• 제목/요약/키워드: Surface Analysis

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X-선 광전자 분광법 및 라더포드 후방산란법에 의한 개질된 고분자 시료의 표면분석 (Surface Analysis of Modified Polymer Samples by X-Ray Photoelectron Spectroscopy and Rutherford Backscattering Spectroscopy)

  • 박성우;김동환;김영만;박병선;한완수;서배석
    • 분석과학
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    • 제7권3호
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    • pp.301-313
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    • 1994
  • X-선 광전자분광법(XPS)과 라더포드 후방산란법(RBS)은 첨가제 분석, 화학구조 규명은 물론 시료 표면 원소의 정성 및 정량, 결합에너지 준위, 수직분포 분석을 통한 동일성 판정 등에 응용할 수 있다. $XeF_2$와 C-F plasma로 표면을 처리한 polyethylene, acrylonitrile butadien rubber, polypropylene, glass, fiber 및 paper를 XPS와 RBS로 분석한 결과 불소원자가 시료의 표면에 침투한 것을 확인할 수 있었으며, 표면 원소의 분포가 미처리된 시료의 표면원소 분포와 차이가 있었다.

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Aerosol Deposition and Behavior on Leaves in Cool-temperate Deciduous Forests. Part 1: A Preliminary Study of the Effect of Fog Deposition on Behavior of Particles Deposited on the Leaf Surfaces by Microscopic Observation and Leaf-washing Technique

  • Watanabe, Yoko;Yamaguchi, Takashi;Katata, Genki;Noguchi, Izumi
    • Asian Journal of Atmospheric Environment
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    • 제7권1호
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    • pp.1-7
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    • 2013
  • To establish the method for investigating the behavior of aerosol particles deposited on the leaf surface against fog water under natural conditions, scanning electron microscopy with energy-dispersive X-ray (SEM-EDX) analysis and wash water analysis by ion chromatography after the washing treatment were performed using leaves of white birch collected from low part of the tree crown and the top of the tree in Sapporo City, Hokkaido, northern Japan. Each of collected leaves was divided into two parts according to the treatment performed: leaf surface (adaxial side) was 1) untreated, and 2) washed with deionized water with a pipette. In untreated samples, many particles of various shapes, including soil particles and organic debris, were deposited on the surface. Particles containing S were found on the surface of samples collected from only low part of the tree crown. After the washing treatment, SEM-EDX analysis revealed that soil particles and particles containing S had been washed off with water, although some particles such as soil particles and organic debris still remained on the leaf surface. The major anion such as $SO{_4}^{2-}$ was detected in wash water of all samples, although the peak of S in X-ray spectra was not detected from samples collected at top of the tree. The combination of SEM-EDX analysis with wash water analysis indicated that $SO{_4}^{2-}$ was deposited on the leaf surface in dissolved state and/or in state of submicron particles. These results suggested that fog water could remove soil particles and particles containing S and $SO{_4}^{2-}$ from the leaf surfaces, but not all particles. There was no difference in sampling position in the tree crown. Our study suggested that combination with SEM-EDX analysis and wash water analysis would be effective for investigation of the behavior of particles on the leaf surface against fog water.

다양한 구강위생기구를 이용하여 임플란트 표면의 Prophylaxis 시행시 표면형태의 변화분석 (Analysis of surface form change after performing prophylaxis procedure on implant surface using various oral hygiene instruments)

  • 이선구;임성빈;정진형;권상호
    • Journal of Periodontal and Implant Science
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    • 제34권1호
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    • pp.1-17
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    • 2004
  • It is improtant that performing prophylaxis procedure on an infected implant surface in order to treat peri-implantitis should not change the surface roughness and composition, so that the surface can be recovered to almost same condition as initial implant surface. This thesis, therefore, studied an effect of various oral hygiene instrument on implant surface. A surface roughness measurement instrument and an infection electron microscope were used to observe a change on surface. The purpose of this study was to obtain a clinical guidelines during implant care and peri-implantitis treatment. The result were as follows 1. Ra values (surface roughness value) at experimental group 1, group 2, and group 5 were increased significantly as compared with comparison group(p<0.05). 2. When compared experimental group 1 with each experimental groups at which prohylaxis procedure was performed, mean values of Ra at experimental group 2, group 3, group 6, and group 7 were decreased significantly(p<0.05). 3. Mean value of Ra was lowest at experimental group 2, and highest at experimental group 2, and highest at experimental group 5. 4. Analysis of SEM showed that was significant surface change at experimental group 2, group 3, group 4, group 5, and group 6 as compared with comparison group(X1000). 5. Analysis fo EDX showed that a quantity of Ti on surface for experimental group 6 was very similar to that for comparison group. In conclusion, air-powder abrasive and citric acid, plastic instrument are safe methods to use for performing prophylaxis procedure on implant care or for cleaning and sterilization process on treatment of peri-implantitis, based on the result that those method did not affect implant surface roughness and Ti composition.

현대건축 표면에 적용된 디지털미디어의 표현 특성 연구 - 설치미술적 특징에 기초한 분석 - (A Study on the characteristics of digital-media application on surface - An analysis based upon the related characteristics of installation art -)

  • 김진영;이현수
    • 한국실내디자인학회논문집
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    • 제19권3호
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    • pp.38-45
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    • 2010
  • Surface has been an important issue in contemporary architecture. That originates in structural freedom of surface since the end of modern architecture and the current stream of surface becoming an identity of building. Development of digital-media has brought a great change to our society in general. Digital-media is characterized by use of digital-information and interactive communication. Digital-media has been applied on surface in contemporary architecture lately. It is a purpose of the study to analyze the characteristics of digital-media application on surface based on the related characteristics of installation art. The categories and the contents for the frame of case analysis were arranged through document research. The foreign and domestic cases of digital-media application were analyzed based on the frame of analysis. Digital-media, which is installed on surface, is interacted with human and surroundings. It enhances emotional communication between human and architecture. Surface is not any more a simple fixture but an interactive creature. It makes surface more dynamically and fluidly that the course of light and human movement affect on digital-media. Surface itself is also turned into an object of art. It reflects the interweaving characteristics between contemporary architecture and installation art. It was analyzed through the study that emotional level of people is the important issue shared in digital-media application on surface and installation art. The complementary relationship between surface of contemporary architecture and installation art can be manipulated by the application of digital-media on surface.

Study of PSII-treated PMMA, PHEMA, and PHPMA ; Investigation of Their Surface Stabilities

  • Hyuneui Lim;Lee, Yeonhee;Seunghee Han;Jeonghee Cho;Moojin suh;Kem, Kang-Jin
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 1999년도 제17회 학술발표회 논문개요집
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    • pp.204-204
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    • 1999
  • The plasma source ion implantation(PSII) technique which is a method using high negative voltage pulse in plasma system has the potential to change the surface properties of polymer. PSII technique increase the surface free energy by introducing polar functional groups on the surface so that it improves reactivity, hydrophilicity, adhension, biocompatability, etc. However, the mobility of polymer chains enables the modified surface layers to adapt their composition to interfacial force. This hydrophobic recovery interrupts the stability of modified surfaces to keep for the long time. In this study, poly(methyl methacrylate)(PMMA), poly(2-hydroxyethyl methacrylate)(PHEMA), and polu(2-hydroxypropyl methacylate)(PHPMA) for contact lens application, were modified to improve the wettability with PSII technique and were investigated the surface stabilities. Polymer film was prepared with solution casting(3 wt.% solution) and was annealed at 11$0^{\circ}C$ under vacuum oven to remove solvent completely and to eliminate physical ageing. The thickness of the film measured by scanning electron microscopy (SEM) and surface profilometer was about 10${\mu}{\textrm}{m}$. Polymers were treated with different kinds of gases, pulse frequency, pulse with, pulse voltage, and treatment time. Even though PMMA, PHEMA, and PHPMA have similar repeat unit structure, the optimal treatment conditions and the tendency to hydrophobic recovery were different. PHPMA, more hydrophilic polymer than PMMA and PHEMA showd better wettability and stability after mild treatment. Surface tensions were obtained by water and diiodomethane contact angle measurements to monitor the relation between hydrophobic recovery and polymer structure. Different ion species in plasma change the polar component and dispersion component of polymer surface. For better wettability surface, the increase of polar component was a dominant factor. We also characterized modified polymer surfaces using x-ray photoelectron spectroscopy(XPS), secondary ion mass spectrometry(SIMS), Fourier Transform infrared spectroscopy(FT-IR), and SEM.

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플라즈마 식각에 의하여 실리콘 표면에 유기된 불순물 오염의 분석 및 제거 (Analysis and Reduction of Impurity Contamination Induced by Plasma Etching on Si Surface)

  • 조선희;이원종
    • 한국전기전자재료학회논문지
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    • 제19권12호
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    • pp.1078-1084
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    • 2006
  • Impurity contamination induced by $CF_4\;and\;HBr/Cl_2/O_2$ plasma etching on Si surface was examined by using surface spectroscopes. XPS(x-ray photoelectron spectroscopy) surface analysis showed that F of 0.4 at % exists in the surface layer in the form of Si-F bonding but Br and Cl are below the detection limit $(0.1{\sim}1.0%)$ of the spectroscope. Static-SIMS(secondary ion mass spectrometry) surface analysis showed that the etched Si surface was contaminated with etching gas elements such as H, F, Cl and Br, and they existed to the depth of about $20{\sim}40nm$. The etched Si surface was treated with three different methods that were HF dip, thermal oxidation followed by HF dip and oxygen-plasma oxidation followed by HF dip. They showed an effect in reducing the impurity contamination and the oxygen-plasma oxidation followed by HF dipping method appears to be a little bit more effective.

Efficient Algorithm for Real-time Generation of Reflection Lines

  • Kim, Tae-wan;Juyup Kang;Lee, Kunwoo;Park, Sangkun
    • Journal of Mechanical Science and Technology
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    • 제15권2호
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    • pp.160-171
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    • 2001
  • Depending upon the method of the surface generation and the quality of the designed boundary curves, the resulting surfaces may have global or local irregularities in many cases. Thus, it would be necessary for the designer to evaluate the surface quality and to modify the surface. This is very important because the defect of the surface causes the rework of the dies, increasing cost and delivery time significantly. To simulate the reflection line test in the actual production line, a faster algorithm for generating reflection lines is presented. In this paper, among various surface interrogation methods using reflection lines, Blinn-Newell type of reflection mapping is applied to generate the reflection lines on the trimmed NURBS surfaces. The derivation of reflection lines is formulated as a surface-plane intersection problem (Jung 1994) and is solved by surface-contouring techniques. Also, for eliminating the discontinuity of reflection lines due to the configuration of reflection map, a modified reflection map is proposed. An efficient traced contouring technique is utilized for the computational efficiency and proves to be well suited for the real-time quality-assessment task.

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Multichannel Analysis of Surface Waves (MASW) Active and Passive Methods

  • Park, Choon-Byong
    • 한국지구물리탐사학회:학술대회논문집
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    • 한국지구물리탐사학회 2006년도 공동학술대회 논문집
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    • pp.17-22
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    • 2006
  • Shear modulus is directly linked to material's stiffness and is one of the most critical engineering parameters. Seismically, shear-wave velocity (Vs) is its best indicator. Although methods like refraction, down-hole, and cross-hole shear-wave surveys can be used, they are generally known to be tougher than any other seismic methods in field operation, data analysis, and overall cost. On the other hand, surface waves, commonly known as ground roll, are always generated in all seismic surveys with the strongest energy, and their propagation velocities are mainly determined by Vs of the medium. Furthermore, sampling depth of a particular frequency component of surface waves is in direct proportion to its wavelength and this property makes the surface wave velocity frequency dependent, i.e., dispersive. The multichannel analysis of surface waves (MASW) method tries to utilize this dispersion property of surface waves for the purpose of Vs profiling in 1-D (depth) or 2-D (depth and surface location) format. The active MASW method generates surface waves actively by using an impact source like sledgehammer, whereas the passive method utilizes those generated passively by cultural (e.g., traffic) or natural (e.g., thunder and tidal motion) activities. Investigation depth is usually shallower than 30 m with the active method, whereas it can reach a few hundred meters with the passive method. Overall procedures with both methods are briefly described.

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수도권 그린벨트가 지표면 온도에 미치는 영향 분석 (Analyzing Impact of the Effect of Greenbelts on the Land Surface Temperature in Seoul Metropolitan Area)

  • 김희재
    • 도시과학
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    • 제9권1호
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    • pp.17-31
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    • 2020
  • This study aims to analyze the relations among greenbelt, urban land surface temperature empirically in order to assess the environmental effects of the greenbelt in the Seoul metropolitan area, objectively. For this purpose, this study conducts an empirical analysis of impacts of greenbelt on urban land surface temperature using a multiple-regression model. The main data employed in the analysis include real-time air pollution data, Landsat 8-OLI Landsat imagery data, KLIS data and Jip-gye-gu data. The major findings are summarized as follows. NDVI has a negative (-) correlation with the land surface temperature, and the urban temperature is high in areas with poor vegetation. The land surface temperature is low in residential or commercial areas, while the temperature is high in industrial areas. The temperature is low in green fields, open spaces, and river areas. it is found that the urban land surface temperature is low in the greenbelt zone. In the greenbelt zone, there is an effect that reduces the land surface temperature by 1% on average, as compared to that at the center of the Seoul metropolitan area. Especially, the center of the Seoul metropolitan area, in a range from 0.6% to 1.9% of the average temperature, the temperature gets lower up to approximately 3km from the greenbelt boundary.