• 제목/요약/키워드: Sub-Structure

검색결과 4,883건 처리시간 0.03초

Preparation of Nanoflake Bi2MoO6 Photocatalyst Using CO(NH2)2 as Structure Orientation and Its Visible Light Degradation of Tetracycline Hydrochloride

  • Hu, Pengwei;Zheng, Dewen;Xian, Yuxi;Hu, Xianhai;Zhang, Qian;Wang, Shanyu;Li, Mingjun;Cheng, Congliang;Liu, Jin;Wang, Ping
    • 한국재료학회지
    • /
    • 제31권6호
    • /
    • pp.325-330
    • /
    • 2021
  • Bi2MoO6 (BMO) via the structure-directing role of CO(NH2)2 is successfully prepared via a facile solvothermal route. The structure, morphology, and photocatalytic performance of the nanoflake BMO are characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), fluorescence spectrum analysis (PL), UV-vis spectroscopy (UV-vis) and electrochemical test. SEM images show that the size of nanoflake BMO is about 50 ~ 200 nm. PL and electrochemical analysis show that the nanoflake BMO has a lower recombination rate of photogenerated carriers than particle BMO. The photocatalytic degradation of tetracycline hydrochloride (TC) by nanoflake BMO under visible light is investigated. The results show that the nanoflake BMO-3 has the highest degradation efficiency under visible light, and the degradation efficiency reached 75 % within 120 min, attributed to the unique hierarchical structure, efficient carrier separation and sufficient free radicals to generate active center synergies. The photocatalytic reaction mechanism of TC degradation on the nanoflake BMO is proposed.

The influence of sodium hypochlorite concentration on the fibrin structure of human blood clots and transforming growth factor-beta 1 release: an ex vivo study

  • Anisha Mishra ;Velmurugan Natanasabapathy;Nandini Suresh
    • Restorative Dentistry and Endodontics
    • /
    • 제47권4호
    • /
    • pp.42.1-42.11
    • /
    • 2022
  • Objective: This study investigated the effects of various concentrations of sodium hypochlorite (NaOCl) on human whole-blood clotting kinetics, the structure of the blood clots formed, and transforming growth factor (TGF)-β1 release. Materials and Methods: Human whole blood was collected from 5 healthy volunteers and divided into 4 groups: CG (control, 0.5 mL of blood), BN0.5 (0.5 mL of blood with 0.5 mL of 0.5% NaOCl), BN3 (0.5 mL of blood with 0.5 mL of 3% NaOCl), and BN5.25 (0.5 mL of blood with 0.5 mL of 5.25% NaOCl). The effects of NaOCl on clotting kinetics, structure of fibrin and cells, and release of TGF-β1 were assessed using thromboelastography (TEG), scanning electron microscopy (SEM), and enzyme-linked immunosobent assay, respectively. Statistical analysis was conducted using the Kruskal Wallis and Mann-Whitney U tests, followed by the post hoc Dunn test. A p value < 0.05 indicated statistical significance. Results: The blood samples in BN0.5 and BN3 did not clot, whereas the TEG of BN5.25 showed altered clot formation. Samples from the CG and BN3 groups could only be processed with SEM, which showed that the latter lacked fibrin formation and branching of fibers, as well as clumping of red blood cells with surface roughening and distortion. TGF-β1 release was significantly highest in BN3 when all groups were compared to CG (p < 0.05). Conclusions: Each concentration of NaOCl affected the release of TGF-β1 from blood clots and altered the clotting mechanism of blood by affecting clotting kinetics and cell structure.

RECURRENT STRUCTURE JACOBI OPERATOR OF REAL HYPERSURFACES IN COMPLEX HYPERBOLIC TWO-PLANE GRASSMANNIANS

  • JEONG, IMSOON;WOO, CHANGHWA
    • Journal of applied mathematics & informatics
    • /
    • 제39권3_4호
    • /
    • pp.327-338
    • /
    • 2021
  • In this paper, we have introduced a new notion of recurrent structure Jacobi of real hypersurfaces in complex hyperbolic two-plane Grassmannians G*2(ℂm+2). Next, we show a non-existence property of real hypersurfaces in G*2(ℂm+2) satisfying such a curvature condition.

MH전지용 $\textrm{ZrV}_{x}\textrm{Mn}_{1-x-y}\textrm{Ni}_{1+y}$ Laves합금의 결정구조 (Crystal Structure of $\textrm{ZrV}_{x}\textrm{Mn}_{1-x-y}\textrm{Ni}_{1+y}$ Laves Phase Alloys for MH Battery Application)

  • 김원백;서창열;최국선;김인곤
    • 한국재료학회지
    • /
    • 제7권3호
    • /
    • pp.234-243
    • /
    • 1997
  • 아크용해로와 진공유도로를 사용하여 니켈-수소 전지의 음극용으로 주목받고 있는 AB2 타입의 ZrV /sub x/Mn/sub 1-x/Ni/sub 1.0/, ZrV/sub x/Mn/sub 0.8-x/Ni/sub 1.2/, ZrV/sub x/Mn/sub 0.6-x/Ni/sub 1.4/합금을 용해하였다. 이들 합금은 용해한 상태에서 C14과 C15의 혼합상을 갖는 것으로 나타났으며 합금조성 및 열처리에 따라 혼합상분율이 크게 변화하였다. 이들의 결정상 및 상분율은 합금원소들의 평균원자반경비(r/sub A//r/sub B)에 따라 결정되는 것으로 밝혀졌으며 특히 열처리한 합금의 경우에는 평균원자반경비가 1.254일때를 경계로 하여 두 상의 명확간 안정구역이 설정되었다. 가압한 분위기에서 아크용해한 경우 합금성분의 손실은 미미하였으나 진공유도로를 사용하여 용해한 경우 Mn이 다량 휘발감소하여 조성이 크게 변화하였다.

  • PDF

저온 H2-SCR용 PtNi/W-TiO2 촉매에 조촉매 CeO2가 NOx 저감에 미치는 영향 (Effect of Co-catalyst CeO2 on NOx Reduction in PtNi/W-TiO2 Catalysts for Low-temperature H2-SCR)

  • 김정수;김영희
    • 청정기술
    • /
    • 제29권4호
    • /
    • pp.313-320
    • /
    • 2023
  • 대표적인 비암모니아성 선택적 촉매환원반응기인 H2-SCR의 활용성을 높이기 위하여 Ce를 조촉매로 활용한 PtNi/CeO2-W-TiO2의 촉매 분말을 합성하고 다공성 금속 구조(porous metal structure, PMS)에 코팅하여 선택적 촉매 환원에 의한 NOx 제거 특성을 평가하였다. CeO2를 조촉매로 사용한 H2-SCR은 CeO2를 사용하지 않은 경우에 비해 더 높은 NOx 제거 효율을 나타내었으며, CeO2 담지율 10 wt%에서는 반응온도 90℃에서 가장 높은 제거효율을 보였다. 한편, 촉매구조체인 PMS의 촉매 코팅량이 증가함에 따라 NOx 제거효율은 90℃ 이하에서는 향상되었으나, 120℃ 이상에서는 감소하는 경향을 보였고 공간속도를 4,000 h-1에서 20,000 h-1로 변경한 경우, 120℃이상의 온도에서 NOx 제거 효율이 향상되는 것을 확인할 수 있었다.

Common sub-expression sharing과 CORDIC을 이용한 OFDM 시스템의 저면적 파이프라인 FFT 구조 (Low-area Pipeline FFT Structure in OFDM System Using Common Sub-expression Sharing and CORDIC)

  • 최동규;장영범
    • 대한전자공학회논문지SP
    • /
    • 제46권4호
    • /
    • pp.157-164
    • /
    • 2009
  • 이 논문에서는 OFDM시스템에서 가장 큰 칩 면적을 차지하고 높은 전력을 요구하는 핵심 연산 블록인 FFT에 대하여 파이프라인 Radix-4 MDC 방식의 저면적 구조를 제안하였다. 나비연산기에서 Twiddle factor 복소 곱셈연산을 수행할 때, 기존의 곱셈기를 사용하지 않고 CSD형 계수의 공통패턴을 공유하여 덧셈의 수를 줄일 수 있는 Common sub-expression sharing 방식과 CORDIC 알고리즘을 사용하여 구현 면적을 감소시켰다. 제안구조는 Verilog-HDL을 통해 모델링하고 Synopsys로 논리합성한 결과 기존구조와 비교하여 복소곱셈부는 48.2%감소효과, 전체 FFT구조는 22.1%의 면적 감소효과를 달성하였다. 따라서 제안된 FFT구조는 다양한 크기의 FFT를 사용하는 OFDM용 시스템에 효율적으로 사용될 수 있는 구조임을 보였다.

TiO2/Si3N4/Ag/Si3N4/TiO2 다층구조에서 Si3N4 버퍼층이 투과율에 미치는 영향 (Effect of Si3N4 Buffer Layer on Transmittance of TiO2/Si3N4/Ag/Si3N4/TiO2 Multi Layered Structure)

  • 이서희;장건익
    • 한국전기전자재료학회논문지
    • /
    • 제25권1호
    • /
    • pp.44-47
    • /
    • 2012
  • The $TiO_2/Si_3N_4/Ag/Si_3N_4/TiO_2$ multi layered structure was designed for the possible application of transparent electrodes in PDP (Plasma Display Panel). Multi layered film was deposited on a glass substrate at room temperature by DC/RF magnetron sputtering system and EMP (Essential Macleod Program) was adopted to optimize the optical characteristics of film. During the deposition process, the Ag layer in $TiO_2/Ag/TiO_2$ became heavily oxidized and the filter characteristic was degraded easily. In thus study, Si3N4 layer was used as a diffusion buffer layer between $TiO_2$ and Ag. in order to prevent the oxidation of Ag layer in $TiO_2/Si_3N_4/Ag/Si_3N_4/TiO_2$ structure. It was confirmed that $Si_3N_4$ layer is one of candidate materials acting as diffusin barrier between $TiO_2/Ag/TiO_2$.