• Title/Summary/Keyword: Structural and dielectric prperties

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Effects of A-Site and B-Site Vacancies on Structural and Dielectric Properties of PLZT Ceramics

  • Jeong, Cheol-Su;Park, Hyu-Bum;Hong, Young-Sik;Kim, Si-Joong
    • The Korean Journal of Ceramics
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    • v.2 no.2
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    • pp.76-82
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    • 1996
  • PLZT ceramics having two nominal compositions, $Pb_{1-3x/2}La_xV_{x/2}(Zr_{03}Ti_{03})O_3$ and $Pb_{1-x}La_x(Zr_{0.2}Ti_{0.5})_{1-x/4}V_{x/4}O_3$ (V: vacancy) with x=0.00~0.30, were prepared. The physical, structural, and dielectric properties were investigated by X-ray diffraction, scanning electron microscopy, Raman spectroscopy, and measurements of bulk density and dielectric constant. The two series with A-stie and B-site vacancies showed different physical, structural, dielectric properties, and, specially, Curie temperature. In comparison to PLZT with B-site vacancies, PLZT with A-site vacancies showed high Curie temperatures and low maxima of dielectric constant. Consequently, it is evident that the properties of PLZT ceramics depend on the vacancy formula adopted as a batch composition in preparation.

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