• 제목/요약/키워드: Structured-surface

검색결과 335건 처리시간 0.027초

Tuning of Electro-optical Properties of Nano-structured SnO2:Ga Powders in a Micro Drop Fluidized Reactor

  • Lim, Dae Ho;Yang, Si Woo;Yoo, Dong June;Lee, Chan Gi;Kang, Yong
    • Korean Chemical Engineering Research
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    • 제57권2호
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    • pp.259-266
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    • 2019
  • Tuning of electro-optical properties of nano-structured $SnO_2:Ga$ powders in a micro drop fluidized reactor (MDFR) was highly effective to enhance the activities of powders to be used as sensor materials. The tuning was conducted continuously in a facile one-step process during the formation of powders. The microscopic hydrodynamic forces affected the band gap structure and charge transfer of $SnO_2:Ga$ powders through the oxygen and interfacial tin vacancies by providing plausible pyro-hydraulic conditions, which resulted in the decrease in the electrical resistance of the materials. The analyses of room-temperature photoluminescence (PL) spectra and FT-IR exhibited that the tuning could improve the surface activities of $SnO_2:Ga$ powders by adjusting the excitation as well as separation of electrons and holes, thus maximizing the oxygen vacancies at the surface of the powders. The scheme of photocatalytic mechanism of $SnO_2:Ga$ powders was also discussed.

Synthesis of Core@shell Structured CuFeS2@TiO2 Magnetic Nanomaterial and Its Application for Hydrogen Production by Methanol Aqueous Solution Photosplitting

  • Kang, Sora;Kwak, Byeong Sub;Park, Minkyu;Jeong, Kyung Mi;Park, Sun-Min;Kang, Misook
    • Bulletin of the Korean Chemical Society
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    • 제35권9호
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    • pp.2813-2817
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    • 2014
  • A new magnetic semiconductor material was synthesized to enable separation after a liquid-type photocatalysis process. Core@shell-structured $CuFeS_2@TiO_2$ magnetic nanoparticles were prepared by a combination of solvothermal and wet-impregnation methods for photocatalysis applications. The materials obtained were characterized using X-ray diffraction, transmission electron microscopy, ultraviolet-visible, photoluminescence spectroscopy, Brunauer-Emmett-Teller surface area measurements, and cyclic voltammetry. This study confirmed that the light absorption of $CuFeS_2$ was shifted significantly to the visible wavelength compared to pure $TiO_2$. Moreover, the resulting hydrogen production from the photo-splitting methanol/water solution after 10 hours was more than 4 times on the core@shell structured $CuFeS_2@TiO_2$ nanocatalyst than on either pure $TiO_2$ or $CuFeS_2$.

분자동역학을 이용한 다양한 구조물 위의 수액적의 특성에 대한 연구 (A Study of Characteristics of Water Droplets on Various Nanoscale Structures Using Molecular Dynamics)

  • 이광호;권태우;하만영
    • 설비공학논문집
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    • 제30권1호
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    • pp.33-43
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    • 2018
  • This study numerically investigated statistic and dynamic behaviors of the water droplet on plate with or without various structured-pillars at nano-scale by molecular dynamics simulation. This study considered smooth plate, plate with the rectangular-structured pillar, and the plate with dual-structured pillar under various characteristic energy conditions. The static behavior of water droplet depending on the plate shape, plate surface energy, and the pillar characteristics were examined. After the water droplet reaches its steady state, this study investigated the dynamic behavior of the water droplet by applying a constant force. Finally, this study investigated the static and dynamic behaviors of the water droplet by measuring its contact angle and contact angle hysteresis. As a result, we found that the structure was more hydrophobic.

Numerical Investigation of Internal Flow Field for Diffuser Passage Compressor

  • Yamagami, Mai;Tsuchiya, Naoki;Kato, Dai;Kodama, Hidekazu;Yamamoto, Kazuomi;Enomoto, Shunji;Horiguchi, Yasuo;Outa, Eisuke
    • 한국추진공학회:학술대회논문집
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    • 한국추진공학회 2008년 영문 학술대회
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    • pp.136-142
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    • 2008
  • The influence of different grids on numerical prediction of subsonic compressor performance and stall was investigated. Two types of grids were examined, structured H type grid and structured O-H type grid. Evaluations were conducted by comparing the numerical results with experimental results obtained from a low-speed single-stage rig test for a new concept compressor, called diffuser passage compressor, aiming at improving tip clearance sensitivity. At low mass flow operating conditions, the numerical calculation with O-H type grid showed that the lowest mass flow operating point for which the calculation was able to converge was almost the same as the lowest steady mass flow obtained from the rig test. On the other hand, the numerical calculation with structured H type grid diverged at higher mass flow operating point. It was found that this difference was attributed to the effect of double-valuedness of H type grid that existed at leading edge on the boundary layer development on the blade surface.

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Structural and component characterization of the B4C neutron conversion layer deposited by magnetron sputtering

  • Jingtao Zhu;Yang Liu;Jianrong Zhou;Zehua Yang;Hangyu Zhu;Xiaojuan Zhou;Jinhao Tan;Mingqi Cui;Zhijia Sun
    • Nuclear Engineering and Technology
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    • 제55권9호
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    • pp.3121-3125
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    • 2023
  • Neutron conversion detectors that use 10B-enriched boron carbide are feasible alternatives to 3He-based detectors. We prepared boron carbide films at micron-scale thickness using direct-current magnetron sputtering. The structural characteristics of natural B4C films, including density, roughness, crystallization, and purity, were analyzed using grazing incidence X-ray reflectivity, X-ray diffraction, X-ray photoelectron spectroscopy, time-of-flight secondary ion mass spectrometry, and scanning electron microscopy. A beam profile test was conducted to verify the practicality of the 10B-enriched B4C neutron conversion layer. A clear profile indicated the high quality of the neutron conversion of the boron carbide layer.

RTM공법을 이용한 승용차용 복합재료 휠의 표면정도 향상 및 개발 (Improvement of Surface Quality and Development of Composite Wheel for Passenger Cars Manufactured by RTM)

  • 김포진;이대길
    • 한국정밀공학회:학술대회논문집
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    • 한국정밀공학회 2003년도 춘계학술대회 논문집
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    • pp.54-57
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    • 2003
  • Since passenger cars require five wheels including a spare, the weight reduction of wheels without sacrificing performance is important. Recently, the structured components of cars made of steel are replaced by composites. plastics and other nonmetallic materials such as aluminum and magnesium for weight reduction. From these new tried materials are most promising due to their high specific stiffness and specific strength. The composites manufactured by resin transfer molding (RTM) process has not only low cost for the manufacturing but also reduces the lead time and development because the molds for RTM is easy to manufacture. In this work, composite wheels for passenger cars were designed and manufactured by RTM process. Since surface quality of wheels is important for passenger cars, the optimal stacking sequence for composite wheels was selected considering surface quality and mechanical properties. Also, the manufacturing method for the composite mold was depicted.

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마이크로/나노 트라이볼로지 기반 기계-화학적 미세가공기술 : 발전과정 및 전망 (Mechano-Chemical Microfabrication Technology Based on Micro/Nano-Tribology : Development Process and Prospect)

  • 성인하;김대은
    • 한국공작기계학회:학술대회논문집
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    • 한국공작기계학회 2002년도 추계학술대회 논문집
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    • pp.274-279
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    • 2002
  • In this paper, the development process of an unique and creative micro/nano-structure fabrication technique based on micro/nano-tribology are reviewed and discussed. The so-called Mechano-Chemical Process(MCP), which has been developed since 1995 by Tribology Research Laboratory at Yonsei University with the motivation to overcome the demerits of the conventional photolithographic techniques, is based on the fundamental understanding of the interaction between the tool tip and the workpiece surface. This process is a maskless process which offers tremendous flexibility in surface patterns that can be created on a workpiece surface without using any capital intensive equipment. It Is capable of fabricating the prototypes of micro/nano-components, micro- structured surface with various geometries, micro-molds for making polymer or metal parts, and micro-fluidic channels for lab-on-a- chip

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스프레이 코팅 증착 방식을 이용한 계층적 미세 구조의 발수표면 제작 및 특성 분석에 대한 연구 (Study on the Fabrication and Characterization of Hydrophobic Surface with Hierarchical Microstructure using Spray Coating Deposition Method)

  • 최종윤;김기웅
    • 한국가시화정보학회지
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    • 제21권3호
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    • pp.15-22
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    • 2023
  • This research introduces an innovative approach for fabricating microstructure surfaces using spray-coating deposition. The resulting surface, referred to as Magnetically Responsive Microstructures (MRM), exhibits hierarchically structured micro-pillar arrays with remarkably high aspect ratios. The fabrication process involves precisely mixing PDMS and hexane with Carbonyl iron powders, followed by ultrasonication and spray-coating on the top of a PDMS substrate placed on the neodymium magnet. The MRM surface shows hydrophobic properties, characterized by a contact angle surpassing 150° and an aspect ratio exceeding 10. Through a comprehensive exploration of critical parameters, including spray amount, magnet-substrate distance, and solution ratio enhanced dynamic tunability and exceptional hydrophobic characteristics are attained. This novel approach holds significant potential for diverse applications in the realm of dynamically tunable microstructures and magnetically responsive surfaces.

Electrical Properties of MIM and MIS Structure using Carbon Nitride Films

  • Lee, Hyo-Ung;Lee, Sung-Pil
    • Transactions on Electrical and Electronic Materials
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    • 제7권5호
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    • pp.257-261
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    • 2006
  • Nano-structured carbon nitride $(CN_x)$ films were prepared by reactive RF magnetron sputtering with a DC bias at various deposition conditions, and the physical and electrical properties were investigated. FTIR spectrum indicated an ${alpha}C_3N_4$ peak in the films. The carbon nitride film deposited on Si substrate had a nano-structured surface morphology. The grain size was about 20 nm and the deposition rate was $1.7{\mu}m/hr$. When the $N_2/Ar$ ratio was 3/7, the level of nitrogen incorporation was 34.3 at%. The film had a low dielectric constant. The metal-insulator-semiconductor (MIS) capacitors that the carbon nitride was deposited as insulators, exhibited a typical C-V characteristics.

적응형 측정계획 기반 치과인상 측정 (Dental Impression Measurement Based on an Adaptive Measuring Process Plan)

  • 박상철;정용호;함원경
    • 한국CDE학회논문집
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    • 제18권4호
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    • pp.283-289
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    • 2013
  • Presented in this paper is an adaptive measuring procedure of dental impression using the Structured Light System. While measuring a complex object, such as dental impression, in the reverse engineering, it is not possible to acquire all parts of the scanned surface. Missing scanned data is resulted in holes in a created triangular mesh. The focus of this paper is to introduce an algorithm for automatic identification of additional scanning orientations to fill holes that are created by a default scan. The proposed algorithm was developed by the three major technological requirements: camera visibility, projector visibility, data reliability. In order to satisfy the requirements, the proposed algorithm determines additional scanning orientation from the orientation of a projection plane derived from the average normal vector of boundary triangles.