• 열처리공학회지
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• 제4권3호
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• pp.47-53
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• 1991

In this study, the structural phase transition and decomposition of superconducting ceramic, Y-Ba-Cu-O system was studied. The results of the study are as follows. The high Tc superconductor $Y_2Ba_2Cu_3O_{7-x}$ is made in solid state reaction of $O_2$ atmosphere and the valve of X in $Y_2Ba_2Cu_3O_{7-x}$ is 0.1~0.2. The transition temperature of tetragonal-orthorhombic phase of $Y_2Ba_2Cu_3O_{7-x}$ appear at $790^{\circ}C-900^{\circ}C$. In the result of measuring the electrical resistance of sample annealed in $O_2$ atmosphere, the electrical resistance show zero at 92 K and the best superconductor, $Y_2Ba_2Cu_3O_{7-x}$(Y 123) can be mabe.

• 한국세라믹학회지
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• 제35권2호
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• pp.137-144
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• 1998

고온초전도체 61심 Bi-2223 선재간의 초전도 접합부위를 화학적 부식 및 열적· 기계적 반복 공정에 의하여 제조하였다. 초전도 선재 테이프의 은 피복재 한쪽 표면을 초전도체와 반응하지 않는 부식액(NH4OH:H2O2=1:1)으로 화학적으로 제거한 다음, 두 시편을 일출가압 성형하여 접합시편을 제조하였고 일련의 서로 다른 열적· 기계적 처리를 거쳐 접합부의 물성 및 미세구조를 분석하였다. 접합부를 따라 임계전류(Ic) 변화와 전류전압 곡선의 특성을 측정하기 위하여 여러 단자를 접합부 주위에 설치하여 부위별 I~V 특성을 측정한 결과 단심선재에 비하여 다심선재에서 선재 전체의 통전 능력을 좌우하는 천이구간의 임계전류값이 높았다. 그러나 단심에 비해 다심선재는 천이급속도를 나타내는 n값이 다심선재내 각각의 초전도 core들의 상호작용에 의하여 낮은 값을 나타내었다. 접합부의 임계전류 통전성은 반복적인 가압성형 공정과 서냉반응 열처리 공정에 의하여 향상되었다.

• E2M - 전기 전자와 첨단 소재
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• 제9권4호
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• pp.404-409
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• 1996

The structural and electric properties of $Y_{1-x}$YbF$_{x}$Ba$_{2}$Cu$_{3}$O$_{7-y}$(x=0.0, 0.1, 0.2, 0.3, 0.4, 0.5 and 0.6) have been investigated by using XRD(X-ray diffraction), TMA(thennomechanical analysis), NMR(nuclear magnetic resonance) analysis and four probe method. $Y_{1-x}$YbF$_{x}$Ba$_{2}$Cu$_{3}$O$_{7-y}$ samples were prepared by conventional solid-state reaction method using $Y_{2}$O$_{3}$, BaCO$_{3}$, CuO and YbF$_{3}$ power. TMA and high temperature XRD results shows that orthorhombic to tetragonal phase transition occurs in the unfluorinated 1-2-3 sample while the phase change is not observed in the fluorinated 1-2-3 samples. Superconducting transition temperature(T$_{c}$) increases with increasing YbF$_{3}$ content ; T$_{c}$, of the sample reaching maximum of 102K for x=0.3, and then decreases with further increasing YbF$_{3}$ content. The structural analysis and T$_{c}$ results shows that the fluorine doping stabilize the orthorhombic phase, together with the increase in T$_{c}$.}$ c/.TEX> c/.

• 한국초전도ㆍ저온공학회논문지
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• 제16권1호
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• pp.9-13
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• 2014

Effects of neutron irradiation on the superconducting properties of the undoped $MgB_2$ and the carbon(C)-doped $MgB_2$ bulk superconductors, prepared by an in situ reaction process using Mg and B powder, were investigated. The prepared $MgB_2$ samples were neutron-irradiated at the neutron fluence of $10^{16}-10^{18}n/cm^2$ in a Hanaro nuclear reactor of KAERI involving both fast and thermal neutron. The magnetic moment-temperature (M-T) and magnetization-magnetic field (M-H) curves before/after irradiation were obtained using magnetic property measurement system (MPMS). The superconducting critical temperature ($T_c$) and transition width were estimated from the M-T curves and critical current density ($J_c$) was estimated from the M-H curves using a Bean's critical model. The $T_cs$ of the undoped $MgB_2$ and C-doped $MgB_2$ before irradiation were 36.9-37.0 K and 36.6-36.8 K, respectively. The $T_cs$ decreased to 33.2 K and 31.6 K, respectively after irradiation at neutron fluence of $7.16{\times}10^{17}n/cm^2$, and decreased to 22.6 K and 24.0 K, respectively, at $3.13{\times}10^{18}n/cm^2$. The $J_c$ cross-over was observed at the high magnetic field of 5.2 T for the undoped $MgB_2$ irradiated at $7.16{\times}10^{17}n/cm^2$. The $T_c$ and $J_c$ variation after the neutron irradiation at various neutron fluences were explained in terms of the defect formation in the superconducting matrix by neutron irradiation.

• 한국초전도ㆍ저온공학회논문지
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• 제5권1호
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• pp.56-59
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• 2003

As electric power systems grow to supply the increasing electric power demand short-circuit current tends to increase and impose a severe burden on circuit breakers and power system apparatuses. Thus, all electric equipment in a power system has to he designed to withstand the mechanical and thermal stresses of potential short-circuit currents. Among current limiting devices, Fault Current Limiter (FCL) is expected to reduce the short-circuit current. Especially, Superconducting Fault Current Limiters (SFCL) offer ideal performance: in normal operation the SFCL is in its superconducting state and has negligible impedance, in the event of a fault, the transition into the normal conducting state passively limits the current. The SFCL using high-temperature superconductors offers a positive resolution to controlling fault-current levels on utility distribution and transmission networks. This study contributes to the EMTDC based modeling and simulation method of DC Reactor type SFCL. Single and three phase faults in the utility system with DC reactor type SFCLs have been simulated using EMTDC in order to coordinate with other equipments, and the results are discussed in detail.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2002년도 하계학술대회 논문집
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• pp.94-97
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• 2002

BSCCO (2223) compound which has the highest temperature of transition to the superconducting state in the homologous series considered is synthesized by SHS. The method exploits self-sustaining solid-flame combustion reactions which develop very high internal material temperatures over short periods. This report introduces the SHS method and its advantages and discusses its application in the synthesis of superconducting materials.

• Progress in Superconductivity
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• 제10권1호
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• pp.17-22
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• 2008

We have examined the effect of ball-milling on the superconducting properties of $MgB_2$ doped with C. The ball-milling of pre-reacted $MgB_2$ powder was carried out in dry or wet state using C or diethylenetriamine ($C_{4}H_{13}N_3$) as additives. The diethylenetriamine, whose chemical formula contains no oxygen, was chosen to avoid an excess oxidation during doping. The superconducting transition temperature (Tc) of the ball-milled or doped $MgB_2$ powders was only slightly smaller than that of undoped $MgB_2$. The critical current density (Jc) of the highly ball-milled $MgB_2$ was higher than that of C-doped $MgB_2$. The addition of diethylenetriamine was detrimental to Jc, although Tc was almost unchanged.

• Progress in Superconductivity
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• 제14권1호
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• pp.24-29
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• 2012

$(TMTSF)_2BF_4$ containing non-centrosymmetric anions is well known to exhibit a metal insulator transition around 37 K by ordering of the anions with a $q_2$=(1/2, 1/2, 1/2) wave vector. We established pressure-temperature phase diagram of the $(TMTSF)_2BF_4$ compound and showed that it can belong to the general phase diagram of the $(TMTSF)_2X$ family. Application of hydrostatic pressure decreases the anion ordering transition temperature and the superconducting state is finally stabilized below 3.77 K under 7.7 kbar. Magnetoresistance measurement on the $(TMTSF)_2BF_4$ under 7.8 kbar is performed but neither the field-induced spin-density-wave state nor the rapid oscillation is observed up to 9 T.

• 한국재료학회지
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• 제1권2호
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• pp.93-98
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• 1991

The as-grown $YBa_2Cu_3O_{7-x}$ superconducting thin films on MgO(100) substrate have been prepared by a reactive coevaporation method. The superconducting transition temperature, surface morphology and crystalline quality were examined as a function of the substrate temperature ranging from $450^{\circ}C$ to $590^{\circ}C$. From the reflection high energy electron diffraction (RHEED) analysis, it was found the film consisted of almost amorphous phase with a halo pattern deposited at the substrate temperature of $450^{\circ}C$. The film deposited at the substrate temperature of $510^{\circ}C$ consisted of polycrystalline phase, showing a broad ring pattern. On the other hand, for the film deposited at $590^{\circ}C$, RHEED showed spotty pattern indicating that this film consisted of single crystal phase. It has rough film surface due to the surface outgrowth. The surface outgrowth increased as the substrate temperature increased from $510^{\circ}C$ to $590^{\circ}C$. the surface outgrowth may be due to the anisotropic growth rate. The highest transition temperature obtained in this study was $Tc_{zero}$ of 83K with $Tc_{onset}$ of 88K for the film deposited at $590^{\circ}C$ using activated RF oxygen plasma.

• Progress in Superconductivity
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• 제13권2호
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• pp.117-121
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• 2011

We have fabricated $FeSe_x$ superconducting thin films at much different substrate temperatures of 430 and $610^{\circ}C$ on $Al_2O_3$(0001) substrates by using a pulsed laser deposition (PLD) technique. Superconducting transitions for both films were shown around 10 K, but their transition width and growth directions of grains were different. We found that superconducting tetragonal FeSe phases and non-superconducting hexagonal FeSe phases were coexisted in the sample grown at the low temperature of $430^{\circ}C$, whereas the hexagonal FeSe phase was decreased with increasing fabrication temperatures.