• 공업화학
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• 제16권5호
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• pp.648-652
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• 2005

대기압하에서 소결이 어렵다고 알려진 초이온 전도체인 $K^+$-beta-aluminas를 attrition mill을 이용하여 약 350 nm의 평균 입도를 가지는 분말로 분쇄한 후, 시편을 일축가압 성형하여 상압 하에서 동일조성의 분위기 분말을 이용하여 소결하였다. 소결온도는 $1400^{\circ}C{\sim}1650^{\circ}C$까지 $50^{\circ}C$ 간격으로 소결하였으며, 각 소결온도에서 시간에 따른 소결특성을 살펴보았다. 또한 고온에서 입자 성장 속도를 조절하기 위하여 $1600^{\circ}C$에서 zone sintering을 실시하였다. $1600^{\circ}C$와 $1650^{\circ}C$에서 소결한 경우와 $1600^{\circ}C$에서 zone sintering한 시편의 경우, 각각 약 93%와 95%의 소결 밀도를 나타내었다. $1600^{\circ}C$ 이상의 온도에서 2 h 이상 장시간 소결할 경우, 입자의 거대성장으로 인하여 소결밀도가 90% 미만으로 감소하였다.

• 대한기계학회논문집B
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• 제39권10호
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• pp.779-786
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• 2015

이 연구의 목적은 열수력 성능을 향상시키기 위하여 PCHE의 새로운 유로 형상을 제안하는 것이다. 기존의 Zigzag 유로는 굽힘점에서 유동 박리와 역류 영역의 발생으로 높은 압력손실을 가지고 있다. 이 단점을 개선하기 위하여 굽힘점에 직관영역을 삽입하였다. 또한 직관의 길이 변화가 열전달 및 압력손실에 미치는 영향을 분석하였다. 새로운 형상과 기존 Zigzag 유로의 열수력 성능을 Goodness Factor를 사용하여 정량적으로 비교하였다. 질량유량은 $1.41{\times}10^{-4}$에서 $2.48{\times}10^{-4}kg/s$까지 변화 하였다. 1mm 직관길이에서 평균 Goodness Factor는 Zigzag보다 약 25% 정도 증가되었다.

• 한국구조물진단유지관리공학회 논문집
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• 제12권5호
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• pp.109-115
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• 2008

구조물이 초고층화, 대형화 되어감에 따라 철근의 이음방법에 대한 필요성이 증대되고 있다. 현재 일반적으로 건설현장에서는 겹이음을 많이 사용하고 있으나 굵은 직경을 사용한 구조부재의 경우 겹이음 사용 시 피복두께 확보의 어려움으로 부착파괴 및 접합부의 복잡한 배근으로 인한 콘크리트 타설의 시공성 저하 등이 문제가 되고 있다. 또한 압접이음은 철근의 단부를 국부적으로 가열하여 접합하는 방식으로 압접 후 철근의 취약부분이 발생할 수 있으므로 시공현장에서의 철저한 품질관리가 요구되는 단점이 있다. 이러한 단점을 해결하고자 새로운 개념의 Up-set Coupler를 적용하였다. 본 연구에서는 기계적 이음방법 중 철근 선조립공법이나 고강도, 대직경의 철근을 사용하는 PSC구조물의 접합부에서 주로 사용되는 대표적인 이음방법인 Screw Coupler와 Up-set Coupler, 그리고 이음이 없는 철근을 사용하여 각각의 인장특성과 사용성을 실험적으로 연구하고자 한다.

• Corrosion Science and Technology
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• 제14권2호
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• pp.76-84
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• 2015

The components in ultra super critical (USC) steam turbine, which is under development for high efficient power generation, are encountering harsher solid particle erosion by iron oxide scales than ones in the existing steam turbines. Therefore, the currently used boride coating will not be able to hold effective protection from particle erosion in USC system and should be replaced by new particle erosion resistant coatings. One of the best protective coatings developed for USC steam turbine parts was found to be vanadium-boride (V-boride) coating which has a hardness of about 3000 HV, much higher than that of boride, 1600~2000 HV. In order to evaluate particle erosion resistance of the various coatings such as V-boride, boride and Cr-carbide coatings at high temperature, particle erosion test equipments were designed and manufactured. In addition, erosion particle velocity was simulated using FLUENT software based on semi-implicity method for pressure linked equations revised (SIMPLER). Based on experimental results of this work, the vanadium-boride coating was found to be superior to others and to be a candidate coating to replace the boride coating.

• 대기
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• 제25권2호
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• pp.261-270
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• 2015

Characteristics of snowfall and snow crystal habits have been investigated in the campaign of Experiment on Snow Storms At Yeongdong (ESSAY) using radiosonde soundings, Global Navigation Satellite System (GNSS), and a digital camera with a magnifier for taking a photograph of snowfall crystals. The analysis period is 6 to 14 February 2014, when the accumulated snowfall amount is 192.8 cm with the longest snowfall duration of 9 days. The synoptic situations are similar to those of the previous studies such as the Low pressure system passing by the far South of the Korean peninsula along with the Siberian High extending to northern Japan, which eventually results in the northeasterly or easterly flows and the long-lasting snowfall episodes in the Yeongdong region. In general, the ice clouds tended to exist below around 2~3 km with the consistent easterly flows, and the winds shifted to northerly~northwesterly above the clouds layer. The snow crystal habits observed in the ESSAY campaign were mainly dendrite, consisting of 70% of the entire habits. The rimed habits were frequently captured when two-layered clouds were observed, probably through the process of freezing of super-cooled droplets on the ice particles. The homogeneous habit such as dendrite was shown in case of shallow clouds with its thickness of below 500 m whereas various habits were captured such as dendrites, rimed dendrites, aggregates of dendrites, plates, rimed plates, etc in the thick cloud with its thickness greater than 1.5 km. The dendrites appeared to be dominant in the condition of cloud top temperature specifically ranging $-12{\sim}-16^{\circ}C$. However, the association of snow crystal habits with temperature and super-saturation in the cloud could not be examined in the current study. Better understandings of characteristics of snow crystal habits would contribute to preventing breakdown accidents such as a greenhouse destruction and collapse of a temporary building due to heavy snowfall, and traffic accidents due to snow-slippery road condition, providing a higher-level weather information of snow quality for skiers participating in the winter sports, and estimating more accurate snowfall amount, location, and duration with the fallspeed of solid precipitation.

• 한국지반공학회:학술대회논문집
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• 한국지반공학회 2004년도 춘계학술발표회
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• pp.137-145
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• 2004

Limestone zone in korea have been distributed to diagonal line so that it is wide from the Gangwondo to the Jeonlanamdo. The limestone cavity and fractured zone were formed by chemical weathering. Limestone cavity and fractured zone was reinforced with cemented milk(w/c=60%)by high pressure jet grouting by tripple -pipe to establish bridge foundation on the ground condition like limestone cavity. To analyze property of limestone and solid of cement milk(w/c=65%), mixed solid of cement, core NX size in the limestone cavity and fractured zone and compressive strength. Seismic tomograpy exploration was pcrforn1cd to analyze deformation modulus of limestone. The analysis suggests that deformation modulus of limestone has effect on uniaxial compressive strength, seismic velocity, seismic elasticity modulus. Average static elasticity modulus of limestone is $5.08{\times}10^5kgf/cm^2$, cement and coal mixed solid is $0.25{\times}10^5kgf/cm^2$, $0.095{\times}10^5kgf/cm^2$. Average seismic velocity of limestone is 5.240m/sec, cement and coal mixed solid is 2,211.3m/sec, 1,447.5m/sec. Average uniaxial compressive strength of limestone was $1,221.3kgf/cm^2$ and limestone specimen mixed with cement milk and solid of cement milk mixed with coal were $125.22kgf/cm^2$, $35kgf/cm^2$ each other. Average friction angle of limestone was $49.14^{\circ}$ and limestone specimen mixed with cement milk and solid of cement milk mixed with coal were $38.39^{\circ}, 25.83^{\circ}$ each other. Average cohesion of limestone was $137.7kgf/cm^2$ and limestone specimen mixed with cement milk and solid of cement milk mixed with coal were $23.5kgf/cm^2$, $15.5kgf/cm^2$ each other. Average deformation modulus of limestone was $2.84{\times}10^5kgf/cm^2$ and limestone specimen mixed with cement milk and solid of cement milk mixed with coal were $0.4{\times}10^5kgf/cm^2, 0.12{\times}10^5kgf/cm^2$ each other. It was analyzed that the elasticity and uniaxial compressive strength, seismic velocity of solid of cement milk mixed limestone pieces and coal had an highly interrelation regardless of existence of limestones pieces and coal but it had shown that limestones had an lower interrelation. In case of field seismic velocity and deformation of limestone, SIC solid of cement milk mixed with coal and limestone pieces had an highly interrelation.

• 한국재료학회지
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• 제12권12호
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• pp.941-946
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• 2002

Both Cu and Cu-oxide nanopowders have great potential as conductive paste, solid lubricant, effective catalysts and super conducting materials because of their unique properties compared with those of commercial micro-sized ones. In this study, Cu and Cu-oxide nanopowders were prepared by Pulsed Wire Evaporation (PWE) method which has been very useful for producing nanometer-sized metal, alloy and ceramic powders. In this process, the metal wire is explosively converted into ultrafine particles under high electric pulse current (between $10^4$ and $10^{ 6}$ $A/mm^2$) within a micro second time. To prevent full oxidations of Cu powder, the surface of powder has been slightly passivated with thin CuO layer. X-ray diffraction analysis has shown that pure Cu nanopowders were obtained at $N_2$ atmosphere. As the oxygen partial pressure increased in $N_2$ atmosphere, the gradual phase transformation occurred from Cu to $Cu_2$O and finally CuO nanopowders. The spherical Cu nanopowders had a uniform size distribution of about 100nm in diameter. The Cu-oxide nanopowders were less than 70nm with sphere-like shape and their mean particle size was 54nm. Smaller size of Cu-oxide nanopowders compared with that of the Cu nanopowders results from the secondary explosion of Cu nanopowders at oxygen atmosphere. Thin passivated oxygen layer on the Cu surface has been proved by XPS and HRPD.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2011년도 제40회 동계학술대회 초록집
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• pp.21-21
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• 2011

A series of Quasi-Elastic Neutron Scattering (QENS) experiments helps us to understand the single-particle (hydrogen atom) dynamics of a globular protein and its hydration water and strong coupling between them. We also performed Molecular Dynamics (MD) simulations on a realistic model of the hydrated hen-egg Lysozyme powder having two proteins in the periodic box. We found the existence of a Fragile-to-Strong dynamic Crossover (FSC) phenomenon in hydration water around a protein occurring at TL=$225{\pm}5K$ by analyzing Intermediate Scattering Function (ISF). On lowering of the temperature toward FSC, the structure of hydration water makes a transition from predominantly the High Density Liquid (HDL) form, a more fluid state, to predominantly the Low Density Liquid (LDL) form, a less fluid state, derived from the existence of a liquid?liquid critical point at an elevated pressure. We showed experimentally and confirmed theoretically that this sudden switch in the mobility of the hydration water around a protein triggers the dynamic transition (so-called glass transition) of the protein, at a temperature TD=220 K. Mean Square Displacement (MSD) is the important factor to show that the FSC is the key to the strong coupling between a protein and its hydration water by suggesting TL${\fallingdotseq}$TD. MD simulations with TIP4P force field for water were performed to understand hydration level dependency of the FSC temperature. We added water molecules to increase hydration level of the protein hydration water, from 0.30, 0.45, 0.60 and 1.00 (1.00 is the bulk water). These confirm the existence of the FSC and the hydration level dependence of the FSC temperature: FSC temperature is decreased upon increasing hydration level. We compared the hydration water around Lysozyme, B-DNA and RNA. Similarity among those suggests that the FSC and this coupling be universal for globular proteins, biopolymers.

• 한국재료학회지
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• 제1권3호
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• pp.156-167
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• 1991

본 연구의 목적은 항공기용 터어보팬 엔진의 재료선정을 위한 데이타 베이스를 구축하는 것이다. 터어보팬 엔진은 고성능이면서도 연료소모율이 적어 경제적인 운용이 가능하므로 최근 여러 용도로 사용되고 있는 엔진이다. 현재 서로 다른 특성을 가진 수백종의 초내열재료들이 개발되어 있는데, 한 엔진설계자가 어떤 엔진요소에 사용할 재료를 선택한다는 것은 매우 어려운 작업이다. 따라서 수 많은 재료에 대한 정보를 관리할 수 있는 데이타 베이스가 절실히 요구되고 있으나, 국내에서는 아직 이 방면의 기초연구가 이루어져 있지 않은 실정이다. 본 연구에서는 재료공학적 관점에서 초내열재료의 대표적 성질로서 고온강도, 내식성, 내산화성, 항복강도, 열팽창계수, 융정등을 고려해서 후보재료를 선정할 수 있도록 하였다. 이외에도 성 형성이나 제조단가등도 고려해야할 변수가 된다. 본 연구에 의해 사용자의 편의를 고려한 전산프로그램이 개발되었으며, 이를 이용하여 새로운 재료정보의 입력, 요구 재료선정 및 선정결과의 출력등이 가능하다. 끝으로 선정된 재료에 대한 성능검토도 실시하였다.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2012년도 제43회 하계 정기 학술대회 초록집
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• pp.375-375
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• 2012

Graphene is a sp2-hybridized carbon sheet with an atomic-level thickness and a wide range of graphene applications has been intensely investigated due to its unique electrical, optical, and mechanical properties. In particular, hybrid graphene structures combined with various nanomaterials have been studied in energy- and sensor-based applications due to the high conductivity, large surface area and enhanced reactivity of the nanostructures. Conventional metal-catalytic growth method, however, makes useful applications difficult since a transfer process, used to separate graphene from the metal substrate, should be required. Recently several papers have been published on direct graphene growth on the two dimensional planar substrates, but it is necessary to explore a direct growth of hierarchical nanostructures for the future graphene applications. In this study, uniform graphene layers were successfully synthesized on highly dense dielectric nanowires (NWs) without any external catalysts. We also demonstrated that the graphene morphology on NWs can be controlled by the growth parameters, such as temperature or partial pressure in chemical vapor deposition (CVD) system. This direct growth method can be readily applied to the fabrication of nanoscale graphene electrode with designed structures because a wide range of nanostructured template is available. In addition, we believe that the direct growth growth approach and morphological control of graphene are promising for the advanced graphene applications such as super capacitors or bio-sensors.