• Title/Summary/Keyword: Sulfur contents

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Optimization of Cure System for the ESBR Silica WMB and BR Silica DMB Blend Compounds

  • Yu, Eunho;Kim, Woong;Ryu, Gyeongchan;Ahn, Byungkyu;Mun, Hyunsung;Hwang, Kiwon;Kim, Donghyuk;Kim, Wonho
    • Elastomers and Composites
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    • v.54 no.2
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    • pp.97-104
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    • 2019
  • Emulsion styrene-butadiene rubber silica wet masterbatch (ESBR silica WMB) technology was studied to develop highly filled and highly dispersed silica compounds, involving the preparation of a composite by co-coagulating the modified silica and the rubber latex in a liquid phase. Previous studies have shown that when manufacturing ESBR silica WMB/Butadiene silica dry masterbatch (BR silica DMB) blend compounds, preparing BR silica dry masterbatch and mixing it with ESBR silica WMB gave excellent results. However, WMB still has the problem of lower crosslink density due to residual surfactants. Therefore, in this study, tetrabenzylthiuram disulfide (TBzTD) was added instead of diphenyl guanidine (DPG) in the ESBR silica WMB/BR silica DMB blend compounds and sulfur/CBS contents were increased to evaluate their cure characteristics, crosslink densities, mechanical properties, and dynamic viscoelastic properties. TBzTD was found to be more effective in increasing the crosslink density and to produce superior properties compared to DPG. In addition, with increasing sulfur/CBS contents, mechanical properties and rolling resistance were enhanced due to high crosslink density, but the abrasion resistance was not significantly changed because of the toughness.

High Temperature Corrosion Properties of Heat Resistant Chrome Steels in SO2 Atmosphere (고온 이산화황 환경 내 내열 크롬강에 대한 부식특성 연구)

  • Lee, Han-sang;Jung, Jine-sung;Kim, Eui-hyun
    • Korean Journal of Metals and Materials
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    • v.47 no.2
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    • pp.99-106
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    • 2009
  • The high temperature corrosion properties of heat resistant steels were investigated in oxidation atmosphere including sulfur dioxide. The heat resistant steels of T22, T92, T122, T347HFG and T304H were evaluated at 620, $670^{\circ}C$ for 400 hours. The corrosion rates showed a decreasing tendency while chrome contents of those steels increased from 2 mass.% to 19 mass.%. The in crease in temperature increasement has an more effect on the corrosion rates of low chrome steels than high chrome steels. The weight gains of T22, T92, T304H at $670^{\circ}C$ were 3.7, 1.65, 1.23 times compared with those at $620^{\circ}C$. The external scale formed on T22 was composed of hematite, magnetite and Fe-Cr spinel and internal layer including iron oxide mixed with sulfide. The scales formed on T92, T122, T304H consisted of an outer layer of hematite and inner layer of chrome oxide and hematite. The proportion of chrome oxide at inner layer was increased when the chrome contents in heat resistant steels were increased.

Effects of Sulfuric Fertilizers on Growth and Allylisothiocyanate Contents of Wasabia japonica $M_{ATSUM}$ Cultivated in Heating Condition (고추냉이 밭재배시 함황비료 처리에 따른 생육 및 Allylisothiocyanate 함량)

  • Moon, Jung-Sub;Song, Young-Ju;Ko, Bok-Rae;Kim, Dong-Won;Sung, Moon-Ho
    • Korean Journal of Medicinal Crop Science
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    • v.7 no.1
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    • pp.31-36
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    • 1999
  • This study was carried out to investigate the effect of sulfuric fertilizers on allylisothiocyanate(allylNCS) content of upland Wasabia japonica Matsum cultivated in heating condition in the winter season. The rhizome's growth characters following soil application of sulfur dust were not significantly different compared to control, though its soil acidity and available sulfur content was higher than other treatments. Total sulfur content of plant was increased by soil application as compared to foliar application and allylNCS content of rhizome increased up to 22.8% in the sulfur dust treatment. The result showed that soil application was effective for supplying $SO_4^{-2}$ in upland Wasabia japonica Matsum when cultivated in heating condition. In the analysis of correlation coefficients between growth and quality characteristics, allylNCS content of rhizome showed the significantly positive correlation with total sulfur content of shoot, rhizome and allylNCS content of shoot.

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Estimation of Relative Air Pollution by the Contents of S. Pb and Cd in Leaves of Roadside Trees in Taejon (가로수 잎의 S 및 중금속 함량에 의한 대기 오염도 추정)

  • Oh, In-Hye
    • The Korean Journal of Ecology
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    • v.16 no.2
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    • pp.199-208
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    • 1993
  • To estimate the level of the air pollution in Taejon city, the contents of S, Pb and Cd of the leaves of the roadside trees were deterimined. And we analyzed the relationship between the contents of S, Pb and Cd in the leaves of the roadside trees and traffic volume. The ranges of S, Pb and Cd contents in all the samples were 1.82~4.34 mg/g, 1.95~$246.80{\mu}g/g$ and 2.00~$20.50{\mu}g/g$ respectively. Areas with the high contents of S, Pb and Cd in the leaves were the road from Taejon railroad station to the provincial government, West Taejon crossroad, Taehwa-dong, Kasuwon-dong and Yongmun crossroad.

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Component Analysis and Metallurgical Study of Bronze Bell in the Naksan-sa (낙산사 동종의 성분분석 및 금속학적 고찰)

  • Hwang, Jin-Ju;Han, Min-Su
    • 보존과학연구
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    • s.26
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    • pp.27-40
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    • 2005
  • This study is to be investigated through component analysis and metallurgical texture in order to save an information of the manufacturing technique for the bronze bell in Naksan-sa. The bronze bell was analyzed with nine samples not stirred by the fire and except the contents of tin is the maximum and minimum the average of Cu is 81.8wt%, Sn is15.8wt% and indicates that some impurities are in it. With the result of an analysis of component and microtexture for impurities material which exists in it with using the SEM-EDS, the material was revealed the sulfur. As the result of these factors, the bronze bell of Naksan-sa is used from ore which mainly consist of the Chalcopyrite($CuFeS_2$) or Bornite($Cu_5FeS_4$) containing much sulfur.

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Study on Performance and An Exhaust Emission by Bio-Diesel Deterioration and Engine Load Rate at Heavy-Duty Diesel Engine (대형디젤기관에서 바이오디젤 열화와 엔진부하에 따른 배출가스특성 및 성능에 관한 연구)

  • Park, Man-Jae;Kim, Mi-Soo
    • Transactions of the Korean Society of Machine Tool Engineers
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    • v.16 no.3
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    • pp.56-63
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    • 2007
  • Modern diesel vehicle has to comply with the EURO IV, V regulation with low level of particulate matter and smoke emission Moreover, emission standards of each countries are becoming stringent in advanced countries such as USA and Europe. Because Bio-diesel is similar to diesel fuel, it is essential to judge the environmental and health effects deriving from the use of Bio-diesel in diesel engine. The deterioration characteristics of emission in accordance with aging vehicles must be regulated for Bio-diesel. Therefore, under 1200 driving hours, 220,000km driving distance condition and full load, the deterioration characteristics of emission were estimated. We could reduce sulfur contents of fuel, particulate matter and smoke emission by using Bio-diesel and conform the influence of engine performance, emission, and fuel consumption by Bio-diesel deterioration

Extraction of Deasphalted Oil from Vacuum Residue (감압잔사유로부터 탈아스팔트오일의 추출)

  • 백일현;김춘호;김성현;김영일;홍성선
    • Journal of Energy Engineering
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    • v.2 no.1
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    • pp.68-74
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    • 1993
  • In order to maximize the utility of vacuum residue, supercritical solvent extraction technique where n-pentane was used as a supercritical solvent was applied to obtain deasphalted oil from vacuum residue. Oil-extraction yield at various temperatures and pressures and the contents of metal complex and sulfur of extracted oil were investigated. In supercritical state, extraction yield of deasphalted oil was found to be strongly dependent on the n-pentane density, and the metal complex content of extracted oil was effectively lowered when compared with that of vacuum residue. However, the sulfur content of extracted oil showed little difference when compared with that of vacuum residue.

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Effect of Mn and S Contents on Edge Cracking of Low Carbon Steels in Mini-Mill Process (미니밀공정 중 저탄소강의 에지크랙에 미치는 Mn 및 S의 영향)

  • 곽재현;정진환;조경목
    • Transactions of Materials Processing
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    • v.9 no.1
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    • pp.66-71
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    • 2000
  • The present study tackles the metallurgical subjects involving the thin slab-direct hot rolling process, i.e. mini-mill process. In order to clarify the effect of chemical composition of steel and MnS precipitation behaviors on the development of edge cracking during hot rolling, the content of manganese and sulfur in low carbon steel was varied and the isothermal treatment prior to roughing was applied. Edge cracking during roughing in the hot-rolling process of mini-mill was effectively prevented by means of the isothermal treatment at 115$0^{\circ}C$ for 5 minutes in the 0.4% manganese steel containing sulfur lower than 0.013%. With the increase in manganese content in low carbon steel, coarser MnS developed. The edge cracking index which denotes the total length of edge crack per unit edge-length of rolled specimens was proposed in this paper. It was found that the edge cracking index linearly decreased with the increase in the ratio of MnS.

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Effect of catalyst poison agents on the hydrogenation of soybean oil (촉매독이 대두유의 경화에 미치는 영향)

  • Lee, Sur-Koo;Kim, Chang-Sik
    • Applied Biological Chemistry
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    • v.36 no.2
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    • pp.93-98
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    • 1993
  • The purpose of this study is to determine the physicochemical properties in soybean oil during the hydrogenation by addition of phosphorus compounds and sulfur compounds is increased in soybean oil, decreased oleic acid and increased linoleic acid and stearic acid contents were found. When the sulfur compounds content is increased, solid fat content is increased at $10.0^{\circ}C$ and $21.1^{\circ}C$ and gradually decreased at $33.3^{\circ}C$ and $37.8^{\circ}C$. Higher melting point in hydrogenated soybean oil is observed on addition of phosphorus compounds compared to addition of sulfur compounds. When the sulfur compounds content is increased, conditions of selective hydrogenation are observed. Lead and arsenic are detected at a concentration of 0.01 ppm in a few kinds at each step of the refining process of soybean oil.

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A Study on Variations of Halitosis According to Sodium Lauryl Sulfate Content of Toothpaste (세치제의 Sodium Lauryl Sulfate 함유정도에 따른 구취변화)

  • Jeong, Hwa-Young;Jeong, Sang-Hee;Jeong, Mi-Ae
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.11 no.8
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    • pp.2935-2941
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    • 2010
  • This study used 3 kinds of experimental toothpaste with different contents(0%, 1.1%,2.2% of SLS. A total of 150 young adults in their 20's without any systemic disease were recruited for the study. These 150 subjects were subdivided into three groups(each having 50 subjects) according to the results of preliminary oral examination.After 4 weeks application of the three groups of toothpaste, Group C showed the highest halitosis index, followed by Groups A and B which had similar halitosis indices. Both oral sulfur compound and aerobic sulfur compound were measured at high content possibly because higher SLS content which is associated with the lower salivary flow rate is causing the xerostomia. SLS content was correlated with oral sulfur compound (r=0.412) and aerobic sulfur compound (r=0.285).