• 제목/요약/키워드: Substitution Degree

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셀룰로오스 카보네이트 유도체로부터 재생 셀룰로오스 섬유의 제조(VI. 셀룰로오스 카보네이트의 치환도 및 용해도 평가) (Preparation of Regenerated Cellulose Fiber from the Cellulose Carbonate Derivative(VI. Degree of substitution and estimation of solubility))

  • 오상연;류동일;신윤숙;김환철;김학용;정용식
    • 한국섬유공학회:학술대회논문집
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    • 한국섬유공학회 2003년도 봄 학술발표회 논문집
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    • pp.299-300
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    • 2003
  • 본 연구자들은 이산화탄소($CO_2$)에 의한 셀룰로오스 카보네이트의 제조 및 재생 셀룰로오스 섬유 제조에 대한 몇몇 기초 연구성과를 발표한 바 있다[1, 2]. 이번 연구에서는 이산화탄소와의 반응을 통해 제조된 셀룰로오스 카보네이트 유도체의 치환도 변화에 따른 용해성을 평가하고 상그림표를 작성하였다. (중략)

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기업용데이터서비스 간 대체성 분석 및 신규서비스 포지셔닝 전략 제언

  • 유광숙;최문기
    • 한국경영과학회:학술대회논문집
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    • 한국경영과학회 2001년도 추계학술대회 논문집
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    • pp.350-353
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    • 2001
  • As different service classifications for existing and new business data services, it is hard to gather necessary data for the service providers to set their strategies and regulations are also applied asymmetrically to each service provider. Therefore an appropriate market classification is required for the business data services. The Hendry model is selected in this paper to analyze substitution degree among services and then Hendry model is applied to competition among four business data services. As a result, it is shown that these services compete directly and future market shares of services are forecasted and positioning strategy for new services is considered.

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비선형 미분방정식으로 표현되는 비선형 시스템의 해석을 위한 볼테리 시리즈의 응용 (Application of Volterra Functional Series to the Analysis of Nonlinear Systems Represented by Nonlinear Differential Equations)

  • Sung, Dan-Keun
    • 대한전자공학회논문지
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    • 제25권3호
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    • pp.315-321
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    • 1988
  • The input-output relation for nonlinear systems can e explicitly represented by the volterra functional series and it is characterized by the Volterra kernels. A block diagram reduction method is proposed to determine the Volterra kernels for nonlinear differential equations and is compared with the direct substitution techniques. The former method can significantly reduce the computational complexity. A degree of nonlinearity is defined and analyzed for the analysis of nonlinear systems.

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CMC섬유내의 양이온이 섬유의 흡습성과 인장 성질에 미치는 영향 (Effect of Cations on the Sorption and the Tensile Properties of CMC Fibers)

  • 이미식
    • 한국의류학회지
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    • 제18권1호
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    • pp.113-120
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    • 1994
  • The Purpose of this study was to improve the moisture related properties of viscose rayon fibers. Viscose rayon filament yarns were partially etherified to make CMC fibers. CMC fibers were converted to the sodium, calcium, and ferric salt forms by an ion exchange method. The property changes of ion exchanged CMC fibers were examined. Cation contents of fibers were varied depending on the degree of substitution of CMC fibers. The strength of Na, Ca, Fe-CMC was higher than H-CMC owing to the plasticization by moisture sorption and the crosslinking by cations. The moisture regain was increased by carboxymethylation and that of Fe-CMC showed the highest value. The degree of swelling determined by the water retention value was observed to be Na-CMC > Ca-CMC > H-CMC > Fe-CMC. The solution retention value was decreased in the order . Ca-CMC > Na-CMC > H-CMC > Fe-CMC.

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펄프몰드용 새로운 고기능 코팅제 제조기술개발(제3보) -코팅용 전분유도체 제조- (Development of Higher Functional Coating Agents for Pulp Mold (III) Manufacture of starch derivatives for coating -)

  • 강진하;임현아
    • 펄프종이기술
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    • 제36권4호
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    • pp.49-59
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    • 2004
  • This study was carried out to obtain the basic data for producing higher functional coating agents for pulp mold by evaluating various kinds of starch derivatives. At that time, four kinds of starch derivatives were manufactured for making coating agents respectively. Physical properties of coated paperboards were tested. Conclusions obtained from this results were as follows. The water and oil resistance of hydroxypropylated, cyanoethylated and carboxymethy­lated starch were high when degree of molar substitution(DS) of propylene oxide, acrylonitrile and sodium monochloroacetate were 0.18, 0.07 and 0.009, respectively. Also, the those of crosslinked starch were high when degree of crosslinking of epichlorohydrin was 0.02. Consequently, $8\%$ solution of carboxymethylated starch made with DS 0.009 of monochloroacetate was the best among coating agents from starch derivatives men­tioned above.

CMC의 물성이 도공액의 특성에 미치는 영향 (Effect of Properties of CMC on the Characteristics of Coating Color)

  • 박종열;김병수;정현채
    • Journal of the Korean Wood Science and Technology
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    • 제24권4호
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    • pp.82-86
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    • 1996
  • This study was performed to elucidate the effect of degree of substitution and degree of polymerization of CMC on the rheological characteristics of coating color which is consisted of calcium carbonate as pigment. The results were as follows: 1. It appeared that DP of CMC rather DS has an effect on the low shear viscosity of coating color. 2. According as shear rate increased, the effect of DP and DS on high shear viscosity of coating color decreased. 3. According to increasing DS and DP, the water retention of coating color increased.

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Hydration properties of cement pastes containing high-volume mineral admixtures

  • Tang, Chao-Wei
    • Computers and Concrete
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    • 제7권1호
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    • pp.17-38
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    • 2010
  • This research aimed to investigate the influence of high-volume mineral admixtures (MAs), i.e., fly ash and slag, on the hydration characteristics and microstructures of cement pastes. Degree of cement hydration was quantified by the loss-on-ignition technique and degree of pozzolanic reaction was determined by a selective dissolution method. The influence of MAs on the pore structure of paste was measured by mercury intrusion porosimetry. The results showed that the hydration properties of the blended pastes were a function of water to binder ratio, cement replacement level by MAs, and curing age. Pastes containing fly ash exhibited strongly reduced early strength, especially for mix with 45% fly ash. Moreover, at a similar cement replacement level, slag incorporated cement paste showed higher degrees of cement hydration and pozzolanic reaction than that of fly ash incorporated cement paste. Thus, the present study demonstrates that high substitution rates of slag for cement result in better effects on the short- and long-term hydration properties of cement pastes.

해안상의 토목섬유 수평배수재의 적용 (Application of Prefabricated Horizontal Drains to Marine Clayey Soils)

    • 한국항만학회지
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    • 제12권2호
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    • pp.329-336
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    • 1998
  • Sandmats are used to dissipate trapped water rapidly from the embankment built on marine soft ground. At present, however, it becomes difficult to obtain qualified sands since natural resources such as river sand are to exhausted. Also, low permeability of sand may cause low degree of consolidation and instability of embankment. In this study, design and construction methods was discussed. Drainage capacities of prefabricated horizontal drains which were installed in highway construction site are investigated in order to find possible substitution for river sands as drainage materials. On the basis of measurement data at the construction site, it was concluded that use of the prefabricated horizontal drains shows satisfactory drainage capacity without instability of embankment.

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Structure-Reactivity Relationship of Substituted Phenylethyl Arenesulfonates with Substituted Pyridines under High Pressure

  • 박헌영;손기주;정덕영;여수동
    • Bulletin of the Korean Chemical Society
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    • 제18권9호
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    • pp.1010-1013
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    • 1997
  • Nucleophilic substitution reactions of (Z)-phenylethyl (X)-benzenesulfonates with (Y)-pyridines were investigated in acetonitrile at 60 ℃ under respective pressures. The magnitudes of the Hammett reaction constants, ρX, ρY and ρZ indicate that a stronger nucleophile leads to a greater degree of bond formation of C-N and a better leaving group is accompanied by a less degree of bond breaking. The magnitude of correlation interaction term, ρij can be used to determine the structure of the transition state (TS) for the SN reaction. As the pressure is increased, the Hammett reaction constants, ρX and |ρY|, are decreased, but correlation interaction coefficient, ρXZ and |ρYZ|, are increased. The results indicate that the reaction of (Z)-phenylethyl (X)-benzenesulfonates with (Y)-pyridines probably moves from a dissociative SN2 to early-type concerted SN2 mechanism by increasing pressure. This result shows that the correlation interaction term ρij can be useful tool to determine the structure of TS, and also the sign of the product ρXZ·ρYZ can be predict the movement of the TS.

치환도가 초산 고구마전분의 물리적 특성에 미치는 영향 (Physical Properties of Acetylated Sweet Potato Starches as Affected by Degree of Substitution)

  • 유병승;이혜린
    • 한국식품영양과학회지
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    • 제40권7호
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    • pp.1048-1052
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    • 2011
  • 각기 다른 치환도를 가진 초산 고구마전분 페이스트의 유동특성 및 투과도 그리고, 이들 전분 겔의 냉.해동안정성 및 강도가 치환도의 함수로 분석되었다. 유동특성 측정 결과 power law 모델식과 Casson 모델식에 잘 적용되었으며, 높은 shear-thinning 거동을 가지고 있는 것으로 나타났다. 특정한 온도 범위($25{\sim}70^{\circ}C$)에서 전분 페이스트의 겉보기 점도($\eta_{a,100}$)의 온도 의존성은 Arrhenius 모델식에 잘 적용되었으며 초산 고구마전분이 천연전분에 비해 더 낮은 온도 의존성을 나타내었다. 전분 페이스트 이수현상 측정에서는 초산화에 의해 이수현상이 감소하는 것으로 나타났으며, 치환도가 증가할수록 낮아지는 것으로 나타났다. 겔 강도 측정에서도 초산화에 의해 겔 강도가 감소하는 것으로 나타났으며, 치환도가 증가할수록 겔 강도는 감소하는 것으로 나타났다. 페이스트 투과도(% T) 측정에서 초산전분은 천연전분 보다 투과도가 높은 것으로 나타났다.