• Proceedings of the Materials Research Society of Korea Conference
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• 2011.05a
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• pp.5-5
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• 2011

The research and development of hybrid electric vehicle (HEV), plug-in hybrid electric vehicle (PHEV) and electric vehicle (EV) are intensified due to the energy crisis and environmental concerns. In order to meet the challenging requirements of powering HEV, PHEV and EV, the current lithium battery technology needs to be significantly improved in terms of the cost, safety, power and energy density, as well as the calendar and cycle life. One new technology being developed is the utilization of composite cathode by mixing two different types of insertion compounds [e.g., spinel $LiMn_2O_4$ and layered $LiMO_2$ (M=Ni, Co, and Mn)]. Recently, some studies on mixing two different types of cathode materials to make a composite cathode have been reported, which were aimed at reducing cost and improving self-discharge. Numata et al. reported that when stored in a sealed can together with electrolyte at $80^{\circ}C$ for 10 days, the concentrations of both HF and $Mn^{2+}$ were lower in the can containing $LiMn_2O_4$ blended with $LiNi_{0.8}Co_{0.2}O_2$ than that containing $LiMn_2O_4$ only. That reports clearly showed that this blending technique can prevent the decline in capacity caused by cycling or storage at elevated temperatures. However, not much work has been reported on the charge-discharge characteristics and related structural phase transitions for these composite cathodes. In this presentation, we will report our in situ x-ray diffraction studies on this mixed composite cathode material during charge-discharge cycling. The mixed cathodes were incorporated into in situ XRD cells with a Li foil anode, a Celgard separator, and a 1M $LiPF_6$ electrolyte in a 1 : 1 EC : DMC solvent (LP 30 from EM Industries, Inc.). For in situ XRD cell, Mylar windows were used as has been described in detail elsewhere. All of these in situ XRD spectra were collected on beam line X18A at National Synchrotron Light Source (NSLS) at Brookhaven National Laboratory using two different detectors. One is a conventional scintillation detector with data collection at 0.02 degree in two theta angle for each step. The other is a wide angle position sensitive detector (PSD). The wavelengths used were 1.1950 ${\AA}$ for the scintillation detector and 0.9999 A for the PSD. The newly installed PSD at beam line X18A of NSLS can collect XRD patterns as short as a few minutes covering $90^{\circ}$ of two theta angles simultaneously with good signal to noise ratio. It significantly reduced the data collection time for each scan, giving us a great advantage in studying the phase transition in real time. The two theta angles of all the XRD spectra presented in this paper have been recalculated and converted to corresponding angles for ${\lambda}=1.54\;{\AA}$, which is the wavelength of conventional x-ray tube source with Cu-$k{\alpha}$ radiation, for easy comparison with data in other literatures. The structural changes of the composite cathode made by mixing spinel $LiMn_2O_4$ and layered $Li-Ni_{1/3}Co_{1/3}Mn_{1/3}O_2$ in 1 : 1 wt% in both Li-half and Li-ion cells during charge/discharge are studied by in situ XRD. During the first charge up to ~5.2 V vs. $Li/Li^+$, the in situ XRD spectra for the composite cathode in the Li-half cell track the structural changes of each component. At the early stage of charge, the lithium extraction takes place in the $LiNi_{1/3}Co_{1/3}Mn_{1/3}O_2$ component only. When the cell voltage reaches at ~4.0 V vs. $Li/Li^+$, lithium extraction from the spinel $LiMn_2O_4$ component starts and becomes the major contributor for the cell capacity due to the higher rate capability of $LiMn_2O_4$. When the voltage passed 4.3 V, the major structural changes are from the $LiNi_{1/3}Co_{1/3}Mn_{1/3}O_2$ component, while the $LiMn_2O_4$ component is almost unchanged. In the Li-ion cell using a MCMB anode and a composite cathode cycled between 2.5 V and 4.2 V, the structural changes are dominated by the spinel $LiMn_2O_4$ component, with much less changes in the layered $LiNi_{1/3}Co_{1/3}Mn_{1/3}O_2$ component, comparing with the Li-half cell results. These results give us valuable information about the structural changes relating to the contributions of each individual component to the cell capacity at certain charge/discharge state, which are helpful in designing and optimizing the composite cathode using spinel- and layered-type materials for Li-ion battery research. More detailed discussion will be presented at the meeting.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.27 no.4
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• pp.226-231
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• 2014

Thin thermistor films of solutions with nickel and manganese oxides were prepared by metal-organic decomposition (MOD). The structural properties of the thin films were investigated as a function of annealing temperature. Field emission scanning electron microscope (FE-SEM) results indicated that the thin films had a thin thickness, smooth and dense surface. The crystallization temperature of $414.9^{\circ}C$ was confirmed from thermogavimetric-differential thermal analysis (TG-DTA) curve. A single phase of cubic spinel structure was obtained for the thin film annealed from $700^{\circ}C$ to $800^{\circ}C$, which was confirmed from the X-ray diffraction (XRD). From the selected area electron diffraction (SAED) in high resolution transmission electron microscope (HRTEM), the nano grains (2~3 nm) of spinel phase with (311) and (222) planes were detected for the thin film annealed at $500^{\circ}C$, which could be applicable to read-out integrated circuit (ROIC) substrate of the uncooled microbolometer with low processing temperature.

• Earthquakes and Structures
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• v.15 no.5
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• pp.453-462
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• 2018

Damages to buildings affected by a near-fault strong ground motion are largely attributed to the vertical component of the earthquake resulting in column failures, which could lead to disproportionate building catastrophic collapse in a progressive fashion. Recently, considerable interests are awakening to study effects of earthquake vertical components on structural responses. In this study, detailed modeling and time-history analyses of a 12-story code-conforming reinforced concrete moment frame building carrying the gravity loads, and exposed to once only the horizontal component of, and second time simultaneously the horizontal and vertical components of an ensemble of far-field and near-field earthquakes are conducted. Structural responses inclusive of tension, compression and its fluctuations in columns, the ratio of shear demand to capacity in columns and peak mid-span moment demand in beams are compared with and without the presence of the vertical component of earthquake records. The influences of the existence of earthquake vertical component in both exterior and interior spans are separately studied. Thereafter, the correlation between the increase of demands induced by the vertical component of the earthquake and the ratio of a set of earthquake record characteristic parameters is investigated. It is shown that uplift initiation and the magnitude of tensile forces developed in corner columns are relatively more critical. Presence of vertical component of earthquake leads to a drop in minimum compressive force and initiation of tension in columns. The magnitude of this reduction in the most critical case is recorded on average 84% under near-fault ground motions. Besides, the presence of earthquake vertical components increases the shear capacity required in columns, which is at most 31%. In the best case, a direct correlation of 95% between the increase of the maximum compressive force and the ratio of vertical to horizontal 'effective peak acceleration (EPA)' is observed.

• Steel and Composite Structures
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• v.18 no.5
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• pp.1305-1330
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• 2015

The successful application of the component-based approach - widely used to model structural joints - requires knowledge of the mechanical properties of the constitutive joint components, including an appropriate assembly procedure to derive the joint properties. This paper presents a component-method model for a structural joint component that is located in the tension zone of blind-bolted connections to concrete-filled tubular steel profiles. The model relates to the response of blind-bolts with headed anchors under monotonic loading, and the blind-bolt is termed the "Extended Hollo-bolt". Experimental data is used to develop the model, with the data being collected in a manner such that constitutive models were characterised for the principal elements which contribute to the global deformability of the connector. The model, based on a system of spring elements, incorporates pre-load and deformation from various parts of the blind-bolt: (i) the internal bolt elongation; (ii) the connector's expanding sleeves element; and (iii) the connector's mechanical anchorage element. The characteristics of these elements are determined on the basis of piecewise functions, accounting for basic geometrical and mechanical properties such as the strength of the concrete applied to the tube, the connection clamping length, and the size and class of the blind-bolt's internal bolt. An assembly process is then detailed to establish the model for the elastic and inelastic behaviour of the component. Comparisons of model predictions with experimental data show that the proposed model can predict with sufficient accuracy the response of the component. The model furthers the development of a full and detailed design method for an original connection technology.

• Communications for Statistical Applications and Methods
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• v.17 no.4
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• pp.551-560
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• 2010

This paper considers a Bayesian approach to modeling a flexible regression function under structural measurement error model. The regression function is modeled based on semiparametric regression with penalized splines. Model fitting and parameter estimation are carried out in a hierarchical Bayesian framework using Markov chain Monte Carlo methodology. Their performances are compared with those of the estimators under structural measurement error model without a semiparametric component.

• The Journal of the Korea Contents Association
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• v.2 no.3
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• pp.87-95
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• 2002

This study proposes method to classify components in repository and retrieve them introducing the idea of domain orientation for successful reuse of components. About components of existing systems design pattern was applied to, us suggest component classification method to compare structural similarity between each component in relevant domain and criterion pattern. Component reusability and portability between platforms can be increased through classifying reusable components by function and giving their structures with diagram. Efficiency of component reuse can be raised because the most appropriate component to query and similar candidate components and provided in priority by use of E-SARM algorithm.

• Earthquakes and Structures
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• v.13 no.1
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• pp.9-15
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• 2017

In this paper, the influence of the rotational component, about a vertical axis, of earthquake ground motion on the response of building structures subjected to seismic action is considered. The torsional component of ground motion is generated from the records of translational components. Torsional component of ground motion is then, together with translational components, applied in numerical linear dynamic analysis of different reinforced concrete framed structure of three stories buildings. In total, more than 40 numerical models were created and analyzed. The obtained results show clearly the dependence of the effects of the torsional seismic component on structural system and soil properties. Thus, the current approach in seismic codes of accounting for the effects of accidental torsion due to the torsional ground motion, by shifting the center of mass, should be reevaluated.

• Journal of Aerospace System Engineering
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• v.17 no.5
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• pp.58-62
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• 2023

In this work, the structural integrity was investigated of the structural design results of internal components for the aircraft engine. The radiator and intercooler were combined with the internal components of the engine. Therefore, the safety of the radiator and intercooler was investigated during flight conditions. The structural integrity was evaluated through structural analysis, using the finite element analysis method. The acceleration load for structural design and analysis was considered. The structural safety evaluation found the structural design results to be valid.

• Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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• 2004.11a
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• pp.755-762
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• 2004

In our country, when the replacement for individual components of equipment in nuclear power plants is required, establishment of individual criteria i.e. Required Response Spectra(RRS) of seismic test/analysis for the component is very difficult because of the absence of Test Response Spectra(TRS) for the individual component to be replaced, from the existing qualification documents. In this case, it is required to perform the structural analysis for the nuclear equipment including the components to be replaced. After the structural analysis, Analysis Response Spectra(ARS) at the point of the component shall be generated and used for seismic test of the component. However, as of today, no standard program authorized for the response spectra generation by using the structural analysis exists in korea. Because of above reason, the STAR-Egs computer program was developed by using the method which calculates directly the expected response spectrum(frequency vs. acceleration type) of the selected points in the nuclear equipment with input spectrum(Required Response Spectra, RRS), based on the dynamic characteristics of the Finite Element(FE) model that is equivalent to the nuclear equipment. The STAR-Egs controls ANSYS/I-DEAS commercial software and automatically extract modal parameters of the FE model. The STAR-Egs calculates response spectrum using the established algorithm based on the extracted modal parameters, too. Reliance on the calculation result of the STAR-Egs was verified through comparison output with the result of MATLAB commercial software based on the identical algorithm. Moreover, actual seismic testing was performed as per IEEE344-1987 for the purpose of program verification by comparison of the FE analysis results.

• The KIPS Transactions:PartD
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• v.11D no.5
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• pp.1133-1142
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• 2004

This paper proposes a method to classify and retrieve components in repository using the idea of domain orientation for the successful reuse of components. A design pattern was applied to existing systems and a component classification method is suggested here to compare the structural similarity between each component in relevant domain and criterion patterns. Classifying reusable components by their functionality and then depicting their structures with a diagram can increase component reusability and portability between platforms. Efficiency of component reuse can be raised because the most appropriate component to query and similar candidate components are provided in priority by use of-SARM algorithm.