• Journal of Surface Science and Engineering
• /
• v.32 no.3
• /
• pp.440-443
• /
• 1999

The morphology and composition of anodic films, formed on aluminium at various current densities, in the range 1-$100{\;}Am^{-2}$, in the molten bisulphate melt at different temperatures (418-498K), have been studied using transmission electron microscopy of ultramicrotomed film sections, and ion beam thinned films. From the structural analysis of the electron diffraction patterns taken from the ultramicrotomed sections and ion beam thinned films, it can be concluded that the crystal modification process from ${\gamma}-Al_2O_3{\;}to{\;}{\alpha}-Al_2O_3$ proceeds in the following steps : (equation omitted)

• Bulletin of the Korean Chemical Society
• /
• v.18 no.4
• /
• pp.395-401
• /
• 1997

The substituent effects in the gas-phase rearrangement of carbenes to ketenes involved in the Wolff reaction have been investigated theoretically using the AM1 method. In the initial state, carbene, there is a relatively strong vicinal n-σ* interaction between the lone pair (n) and carbonyl group (σ*). In the bridged transition state (TS), electronic charge is transferred from the migrating ring (Z-ring) toward the nonmigrating ring (Y-ring). The carbenes are stabilized by an electron donor Y (δσY < 0) whereas the TS is stabilized by an electron acceptor Y (δσY > 0). Multiple regression analysis of log (kYZ/kHH)(=-δΔG≠/2.3RT) leads to a relatively large negative cross-interaction constant, ρYZ=-0.53, log (kYZ/kHH)=2.96 σY--1.40 σZ-0.53 σY-σZ reflecting an extensive structural change in the transition state due to the stabilization of the initial state by the vicinal n-σ* overlap. When the solvent (water) effects are accounted for by the SM2.1 model of the Cramer and Truhlar method, the magnitude of all the selectivity parameters, ρY-, ρZ and ρYZ (=-0.66) are increased.

• Bulletin of the Korean Chemical Society
• /
• v.21 no.12
• /
• pp.1187-1192
• /
• 2000

Ternary (Mo-Ru-Pd) and binary (Mo-Ru, Mo-Pd) alloys have been prepared using an Ar arc melting furnace. Mo and the noble metals, Ru and Pd, are the constituents of metallic insoluble residues, which were found in the early days of post-irradiation studies on uranium oxide fuels. In the present study, the structure of the alloys was evaluated using a powder X-ray diffractometer. Unit cell parameters were determined by least squares refinements of powder X-ray diffraction data. Scanning electron microscopic analyses of the surface of the alloys indicated that surface morphology was dependent on the crystallographic structure as well as its composition. Measurements of the magnetic susceptibility of the alloys showed evidence of superconducting transition from 3 to 9.2 K. Among the ternary and binary alloys, the ${\sigma}-phase$ showed the highest superconducting transition temperature,~9.2 K.

• Molecules and Cells
• /
• v.21 no.2
• /
• pp.229-236
• /
• 2006

Gaegurin 4 (GGN4), a novel peptide isolated from the skin of a Korean frog, Rana rugosa, has broad spectrum antimicrobial activity. A number of amphipathic peptides closely related to GGN4 undergo a coil to helix transition with concomitant oligomerization in lipid membranes or membrane-mimicking environments. Despite intensive study of their secondary structures, the oligomeric states of the peptides before and after the transition are not well understood. To clarify the structural basis of its antibiotic action, we used analytical ultracentrifugation to define the aggregation state of GGN4 in water, ethyl alcohol, and 1,1,1,3,3,3-hexafluoro-2-propanol (HFIP). The maximum size of GGN4 in 15% HFIP corresponded to a decamer, whereas it was monomeric in buffer. The oligomeric transition is accompanied by a cooperative 9 nm blue-shift of maximum fluorescence emission and a large secondary structure change from an almost random coil to an ${\alpha}$-helical structure. GGN4 induces pores in lipid membranes and, using electrophysiological methods, we estimated the diameter of the pores to be exceed $7.3{\AA}$, which suggests that the minimal oligomer structure responsible is a pentamer.

• Journal of Convergence for Information Technology
• /
• v.9 no.3
• /
• pp.82-89
• /
• 2019

The reason why NCS education is conducted in college is because students are expected to improve their skills through practical education. In addition, NCS education is expected to have a positive impact on job competence and competitiveness. The purpose of this study is to explain the necessity of NCS education, and to analyze whether the education transition and practical performance are manifested. For this purpose, the research model was composed of "NCS Education ${\Rightarrow}$ Educational Transition ${\Rightarrow}$ Practical Results" and surveyed about 300 college students in the metropolitan area. If NCS education is necessary in practice, colleges and other educational institutions should plan to make NCS education operate efficiently. As a analysis result, it was confirmed that the internal consistency was secured and both the intensive validity & discriminant validity were confirmed in the validity. As a result of using the structural equation model, this research model was found to be suitable. As a result of the hypothesis test, it is analyzed that the standardization coefficient of the research hypothesis is above the appropriate level and the correlation is highly formed.

• Proceedings of the Korean Vacuum Society Conference
• /
• 2012.08a
• /
• pp.169-169
• /
• 2012

The high-temperature superconductor YBa2Cu3O7-x (YBCO) have attached attentions because of a high superconducting transition temperature, low surface resistance, high superconducting critical current density (Jc), and superior superconducting capability under magnetic field. Moreover, the Jc of YBCO superconductors can be enhanced by adding impurities to the YBCO films for vortex-pinning. Understanding and controlling pinning centers are key factors to realize high Jc superconductors. We synthesized vertically-aligned ZnO nanorods on SrTiO3 (STO) substrates by catalyst-free metal-organic chemical vapor deposition (MOCVD), and subsequently, deposited YBCO films on the ZnO nanorods/STO templates using pulsed laser deposition (PLD). The various techniques were used to analyze the structural and interfacial properties of the YBCO/ZnO nanorods/STO hybrid structures. SEM, TEM, and XRD measurements demonstrated that YBCO films on ZnO nanorods/STO were well crystallized with the (001) orientation. EXAFS measurements from YBCO/ZnO nanorods/STO at Cu K edge demonstrated that the local structural properties around Cu atoms in YBCO were quite similar to those of YBCO/STO.

• Advances in aircraft and spacecraft science
• /
• v.4 no.6
• /
• pp.613-637
• /
• 2017

The development systems for the Structural Health Monitoring has attracted considerable interest from several engineering fields during the last decades and more specifically in the aerospace one. In fact, the introduction of those systems could allow the transition of the maintenance strategy from a scheduled basis to a condition-based approach providing cost benefits for the companies. The research presented in this paper consists of a definition and next comparison of four methods applied to numerical measurements for the extraction of damage features. The first method is based on the determination of the Structural Intensity field at the on-resonance condition in order to acquire information about the dissipation of vibrational energy throughout the structure. The Damage Quantification Indicator and the Average Integrated Global Amplitude Criterion methods need the evaluation of the Frequency Response Function for a healthy plate and a damaged one. The main difference between these two parameters is their mathematical definition and therefore the accuracy of the scalar values provided as output. The fourth and last method is based on the Mode-shape Curvature, a FRF-based technique which requires the application of particular finite-difference schemes for the derivation of the curvature of the plate. All the methods have been assessed for several damage conditions (the shape, the extension and the intensity of the damage) on two test plates: an isotropic (steel) plate and a 4-plies composite plate.

• Fashion & Textile Research Journal
• /
• v.4 no.2
• /
• pp.198-202
• /
• 2002

Degummed silk from Bombyx mori was dissolved in 9.3M lithium bromide solution. The regenerated silk fibroin films were completely ${\alpha}$-randomcoil type as shown by x-ray diffraction and infrared spectroscopy. The structural changes in silk fibroin induced by immersion into methanol and dilute hydrochloric acid and its photo-yellowing effect was studied. The changes of crystallinity were measured by infrared spectrometer. Yellowness index caused by ultraviolet irradiation were observed as a function of the structural change on silk fibroin. On treatment with methanol, ${\alpha}$-randomcoil silk film is converted to the ${\beta}$-form structure. After the treatment of hydrochloric acid on ${\beta}$-form structure in silk induced by immersion into methanol, ${\beta}$-form in silk fibroin is partially decreased. Crystallization owing to ${\beta}$-form transition reduced the initial yellowness index by ultraviolet irradiation. A little ${\beta}$-form structure in silk fibroin increased the initial yellowness in comparison with more ${\beta}$-form structure.

• Journal of Mechanical Science and Technology
• /
• v.19 no.11
• /
• pp.1988-1997
• /
• 2005

This study is concerned with structural integrity evaluations for the interference-fit flywheels in reactor coolant pumps (RCPs) of nuclear power plants. Stresses in the flywheel due to the shrinkage loads and centrifugal loads at the RCP normal operation speed, design overspeed and joint-release speed are obtained using the finite element method (FEM), where release of the deformation-controlled stresses as a result of structural interactions during rotation is considered. Fracture mechanics evaluations for a series of cracks assumed to exist in the flywheel are conducted, considering ductile (fatigue) and non-ductile fracture, and stress intensity factors are obtained for the cracks using the finite element alternating method (FEAM). From analysis results, it is found that fatigue crack growth rates calculated are negligible for smaller cracks. Meanwhile, the material resistance to non-ductile fracture in terms of the critical stress intensity factor (K$_{IC}$) and the nil-ductility transition reference temperature (RT$_{NDT}$) are governing factors for larger cracks.

• Journal of the Korean Ceramic Society
• /
• v.54 no.6
• /
• pp.484-491
• /
• 2017

Chalcogenide glasses have been investigated in their thermodynamic, structural, and optical properties for application in various opto-electronic devices. In this study, the $Sb_{20}Se_{80-x}Ge_x$ with x = 10, 15, 20, and 25 were selected to investigate the glass stability according to germanium ratios. The thermal, structural, and optical properties of these glasses were measured by differential scanning calorimetry (DSC), X-ray diffraction (XRD), and UV-Vis-IR Spectrophotometry, respectively. The DSC results revealed that $Ge_{20}Sb_{20}Se_{60}$ composition showing the best glass stability theoretically results due to a lower glass transition activation energy of 230 kJ/mol and higher crystallization activation energy of 260 kJ/mol. The structural and optical analyses of annealed thin films were carried out. The XRD analysis reveals obvious results associated with glass stabilities. The values of slope U, derived from optical analysis, offered information on the atomic and electronic configuration in Urbach tails, associated with the glass stability.