• Journal of Korea Water Resources Association
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• v.37 no.2
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• pp.163-172
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• 2004

In this paper, the sub-soil storage system for utilizing urban instream flow of rainfall runoff was developed and examined through experiments. The artificial rainfall facility and sub-soil storage were installed in the experimental area. The effect of the water qualify improvement and the storage effect were analyzed through the several experiments. Through the experiments of rainfall intensity variation, which are the rainfall intensity of 20mm/hr, 30mm/hr, 40mm/hr, 50mm/hr was indicated SS concentration can be reduction until 68％. Also, the ration of the storage volume is varied from 42.8％∼79.9％ based on the rainfall intensity. The reduction rate of the BOD, CO $D_{Mn}$, SS, T-N, T-P was 30％, 42％, 68％, 39％, 26％. As the result, water quality of runoff and efficient of runoff reduction by the system are much improved. The rainfall runoff with the installation of sub-soil storage could be used for instream flow.

• Journal of Ecology and Environment
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• v.29 no.1
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• pp.23-27
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• 2006

This study was conducted to evaluate forest carbon cycling and soil $CO_2$ efflux rates in a 42-year-old pine (Pinus densiflora) stand located in Hamyang-gun, Korea. Aboveground and soil organic carbon storage, litterfall, litter decomposition, and soil $CO_2$ efflux rates were measured for one year. Estimated aboveground biomass carbon storage and increment in this stand were $3,250gC/m^2\;and\;156gC\;m^{-2}yr^{-1}$, respectively. Soil organic carbon storage at the depth of 30 cm was $10,260gC/m^2$ Mean organic carbon inputs by needle and total litterfall were $176gC\;m^{-2}yr^{-1}\;and\;235gC\;m^{-2}yr^{-1}$, respectively. Litter decomposition rates were faster in nne roots less than 2 mm diameter size ($<220\;g\;kg^{-1}yr^{-1}$) than in needle litter ($<120\;g\;kg^{-1}yr^{-1}$). Annual mean and total soil respiration rates were $0.37g\;CO_2m^{-2}h^{-1}$ and $2,732g\;CO_2m^{-2}yr^{-1}$ during the study period. A strong positive relationship existed between soil $CO_2$ efflux and soil temperature (r=0.8149), while soil $CO_2$ efflux responded negatively to soil pH (r=-0.3582).

• Journal of Soil and Groundwater Environment
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• v.21 no.1
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• pp.49-60
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• 2016

Distribution and behavior of baseline soil CO₂ were investigated in a candidate geologic CO₂ storage site in Pohang, with measuring CO₂ concentrations and carbon isotopes in the vadose zone as well as CO₂ fluxes and concentrations through ground surface. This investigation aimed to assess the baseline CO₂ levels and to build the CO₂ monitoring system before injecting CO₂. The gas in the vadose zone was collected using a peristaltic pump from the depth of 60 cm below ground surface, and stored at gas bags. Then the gas components (CO₂, O₂, N₂, CH₄) and δ¹³C_CO2 were analyzed using GC and CRDS (cavity ringdown spectroscopy) respectively in laboratory. CO₂ fluxes and CO₂ concentrations through ground surface were measured using Li-COR in field. In result, the median of the CO₂ concentrations in the vadose zone was about 3,000 ppm, and the δ¹³C_CO2 were in the wide range between −36.9‰ and −10.6‰. The results imply that the fate of CO₂ in the vadose zone was affected by soil property and vegetations. CO₂ in sandy or loamy soils originated from the respiration of microorganisms and the decomposition of C₃ plants. In gravel areas, the CO₂ concentrations decreased while the δ¹³C_CO2 increased because of the mixing with the atmospheric gas. In addition, the relation between O₂ and CO₂, N₂, and the relation between N₂/O₂ and CO₂ implied that the gases in the vadose zone dissolved in the infiltrating precipitation or the soil moisture. The median CO₂ flux through ground surface was 2.9 g/m²/d which is lower than the reported soil CO₂ fluxes in areas with temperate climates. CO₂ fluxes measured in sandy and loamy soil areas were higher (median 5.2 g/m²/d) than those in gravel areas (2.6 g/m²/d). The relationships between CO₂ fluxes and concentrations suggested that the transport of CO₂ from the vadose zone to ground surface was dominated by diffusion in the study area. In gravel areas, the mixing with atmospheric gases was significant. Based on this study result, a soil monitoring procedure has been established for a candidate geologic CO₂ storage site. Also, this study result provides ideas for innovating soil monitoring technologies.

• Journal of the Korean Institute of Landscape Architecture
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• v.23 no.3
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• pp.80-93
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• 1995

The purpose of this study was to assess functioni fo urban greenspace to reduce atmospheric CO\sub 2\ concentration. The study quantified carbon storage in urban greenspace and carbon emission by fossil fuel consumptio in Chuncheon. The amount of carbon storage in vegetation by land use type was 0.02kg/$m^2$ for commercial land, 4.36kg/$m^2$ for natural land, and 0.54kg/$m^2$ for the other urban lands. In 1994, total amount of carbon emission by fossil fuel consumption was about 257,358 metric tons, and the per capita carbon emission was 1.4 metric ton. Total amount of carbon storage in vegetation was 42,942 metric tons, approximately 17% of the carbon emission. This study excluded quantification of carbon storage in soils. The role of urban greenspace to sequester atomspheric carbon might be much greater, if a soil greenspace to sequester atmospheric carbon might be much greater, if a soil greenspace to sequester atmospheric carbon might be much greater, if a soil carbon storage is included quantification of carbon storage is included. However, increasing coverage of trees and managing them for healthy growth would not be sufficient for avoiding adverse impacts by future climate change. Additional measures should be followed such as an increase of energy use efficiency and development of substitute energy.

• Journal of Soil and Groundwater Environment
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• v.20 no.1
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• pp.41-55
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• 2015

Monitoring of $CO_2$ release through the ground surface is essential to confirm the safety of carbon storage projects. We conducted a feasibility study of the multi-channel surface-soil $CO_2$-concentration monitoring (SCM) system as a soil $CO_2$ monitoring tool with a small scale injection test. The background concentrations showed the distinct diurnal variation. The negative relation of $CO_2$ with temperature and the low $CO_2$ concentrations during the day imply that surface-soil $CO_2$ depends on photosynthesis and respiration. After 4.2 kg of $CO_2$ injection (1 m depth for 29 minutes), surface-soil $CO_2$ concentrations increased in the all five chambers, which were located less than 2.8 m of distance from each other. The $CO_2$ concentrations seem to be recovered to the background around 4 hours after the injection ended. To determine the leakage, the data from Chamber 2 and 5 with low increase rates were used for statistical analyses. Coefficient of variation for 30 minutes ($CV_{30min}$.) is efficient to determine a leakage signal, with reflecting the fast change in $CO_2$ concentrations. Consequently, SCM and $CV_{30min}$ could be applied for an efficient monitoring tool to detect $CO_2$ release through the ground surface. Also, this study provides ideas for establishing action steps after leakage detection.

• Economic and Environmental Geology
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• v.55 no.4
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• pp.407-419
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• 2022

Soil(vadose zone) gas compositions were measured for about 3 days to suggest a method for monitoring and interpreting soil gas data collected around wells from which methane(CH₄) is outflowing. The vadose zone gas samples were collected within 1 m around two test wells(TB2 and TB3) at Pohang and analyzed for CO₂, CH₄, N₂ and O₂ concentrations in situ. CO₂ flux was measured beside TB2. In addition, gas samples from well head in TB2 and atmospheric air samples were collected for comparison. Carbon isotopes of CO₂(δ¹³C_CO2) of samples collected on the last day of the study period were analyzed in the laboratory. The two test wells (TB2 and 3) were 12.7 m apart and only TB3 was cemented to the surface. According to the bio-geochemical process-based interpretation, the relationships between CO₂ and O₂, N₂, and N₂/O₂ of vadose zone gas were plotted between the lines of CH₄ oxidation and CO₂ dissolution. In addition, the CH₄ concentrations of gas samples from the wellhead of the uncemented well (TB2) were 5.2 times higher than the atmospheric CH₄ concentration. High CO₂ concentrations (average 1.148%) of vadose zone gas around TB2 seemed to be attributed to the oxidation of CH₄. On the other hand, the vadose zone CO₂ around the cemented well(TB3) showed a relatively low concentration(0.136%). This difference indicates that the vadose zone gas(including CO₂) around the CH₄ outflowing well were strongly affected by well completion(cementing). This study result can be used to establish strategies for environmental monitoring of soil around natural gas sites, and can be used to monitor leakage around injection and observation wells for CO₂ geological storage. In addition, the method of this study is useful for soil monitoring in natural gas storage and oil-contaminated sites.

• Journal of Soil and Groundwater Environment
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• v.29 no.1
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• pp.1-9
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• 2024

As part of monitoring technology aimed at verifying the stability of CO₂ geologic storage and mitigating concerns about leakage, a method for measuring the pH and alkalinity of high-pressure fluid samples was established to obtain practical technology. pH measurement for high-pressure samples utilized a high-pressure pH electrode, and alkalinity was measured using the Gran titration method for samples collected with a piston cylinder sampler (PCS). Experimental samples, referencing CO₂-rich water and CO₂ geologic storage studies, were prepared in the laboratory. The PCS controls the piston, preventing CO₂ degassing and maintaining fluid pressure, allowing mixing with KOH to fix dissolved CO₂. Results showed a 6.1% average error in high-pressure pH measurement. PCS use for sample collection maintained pressure, preventing CO₂ degassing. However, PCS-collected sample alkalinity measurements had larger errors than non-PCS measurements, limiting PCS practicality in monitoring field settings. Nevertheless, PCS could find utility in preprocessing for carbon isotope analysis and other applications. This research not only contributes to the field of CCS monitoring but also suggests potential applications in studies related to natural analogs of CCS, CO₂-rock interaction experiments, core flooding experiments, and beyond.

• Journal of Ecology and Environment
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• v.46 no.3
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• pp.250-258
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• 2022

Background: To assess the carbon sequestration capacity and net ecosystem productivity (NEP) of Quercus glauca forests, we analyzed the net primary productivity (NPP), carbon storage, and carbon emission of soil in a Q. glauca forest on Jeju Island (South Korea) from 2016 to 2018. Results: The average carbon stock in the above- and below-ground plant biomass was 223.7 Mg C ha^-1, while the average amount of organic carbon fixed by photosynthesis was 9.8 Mg C ha^-1 yr^-1, and the average NPP was 9.6 Mg C ha^-1 yr^-1. Stems and branches contributed to the majority of the above- and below-ground standing biomass and NPP. The average heterotrophic carbon emission from the soil was 8.7 Mg C ha^-1 yr^-1, while the average NEP was 1.1 Mg C ha^-1 yr^-1. Although the carbon stock, carbon absorption, and soil respiration values were higher than those reported in other oak forests in the world, the NEP was similar or lower. Conclusions: These results indicator that Q. glauca forests perform the role of a large carbon sink through the CO₂ absorption in the plants in terms of carbon balance. And it is judged to be helpful as data for assessment of carbon storage and flux in the forests and mitigation of elevated CO₂ in the atmosphere.

• Journal of the Korean Society of Environmental Restoration Technology
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• v.24 no.4
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• pp.1-14
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• 2021

This study suggested suitable soil textures that is proper to propagate native plants to manage and restore barren land in DMZ. Germination tests were conducted for 16 native herbaceous plants growing in the DMZ border area in accordance with FAO-BI (Biodiversity International) standards, and the germination rate and T₅₀ in vitro were investigated. In order to examine the germination characteristics according to the soil textures, we used gravel, bed and mixed soil and investigated the germination characteristics under ordinary room temperature conditions in the greenhouse. As a result, it was observed that the germination rate in the greenhouse was significantly decreased compared to the germination rate in vitro of the species advertised due to soil textures. T₅₀ between the in vitro and each soil texture showed significant differences whereas T₅₀ between soil textures alone did not in all species advertised. The germination rate in vitro of Aster koraiensis, Dendranthema zawadskii var. latilobum, Hosta clausa, and Hosta minor there was no significant difference compared to ordinary room temperature conditions. In addition, as the germination rate is demonstrated more than 70%, which is relatively higher than other species advertised, it is considered to have strong environmentally adaptable. On the other hand, considering that the 6 species of Leontopodium coreanum, Plantago major, Potentilla chinensis, Sedum kamtschaticum, Sedum latiovalifolium, and Veronica kiusiana demonstrated less than 50% of germination rate in vitro, it is expected to be difficult to propagate without pre-treatment. In order to use these 6 species as restoration material plants, it needs to be considered to pre-treat to improve germination rate, or to enhance the vitality of seeds by improving the seed gathering period and storage method.

• Economic and Environmental Geology
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• v.54 no.4
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• pp.409-425
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• 2021

Carbon dioxide has been known to be a typical greenhouse gas causing global warming, and a number of efforts have been proposed to reduce its concentration in the atmosphere. Among them, carbon dioxide capture and storage (CCS) has been taken into great account to accomplish the target reduction of carbon dioxide. In order to commercialize the CCS, its safety should be secured. In particular, if the stored carbon dioxide is leaked in the arable land, serious problems could come up in terms of crop growth. This study was conducted to investigate the effect of carbon dioxide leaked from storage sites on soil fertility. The leakage of carbon dioxide was simulated using the facility of its artificial injection into soils in the laboratory. Several soil chemical properties, such as pH, cation exchange capacity, electrical conductivity, the concentrations of exchangeable cations, nitrogen (N) (total-N, nitrate-N, and ammonia-N), phosphorus (P) (total-P and available-P), sulfur (S) (total-S and available-S), available-boron (B), and the contents of soil organic matter, were monitored as indicators of soil fertility during the period of artificial injection of carbon dioxide. Two kinds of soils, such as non-cultivated and cultivated soils, were compared in the artificial injection tests, and the latter included maize- and soybean-cultivated soils. The non-cultivated soil (NCS) was sandy soil of 42.6% porosity, the maize-cultivated soil (MCS) and soybean-cultivated soil (SCS) were loamy sand having 46.8% and 48.0% of porosities, respectively. The artificial injection facility had six columns: one was for the control without carbon dioxide injection, and the other five columns were used for the injections tests. Total injection periods for NCS and MCS/SCS were 60 and 70 days, respectively, and artificial rainfall events were simulated using one pore volume after the 12-day injection for the NCS and the 14-day injection for the MCS/SCS. After each rainfall event, the soil fertility indicators were measured for soil and leachate solution, and they were compared before and after the injection of carbon dioxide. The results indicate that the residual concentrations of exchangeable cations, total-N, total-P, the content of soil organic matter, and electrical conductivity were not likely to be affected by the injection of carbon dioxide. However, the residual concentrations of nitrate-N, ammonia-N, available-P, available-S, and available-B tended to decrease after the carbon dioxide injection, indicating that soil fertility might be reduced. Meanwhile, soil pH did not seem to be influenced due to the buffering capacity of soils, but it is speculated that a long-term leakage of carbon dioxide might bring about soil acidification.