• Title/Summary/Keyword: Structural Transition

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A Study of Structure and Thermal Properties of K2O·CaO·P2O5 Glasses (K2O·CaO·P2O5계 유리의 열적특성과 구조분석)

  • Yoon, Young-Jin;Yoon, Tae-Min;Lee, Yong-Soo;Kang, Won-Ho
    • Journal of the Korean Ceramic Society
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    • v.39 no.2
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    • pp.194-198
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    • 2002
  • Various composition of $K_2O{\cdot}CaO{\cdot}P_2O_5$ glasses were studied by melting process to identify glass forming region. Thermal properties were observed by DSC and TG-DTA, structural properties were investigated by FT-IR and Raman Spectroscopy. The glass transition temperature (Tg) and softening temperature (Ts) were decreased with increasing $K_2O\;and\;P_2O_5$ contents. The basic structural unit of phosphate glasses is the $PO_2\;and\;PO_4^{3-}$ groups to make a cross-link and P-O-P group to form skeleton structure. As CaO content was increased, the P-O-P field strength in these glass was increased and intensity of $PO_2\;and\;PO_4^{3-}$ stretch was decreased.

Wave Propagation Characteristics in Saturated Porous Media II. Parametric Studies (포화된 다공성매체에서 파동의 전파특성 II. 파라미터 연구)

  • Kim, Sun-Hoon;Kim, Kwang-Jin
    • Journal of the Computational Structural Engineering Institute of Korea
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    • v.20 no.2
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    • pp.191-206
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    • 2007
  • The general theoretical solutions for the wavespeed and damping derived in Part 1 of this work, are incorporated into the computer code. In this paper the code is used in a parametric study of the influence of excitation frequency and variations in material properties on propagation velocity and damping. Compressional wave velocity for waves of the first kind is shown to vary as a function of the frequency-permeability product, with a zone where wavespeed transitions from a lower bound value to a higher bound value with increasing values of the product. Damping is seen to be a maximum where the rate of change in wavespeed is greatest. Waves of the second kind also show a transition in wavespeed from near zero at low values of the frequency-permeability product to an upper bound value at higher values of the product.

The Model Development of Satisfaction Measurement Index of Education Service and the Improvement Plan of IPA (교육서비스의 만족도지수 모형개발 및 IPA를 통한 개선방안)

  • Lee, Sang-Jun;Yoon, Kwan-Ho;Kim, Seong-Yoon
    • The Journal of the Korea Contents Association
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    • v.13 no.11
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    • pp.510-521
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    • 2013
  • The awareness of education service is undergoing a transition from demand side to supply side. This study 1) develops an evaluation model of education service composed of three core factors(curriculum content, professor activities, job search activity) and additional factors(public welfare, education environment, campus life), 2) verifies a model using the structural equation model, 3) calculates the satisfaction measurement index of education service, and 4) proposes the results of IPA for evaluating the satisfaction measurement of education service. The results show significant notions that core factors(curriculum content, professor activities, job search activities) and additional factors(public welfare, education environment, campus life) determine students satisfaction, and that student satisfaction effects the recommend purpose significantly. Especially, student satisfaction influenced curriculum content, job search activity, campus life, public welfare, professor activities, education environment in order. This study provides improved strategic implications based on the calculated results of component satisfaction measurement index, and the results of IPA.

A Study on Structural Characteristics of SM490A TMC Thick Steel Plates (SM490A TMC 후판강재의 소재 및 용접부 특성에 관한 연구)

  • Kim, Jong Rak;Park, Yang Hee
    • Journal of Korean Society of Steel Construction
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    • v.15 no.3
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    • pp.331-339
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    • 2003
  • The study discussed in this paper investigated the material characteristics for the Thermo-Mechanical Control Process(TMCP) plates, which are controlled by several factors such as rolling, cold-stripping, cooling rate, and fixed carbon quantity. The suitability of thick TMCP steel plates as structural steel was also estimated through several experiments and with the us of a statistical method to analyze mill certificate sheets provided by the manufacturer. The results of this study are as follows: the TMCP steel plates showed stable values of the composition parameter ($P_cm$) and the carbon equivalents ($C_eq$ ) with satisfied yield strength, ultimate strength, and low-yield ratio.

Petrological and Conservational Scientific Deterioration Assessment of the Chungung-dong 5-Storied Stone Pagoda, Hanam City, Korea (하남시 춘궁동 오층석탑의 암석학적 및 보존과학적 훼손도 평가)

  • 이찬희;서만철;채상정;정연삼;이효민
    • Economic and Environmental Geology
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    • v.37 no.2
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    • pp.225-234
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    • 2004
  • The Chungung-dong 5-storied pagoda (Treasure No. 12) in the nnm, Korea was studied on the basis of petrological weathering and deterioration diagnosis. Frontal part of the pagoda is looked out on the N30$^{\circ}$W. Constitution rocks of this pagoda show augen gneiss and biotite granite. Host rock of the pagoda was highly exfoliation and discoloration, therefore most rock-forming minerals were altered to the clay minerals due to the mineralogical and chemical weathering. Open cavity and rock surface occur partly green and black patchs because of contamination by algae, lichen and moss, and the lower part of the pagoda is transition to the some weeds. This biological problems are need for cleaning and chemical treatments. For the structural stability, the pagoda is rebuilt without open gap between the each rock materials. All iron plates eliminate from the difference gap of the rock materials, and properly conservation treatments need to be repaired petro-filler for stone cultural properties and water curtain for the humidity attenuation of the ground.

Structural Analysis & Phase Transition of Amorphous Silica Nanoparticles Using Energy-Filtering TEM (EF-TEM을 이용한 비정질 실리카 나노입자의 구조 및 상전이 연구)

  • Park, Jong-Il;Kim, Jin-Gyu;Song, Ji-Ho;Kim, Youn-Joong
    • Applied Microscopy
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    • v.34 no.1
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    • pp.23-29
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    • 2004
  • In this study, we introduce the structural analysis of amorphous silica nanoparticles by EF-TEM electron diffraction and in-situ heating experiments. Three diffused rings were observed on the electron diffraction patterns of initial silica nanoparticles, while crystalline spot patterns were gradually appeared during the insitu heating process at $900^{\circ}C$. These patterns indicate the basic unit of $SiO_4$ tetrahedra consisting amorphous silica and gradual crystallization into the ideal layer structure of tridymite by heating. Under high vacuum condition in TEM, SiO nanoparticles were redeposited on the carbon grid after evaporation of SiO gas from $SiO_2$ above $850^{\circ}C$ and the remaining $SiO_2$ were crystallized into orthorhombic tridymite, consistent with ex-situ heating results in furnace at $900^{\circ}C$.

Structural Modification of Alkali Tellurite Binary Glass System and Its Characterization

  • Lee, Kyu-Ho;Kim, Tae-Ho;Kim, Young-Seok;Jung, Young-Joon;Na, Young-Hoon;Ryu, Bong-Ki
    • Korean Journal of Materials Research
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    • v.18 no.5
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    • pp.235-240
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    • 2008
  • This paper presents results and observations obtained from a study of the optical and thermal properties of alkali tellurite depending on the composition. Fourier transform infrared (FT-IR) spectra showed evidence of chemical modification from $TeO_4$ trigonal bipyramids (tbp) to $TeO_3$ trigonal pyramids (tp) in tellurite glasses. The optical band gaps of the different glass samples calculated using Tauc's method were found to range from 3.5-3.8 eV. The glass transition temperature (Tg) and glass stability (${\Delta}T$) of alkali tellurite glasses were investigated, as $M_2O$ [M: Li, Na, K] amounted to 25 mol%, through the use of differential thermal analysis (DTA). The coefficient of thermal expansion (CTE) was measured in a thermo mechanical analysis (TMA) with a slow heating rate after the glass samples were annealed. The results confirm that the optical band gap of alkali tellurite glasses depends on the Te-O-Te structural relaxation related to the ratio of bridging/non bridging oxygen (BO/NBO). In contrast, the thermal properties are related to the ionic field strength of the Te-O-M and M-O-M bonds, and the Te-O-Te breakage depends on the ratio of BO/NBO.

Cleavage-Dependent Activation of ATP-Dependent Protease HslUV from Staphylococcus aureus

  • Jeong, Soyeon;Ahn, Jinsook;Kwon, Ae-Ran;Ha, Nam-Chul
    • Molecules and Cells
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    • v.43 no.8
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    • pp.694-704
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    • 2020
  • HslUV is a bacterial heat shock protein complex consisting of the AAA+ ATPase component HslU and the protease component HslV. HslV is a threonine (Thr) protease employing the N-terminal Thr residue in the mature protein as the catalytic residue. To date, HslUV from Gram-negative bacteria has been extensively studied. However, the mechanisms of action and activation of HslUV from Gram-positive bacteria, which have an additional N-terminal sequence before the catalytic Thr residue, remain to be revealed. In this study, we determined the crystal structures of HslV from the Gram-positive bacterium Staphylococcus aureus with and without HslU in the crystallization conditions. The structural comparison suggested that a structural transition to the symmetric form of HslV was triggered by ATP-bound HslU. More importantly, the additional N-terminal sequence was cleaved in the presence of HslU and ATP, exposing the Thr9 residue at the N-terminus and activating the ATP-dependent protease activity. Further biochemical studies demonstrated that the exposed N-terminal Thr residue is critical for catalysis with binding to the symmetric HslU hexamer. Since eukaryotic proteasomes have a similar additional N-terminal sequence, our results will improve our understanding of the common molecular mechanisms for the activation of proteasomes.

Fatigue Crack Growth of Welded-Structural Steel under Simple-Variable Loading (단순변동하중(單純變動荷重)을 받는 용접구조용강(鎔接構造用鋼)의 피로균열성장(疲勞龜裂成長))

  • Chang, Dong Il;Bak, Yong Gul;Lee, Bong Hak
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.7 no.4
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    • pp.103-113
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    • 1987
  • Fatigue tests using a single-peak loading and a two-step loading were carried out to examine the fatigue crack growth behaviar and to find the appropriate analysis method. C-T specimens were made using structural steel SWS58 for the tests. From this, just after a single-peak loading acceleration effect was occured and after some times retardation effect was found. And eminent retardation effect was found after High-Low two-step loading. The transition effect of crack growth due to this variable loading was occured owing to the residual stress and the plastic zone size at the crack tip. And the behaviors of these are well explained by Elber's Crack Closure Model. Also I could find that the Wheeler's Retardation Model is a simple and appropriate theory among analysis methods of fatigue crack growth under the variable loading.

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Structural Changes and Dielectric Properties of$Pb(Mg_{1}{3}Nb_{2}{3})O_3$Ceramics Substituted by$Na^+/La^{3+}$Ions ($Na^+/La^{3+}$이온으로 치환된$Pb(Mg_{1}{3}Nb_{2}{3})O_3$의 구조 변화 및 유전 성질)

  • Hong, Young-Sik;Park, Hyu-Bum;Ahn, Tae-Ho;Kim, Si-Joong
    • Journal of the Korean Chemical Society
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    • v.40 no.9
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    • pp.607-614
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    • 1996
  • The structural changes and dielectric properties of Pb1-x(Na1/2La1/2)x(Mg1/3Nb2/3)O3 compounds substituted by 0∼50 mol.% of Na+/La3+ mixed ions were investigated by X-ray diffraction method, IR and Raman spectroscopy, and LCR meter. The amount of perovskite phase increased with the increases of Na+/La3+ substituents and sintering temperatures. Although the superlattice lines due to 1:1 ordering were not detected by X-ray diffraction method, it was found, from the Raman spectroscopy and the increase of diffuseness coefficient, that the ordering behavior was related to the decrease of A site ion size. Dielectric properties in Pb1-x(Na1/2La1/2)x(Mg1/3Nb2/3)O3 were affected by the amount of perovskite phase, grain size, and density. The phase transitions were broadened and phase transition temperatures were lowered by the increase of Na+/La3+ ions.

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