the solution containing 0.01 M Dimethylamine borane (DMAB) increased slightly with increasing agitation time regardless of agitation methods. Thermal stability of the electrodeposited Ni-$TiO_2$ composite increased with lower pH at the temperature range of $200{\sim}800^{\circ}C$, and the results showed that the amount of co-deposited $TiO_2$ relies more on the deposition rate than zetapotential of $TiO_2$ particles.

• Geophysics and Geophysical Exploration
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• v.19 no.4
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• pp.187-199
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• 2016

In order to delineate the soft ground distribution, an integrated geostatistical analysis was performed using the MASW (Multichannel Analysis of Surface Wave) which has the information of overall region and CPTu (Piezo Cone Penetration Test) which provides the direct information of the measuring point of the ground. MASW results were known to have close relationship with the ground stiffness. This correlation was confirmed through the comparison of MASW data obtained from two survey lines to the laboratory test with extracted soil samples. 3D physical property distribution in the study area was acquired by geostatistical integrated analysis with the data of tip resistance ($q_c$) and pore pressure (u) from the CPTu obtained at 6 points within the study area. The integrated analysis was conducted by applying the COSGSIM (Sequential Gaussian Co-Simulation) technology which can carry out the simulation in accordance with the spatial correlation between the MASW results and both tip resistance and pore pressure. Besides the locations of CPTu, borehole investigations were also conducted at two different positions. As a result, the N value of SPT and borehole log could be secured, so these data were used for the analysis of the geotechnical engineering accuracy of the integrated analysis result. For the verification of reliability of the 3D distribution of tip resistance and pore pressure secured through integrated analysis, the geotechnical information gained from the two drilling areas was compared, and the result showed extremely high correlation.

• Journal of Adhesion and Interface
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• v.12 no.3
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• pp.88-93
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• 2011

Optimal dispersion and fabrication conditions of carbon nanotube (CNT) embedded in phenolic resin were determined by electrical resistance measurement; and interfacial property was investigated between plasma treated carbon fiber and CNT-phenolic composites by electro-micromechanical techniques. Wettability of carbon fiber was improved significantly after plasma treatment. Surface energies of carbon fiber and CNT-phenolic nanocomposites were measured using Wilhelmy plate technique. Since surface activation of carbon fiber, the advancing contact angle decreased from $65^{\circ}$ to $28^{\circ}$ after plasma treatment. It was consistent with static contact angle results of carbon fiber. Work of adhesion between plasma treated carbon fiber and CNT-phenolic nanocomposites was higher than that without modification. The interfacial shear strength (IFSS) and apparent modulus also increased with plasma treatment of carbon fiber.

• Polymer(Korea)
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• v.33 no.2
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• pp.111-117
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• 2009

This study aims to verify for humans the suitability of the enzyme-fixed hydrogel used for the patch sensor of the blood sugar testing system without blood sampling, which utilizes reverse iontophoresis. Using acrylate monomers, hydrogel was synthesized to which a certain unit of enzyme is fixed. In order to analyze the material property of the synthesized hydrogel, a structural analysis was performed using FT-IR spectroscopy, while the DSC was used to verify the thermal stability. In addition, with the UV-Vis spectrophotometer, it was verified that the degree of active enzyme is at least 50% greater than the standard product. The SEM was used to verify secure fixation of the enzyme onto the surface. As a result, it was observed that the enzyme is successfully fixed to the surface. Since the hydrogel makes direct contact with a patient's skin, it is essential to evaluate the toxicity when making direct contact with the skin. For that purpose, various sets of tests were undertaken according to the ISO 10993-cytotoxicity, intracutaneous reactivity, skin irritation test and maximization sensitization. Consequently, it was successfully verified that the enzyme-fixed hydrogel have bioavailability.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.31 no.5
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• pp.203-211
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• 2021

Octacalcium phosphate(OCP, Ca₈H₂(PO₄)₆·5H₂O) is one of biodegradable calcium phosphate materials with osteoconductivity and biocompatibility. It has the advantage of rapid bone formation and resorption due to the property of stimulating stromal cells to differentiate into osteoblasts. However, if OCP is inserted in body, it is immediately decomposed without maintaining of its shape as scaffolds due to their weak cohesive force between powder. On the other hand, hydroxyapatite (HA, Ca₁₀(PO₄)₆(OH)₂), which has a crystal structure similar to that of OCP, remains in the body without decomposition until the bone defect is restored. In this study, the degradation behavior of OCP/HA disc with different amount of HA in SBF (simulated body fluid) solution was characterized in terms of the weight loss, pH variation and microstructure change with immersion duration in SBF solution. As a result, the OCP/HA disc was not quickly decomposed and maintained its own shape for 2 weeks regardless of HA content. In particular, the surface of 40HA specimen was uniformly dissolved and then CDHA (calcium deficient hydroxyapatite) phase were formed onto the surface of disc after 7 days in SBF solution. It would be suggested that the 40HA specimen would be suitable candidate material as the scaffolds for the restoration of bone defect.

• Economic and Environmental Geology
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• v.51 no.6
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• pp.531-542
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• 2018

Batch sorption experiments were performed to remove the uranium (U) in groundwater by using the bamboo charcoal. For 2 kinds of commercialized bamboo charcoals in Korea, the U removal efficiency at various initial U concentrations in water were investigated and the optimal sorption conditions to apply the bamboo charcoal were determined by the batch experiments with replicate at different pH, temperature, and reaction time conditions. From results of adsorption batch experiments, the U removal efficiency of the bamboo charcoal ranged from 70 % to 97 % and the U removal efficiency for the genuine groundwater of which U concentration was 0.14 mg/L was 84 %. The high U removal efficiency of the bamboo charcoal maintained in a relatively wide range of temperatures ($10{\sim}20^{\circ}C$) and pHs (5 ~ 9), supporting that the usage of the bamboo charcoal is available for U contaminated groundwater without additional treatment process in field. Two typical sorption isotherms were plotted by using the experimental results and the bamboo charcoal for U complied with the Langmuir adsorption property. The maximum adsorption concentration ($q_m:mg/g$) of A type and C type bamboo charcoal in the Langmuir isotherm model were 200.0 mg/g and 16.9 mg/g, respectively. When 2 g of bamboo charcoal was added into 100 mL of U contaminated groundwater (0.04 ~ 10.8 mg/L of initial U concentration), the separation factor ($R_L$) and the surface coverage (${\theta}$) maintained lower than 1, suggesting that the U contaminated groundwater can be cleaned up with a small amount of the bamboo charcoal.

• Journal of Conservation Science
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• v.37 no.2
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• pp.101-119
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• 2021

Korea's National Treasure No. 229, the Jagyeongnu (clepsydra) of Changgyeonggung Palace, is a scientific and cultural property representing the pinnacle of science and technology in the Joseon Dynasty. Currently, only the large, mid-sie, and small Pasuhos (bronze jars) remain. During a nearly two-year conservation project by the Cultural Heritage Conservation Science Center (CHCSC) that began in 2018, conservators identified the contaminants on the surface of the water clock's components. It turned out that the contaminants had been caused by the exposure of squalane and silicone oil, used in an earlier preservation treatment, to the elements. The CHCSC conducted experiments to determine the most effective method to remove the contaminants. First, the conservators tried using an organic solvent, a poultice, and the application of toluene and bentonite, which yielded excellent reactivity and significant color difference changes (𝚫E). However, the reactivity was insufficiently effective to warrant the health hazards to the conservators and the environment (toluene is toxic). Although organic solvents required considerably more effort, time, and human resources, the conservators confirmed that their use achieved a true color difference variation (𝚫E) that was within the same range as the toxic hydrocarbon. Thus, they confirmed that using an organic surfactant was the best method for removing the contaminants.

• Applied Chemistry for Engineering
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• v.22 no.2
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• pp.138-143
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• 2011

To investigate the electromagnetic interference shielding efficiency (EMI SE) property based on heat treatment effects of carbon fibers in various temperatures, the polyacrilonitrle-based carbon fibers were prepared by electrospinning method and treated at 1073, 1323, 1873 and 2573 K. The surface morphology of carbon fibers was investigated by using FE-SEM and the carbon crystallization was studied by Raman spectroscopy based on effects of reaction temperatures. The electrical conductivity was obtained by measuring the surface resistance with four probe method on carbon crystallization. The permittivity, permeability and EMI SE were investigated by using S-parameter in the range of 800~4500 MHz. In case of carbon fibers treated at 2573 K, the improved carbon crystallization was confirmed by Raman spectrum and the enhanced electrical conductivity showing 54.7 S/cm was also observed. The permittivity was dramatically improved by factor of 4 based on effect of high reaction temperature. Eventually, the highly improved EMI SE value was obtained showing around 41.7 dB.