• Title/Summary/Keyword: Superbase

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Carbon Dioxide Absorption in a Packed Column Using Guanidine-based Superbase Solution (구아니딘계 초염기 흡수제에 의한 충진탑에서의 이산화탄소 포집 특성)

  • Choi, Young Min;Hong, Yeon Ki;You, Jong Kyun
    • Korean Chemical Engineering Research
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    • v.54 no.5
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    • pp.648-652
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    • 2016
  • The study of $CO_2$ absorption in a packed column by 1,1,3,3-tetramethylguanidine (TMG) dissolved in ethylene glycol is presented. Absorption column of inner diameter 1 in and 0.6 m length was filled with Protruded-packing $0.16in{\times}0.16in$. We investigated the effect of operating conditions on overall mass transfer coefficients as well as on $CO_2$ removal efficiency. The loading values reached at about $1.0mol_{CO2}/mol_{TMG}$. In case of absorbent with lean $CO_2$ loading, the overall mass transfer coefficient was proportional to the concentration of TMG. However, in the range of more than ${\alpha}=0.5molCO_2/molTMG$, the overall mass transfer coefficients decreased with the concentration of TMG. It is due to the increasing of mass transfer resistance in liquid phase as increasing of viscosity at higher loading values.