• Title/Summary/Keyword: Sulfuric acid loop

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Development of a Compact Nuclear Hydrogen Coupled Components Test Loop (원자로수소생산을 위한 연결부품 실험용 소형 컴팩트 실험장치 개발)

  • Hong, S.D.;Kim, J.H.;Kim, C.S.;Kim, Y.W.;Lee, W.J.
    • Proceedings of the KSME Conference
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    • 2008.11b
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    • pp.2850-2855
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    • 2008
  • Very High Temperature Reactor (VHTR) has been selected as a high energy heat source for a nuclear hydrogen generation. The VHTR heat is transferred to a thermo-chemical hydrogen production process through an intermediate loop. Both Process Heat Exchanger and sulfuric acid evaporator provide the coupled components between the VHTR intermediate loop and hydrogen production module. A small scaled Compact Nuclear Hydrogen Coupled Components test loop is developed to simulate the VHTR intermediate loop and hydrogen production module. Main objective of the loop is to screening the candidates of NHDD (Nuclear Hydrogen Development and Demonstration) coupled components. The operating condition of the gas loop is a temperature up to $950^{\circ}C$ and a pressure up to 6.0MPa. The thermal and fluid dynamic design of the loop is dependent on the structures that enclose the gas flow, especially primary side that has fast gas velocity. We designed and constructed a small scale sulfuric acid experimental system which can simulate a part of the hydrogen production module also.

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A DYNAMIC SIMULATION OF THE SULFURIC ACID DECOMPOSITION PROCESS IN A SULFUR-IODINE NUCLEAR HYDROGEN PRODUCTION PLANT

  • Shin, Young-Joon;Chang, Ji-Woon;Kim, Ji-Hwan;Park, Byung-Heung;Lee, Ki-Young;Lee, Won-Jae;Chang, Jong-Hwa
    • Nuclear Engineering and Technology
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    • v.41 no.6
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    • pp.831-840
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    • 2009
  • In order to evaluate the start-up behavior and to identify, through abnormal operation occurrences, the transient behaviors of the Sulfur Iodine(SI) process, which is a nuclear hydrogen process that is coupled to a Very High Temperature Gas Cooled Reactor (VHTR) through an Intermediate Heat Exchanger (IHX), a dynamic simulation of the process is necessary. Perturbation of the flow rate or temperature in the inlet streams may result in various transient states. An understanding of the dynamic behavior due to these factors is able to support the conceptual design of the secondary helium loop system associated with a hydrogen production plant. Based on the mass and energy balance sheets of an electrodialysis-embedded SI process equivalent to a 200 $MW_{th}$ VHTR and a considerable thermal pathway between the SI process and the VHTR system, a dynamic simulation of the SI process was carried out for a sulfuric acid decomposition process (Second Section) that is composed of a sulfuric acid vaporizer, a sulfuric acid decomposer, and a sulfur trioxide decomposer. The dynamic behaviors of these integrated reactors according to several anticipated scenarios are evaluated and the dominant and mild factors are observed. As for the results of the simulation, all the reactors in the sulfuric acid decomposition process approach a steady state at the same time. Temperature control of the inlet helium is strictly required rather than the flow rate control of the inlet helium to keep the steady state condition in the Second Section. On the other hand, it was revealed that the changes of the inlet helium operation conditions make a great impact on the performances of $SO_3$ and $H_2SO_4$ decomposers, but no effect on the performance of the $H_2SO_4$ vaporizer.