• Journal of Environmental Science International
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• v.32 no.4
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• pp.205-220
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• 2023

In this study, impact of the COVID-19 outbreak on PM_2.5 mass and its five chemical components (NH₄⁺, NO₃^-, SO₄^2-, OC, EC) in Busan was evaluated, and compared with that of Seoul. The study period over the recent three years was sub-divided into two periods: Pre-COVID (2018~2019) and COVID (2020) periods, and the differences in observed annual and monthly variations between the two periods were explored here. The results indicated that annual mean PM_2.5 mass concentrations decreased during the COVID period by 16% in Seoul and 29% in Busan, and the satellite-observed annual average of aerosol optical depth (AOD) over the Korean Peninsula also decreased by approximately more than 10% compared with that of the Pre-COVID period. All of the five chemical components decreased but no particular changes were found in their fractions occupied during the COVID period. However, over the Lock-down period (2020-March), the sulfate fraction decreased in Seoul, mostly reflecting the recent Chinese trends of aerosol characteristics, whereas the nitrate fraction considerably decreased in Busan, which was attributable to the local emission changes and their variabilities in Busan. Other meteorological characteristics such as higher frequencies of easterly winds in the Busan area during the COVID period were also discussed in comparison with those in the Seoul area.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.12 no.4
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• pp.1867-1875
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• 2011

In this paper, a low-area 256-point FFT structure is proposed. For low-area implementation CSD(Canonic Signed Digit) multiplier method is chosen. Because multiplication type should be less for efficient CSD multiplier application to the FFT structure, the Radix-$4^2$ algorithm is chosen for those purposes. After, in the proposed structure, the number of multiplication type is minimized in each multiplication block, the CSD multipliers are applied for implementation of multiplication. Furthermore, in CSD multiplier implementation, cell-area is more reduced through common sub-expression sharing(CSS). The Verilog-HDL coding result shows 29.9% cell area reduction in the complex multiplication part and 12.54% cell area reduction in overall 256-point FFT structure comparison with those of the conventional structure.

• Structural Engineering and Mechanics
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• v.84 no.4
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• pp.561-573
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• 2022

This paper presents a new model to obtain the minimum area of the contact surface for rectangular isolated footings, considering that the contact surface works partially to compression (a part of the contact surface of the footing is subjected to compression and the other is not in compression or tension). The methodology is developed by integration to obtain the axial load "P", moment around the X axis "M_x" and moment around the Y axis "M_y". This document presents the simplified and precise equations of the four possible cases of footing subjected to uniaxial bending and five possible cases of footing subjected to biaxial bending. The current model considers the contact area of the footing that works totally in compression, and other models consider the contact area that works partially under compression and these are developed by very complex iterative processes. Numerical examples are presented to obtain the minimum area of rectangular footings under an axial load and moments in two directions, and the results are compared with those of other authors. The results show that the new model presents smaller areas than the other authors presented.

• Korean Chemical Engineering Research
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• v.60 no.4
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• pp.564-573
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• 2022

Calcium carbonate (CaCO₃) exhibits three polymorphs: calcite with arhombohedral, vaterite with a spherical, and aragonite with a needle-like structure. Qualitative and quantitative analyses of the morphology of CaCO₃ are very important to investigate the synthesis of single-crystal vaterite and aragonite. In this work, the polymorphs of calcium carbonate were quantitatively analyzed using XRD. Pure vaterite and pure aragonite were synthesized and the peak distribution of a single phase was analyzed. The vaterite fraction of a mixture of calcite and vaterite was calculated based on the intensity of a specific diffraction peak, and compared to the results based on the peak area. The mean value of f_sV (the correction factor for the peak area of vaterite) was 0.654. The phase analysis of calcite-aragonite mixtures was performed, and the mean value of f_sA (the correction factor for the peak area of aragonite) was obtained as 0.6713. Using these factors, Eq. (24)~Eq. (32) for the quantitative analysis based on the total peak area of XRD were derived to calculate the phase contents of ternary phase CaCO₃. And three-component XRD section was defined considering overlapping sections.

• Applied Chemistry for Engineering
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• v.7 no.3
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• pp.543-553
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• 1996

Oxygen reduction in an alkaline fuel cell was studied by using perovskite type oxides as an oxygen electrode catalyst. The high surface area catalysts were prepared by malic acid method and had a formula of $La_{0.6}Sr_{0.4}Co_{1-x}Fe_xO_3$(x=0.00, 0.01, 0.10, 0.20, 0.35 and 0.50). From the result of XRD pattern and specific surface area due to the amount of Fe substitution and the consumption of ammonia-water, the complex formation of Fe ion with $NH_3$ was the main factor for both the phase stability of perovskite and the increase of specific surface area. Multi-step calcination was necessary to give a single phase of perovskite in catalyst precursor. The crystal structure of the catalysts was simple cubic perovskite, which was verified from the XRD patterns of the catalysts. The activity of oxygen reduction was monitored by the techniques of cyclic voltammetry, static voltage-current method, and current interruption method. The activity(current density) of oxygen reduction showed its minimum at x=0.01 and its maximum between 0.20 and 0.35 of x-value in $La_{0.6}Sr_{0.4}Co_{1-x}Fe_xO_3$. This tendency was independent of the change of surface area.

• Atmosphere
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• v.33 no.5
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• pp.531-548
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• 2023

We developed the Aviation Convective Index (ACI) for predicting deep convective area using the operational global Numerical Weather Prediction model of the Korea Meteorological Administration. Seasonally optimized ACI (ACI_SnOpt) was developed to consider seasonal variabilities on deep convections in Korea. Yearly optimized ACI (ACI_YrOpt) in Part 1 showed that seasonally averaged values of Area Under the ROC Curve (AUC) and True Skill Statistics (TSS) were decreased by 0.420% and 5.797%, respectively, due to the significant degradation in winter season. In Part 2, we developed new membership function (MF) and weight combination of input variables in the ACI algorithm, which were optimized in each season. Finally, the seasonally optimized ACI (ACI_SnOpt) showed better performance skills with the significant improvements in AUC and TSS by 0.983% and 25.641% respectively, compared with those from the ACI_YrOpt. To confirm the improvements in new algorithm, we also conducted two case studies in winter and spring with observed Convectively-Induced Turbulence (CIT) events from the aircraft data. In these cases, the ACI_SnOpt predicted a better spatial distribution and intensity of deep convection. Enhancements in the forecast fields from the ACI_YrOpt to ACI_SnOpt in the selected cases explained well the changes in overall performance skills of the probability of detection for both "yes" and "no" occurrences of deep convection during 1-yr period of the data. These results imply that the ACI forecast should be optimized seasonally to take into account the variabilities in the background conditions for deep convections in Korea.

• The Bulletin of The Korean Astronomical Society
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• v.37 no.2
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• pp.123.2-123.2
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• 2012

We investigate the solar flare occurrence rate and daily flare probability in terms of the sunspot classification supplemented with sunspot area and its changes. For this we use the NOAA active region data and GOES solar flare data for 15 years (from January 1996 to December 2010). We consider the most flare-productive eleven sunspot classes in the McIntosh sunspot group classification. Sunspot area and its changes can be a proxy of magnetic flux and its emergence/cancellation, respectively. We classify each sunspot group into two sub-groups by its area: "Large" and "Small". In addition, for each group, we classify it into three sub-groups according to sunspot area changes: "Decrease", "Steady", and "Increase". As a result, in the case of compact groups, their flare occurrence rates and daily flare probabilities noticeably increase with sunspot group area. We also find that the flare occurrence rates and daily flare probabilities for the "Increase" sub-groups are noticeably higher than those for the other sub-groups. In case of the (M+X)-class flares in the 'Dkc' group, the flare occurrence rate of the "Increase" sub-group is three times higher than that of the "Steady" sub-group. Our results statistically demonstrate that magnetic flux and its emergence enhance the occurrence of major solar flares.

• The Journal of Engineering Geology
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• v.26 no.1
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• pp.33-49
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• 2016

The study area, located in Sinam-ri, Ulsan, in the southeastern part of the Korean Peninsula, is mainly composed of hornblende granite (ca. 65 Ma). Fracturing and reactivation of a fault striking ENE-WSW was strongly controlled by the intrusion of a mafic dyke (ca. 44 Ma), which behaves as a discontinuity in the mechanically homogeneous pluton, increasing the instability of the basement in this area. A geometric and kinematic study undertaken to interpret the faults and fractures was performed in a trench excavated almost perpendicular to the orientation of the dyke. The analysis of structural elements, such as dykes, veins, and faults, is used to infer the deformation history and to determine the paleostress orientations at the time of formation of the structures. The deformation history established based on this analysis is as follows: (1) NNE-SSW, E-W, ENE-WSW, and NE-SW trending fractures had already developed in the pluton before dyke intrusion; (2) felsic dykes intruded under conditions of σ_Hmax oriented N-S and σ_Hmin oriented E-W; (3) mafic dykes intruded under conditions of σ_Hmax oriented E-W and σ_Hmin oriented N-S; (4) dextral reactivation of the main fault associated with the development of hydrothermal quartz veins under conditions of σ_Hmax oriented E-W and σ_Hmin oriented N-S; (5) sinistral reactivation of the main fault and high-angle normal faults under conditions of σ_Hmax oriented NE-SW and σ_Hmin oriented NW-SE; and (6) dextral reactivation of the main fault and NE-SW low-angle reverse faults under conditions of σ_Hmax oriented NW-SE and σ_Hmin oriented NE-SW. These results are consistent with the tectonic history of the Pohang-Ulsan block in the southeastern part of the Korean Peninsula, and indicates the tectonic deformation of the southern area of the Ulsan fault bounded by Yangsan fault was analogous to that of the Pohang-Ulsan area from the Cenozoic. This work greatly aids the selection of sites for critical facilities to prevent potential earthquake hazards in this area.

• Bulletin of the Korean Chemical Society
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• v.30 no.12
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• pp.2921-2926
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• 2009

Cu-BTC[$Cu_3(BTC)_2(H_2O)_3$, BTC = 1,3,5-benzenetricarboxylate], one of the most well-known metal-organic framework materials (MOF), has been synthesized under atmospheric pressure and room temperature by using ultrasound. The Cu-BTC can be obtained in 1 min in the presence of DMF (N,N-dimethylformamide), suggesting the possibility of continuous production of Cu-BTC. Moreover, the surface area and pore volume show that the concentration of DMF is important for the synthesis of Cu-BTC having high porosity. The morphology and phase also depend on the concentration of DMF : Cu-BTC cannot be obtained at room temperature in the absence of DMF and aggregated Cu-BTC (with low surface area) is produced in the presence of high concentration of DMF. It seems that the deprotonation of benzenetricarboxylic acid by base (such as DMF) is inevitable for the room temperature syntheses.

• New & Renewable Energy
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• v.18 no.2
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• pp.40-49
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• 2022

In this study, the phase and electrochemical properties of Co and Ti substituted layered perovskites SmBaCo_2-xTi_xO_5+d (x=0.5, 0.7, 1.0, 1.1, 1.3, and 1.5) were analyzed, and their application as electrodes in solid oxide fuel cells (SOFCs) were evaluated. After calcination at 1300℃ for 6 h, a single phase was observed for two compositions of the SmBaCo_2-xTi_xO_5+d oxide system, SmBaCoTiO_5+d (x=1.0) and SmBaCo_0.9Ti_1.1O_5+d (x=1.1). However, the phases of SmBaCoTiO_5+d (SBCTO) and SmTiO₃ coexisted for compositions with x≥1.3 (Ti content). In contrast, for compositions of x≤0.7, the SmBaCo₂O_5+d phase was observed instead of the SmTiO₃ phase. To evaluate the applicability of these materials as SOFC electrodes, the electrical conductivities were measured under various atmospheres (air, N₂, and H₂). SBCTO exhibited stable semi-conductor electrical conductivity behavior in an air and N₂ atmosphere. However, SBCTO showed insulator behavior at temperatures above 600℃ in a H₂ atmosphere. Therefore, SBCTO may only be used as cathode materials. Moreover, SBCTO had an area specific resistance (ASR) value of 0.140 Ω·cm² at 750℃.