• Journal of Pharmaceutical Investigation
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• v.27 no.2
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• pp.119-123
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• 1997

The physicochemical and structural properties of new capsaicin derivative, DA-5018, were examined. The reference standard of this compound was obtained by the recrystallization. A method for the determination of the dissociation constant of the compound is described. pH-solubility and distribution coefficient were determined by chromatographic method. Fundamental properties on thermal behaviors were investigated by TG, DTA and DSC. Structural analysis based on spectroscopic method coincided with the chemical structure of DA-5018. Approximate dissociation constant of the compound determined by UV spectral method was 9.35. Solubilities and partition coefficients in various pH buffer solution appeared pH-dependency. No crystal transition or further transition was found in the thermal analysis. This compound showed good stability, but pH 13 buffer and acetone made some degradative products.

• Resources Recycling
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• v.31 no.1
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• pp.46-55
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• 2022

The recycling of coated cemented carbide scraps is becoming increasingly significant for the recovery of rare metals. However, coatings consisting of Group IV and V transition metal nitrides are one of the challenging factors in obtaining high-purity materials. We investigated the structural, elastic, and mechanical properties of Group IV and V transition-metal nitrides (TiN, VN, ZrN, NbN, HfN, and TaN) using first-principle calculations. Convergence tests were performed to obtain reliable calculated results. The equilibrium structures of the nitrides were in good agreement with those of a previous study, indicating the reliability of the data. Group IV transition metal nitrides show a higher covalent bonding nature. Thus, they exhibit a higher degree of brittleness than that of Group V transition metal nitrides. In contrast, Group V transition metal nitrides show weaker resistance to shear loading and more ductile behavior than Group IV transition metal nitrides because of the metallic bonds characterized by valence electron concentration. The results of the crystal orbital Hamilton population analysis showed good agreement with the shear resistance tendencies of all transition metal nitrides.

• Structural Engineering and Mechanics
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• v.42 no.2
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• pp.131-152
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• 2012

In-plane free vibrations of circular beams with stepped cross-sections are investigated by using the exact analytical solution. The axial extension, transverse shear deformation and rotatory inertia effects are taken into account. The stepped arch is divided into a number of arches with constant cross-sections. The exact solution of the governing equations is obtained by the initial value method. Several examples of arches with different step ratios, different locations of the steps, boundary conditions, opening angles and slenderness ratios for the first few modes are presented to illustrate the validity and accuracy of the method. The effects of the geometric parameters on the natural frequencies are investigated in details. Several examples in the literature are solved and the results are given in tables. The agreement of the results is good for all examples considered. The mode transition phenomenon is also observed for the stepped arches. Some examples are solved also numerically by using the commercial finite element program ANSYS.

• Steel and Composite Structures
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• v.18 no.1
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• pp.135-148
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• 2015

The cutout hole locating at the place of rib-to-diaphragm welded connection is adopted to minimize the restraint, which is caused by the floor-beam web to rib rotation at the support due to the unsymmetrical loads in orthotropic deck. In practice, an inevitable problem is that there is a large number of welding joint's cracks formed at the edge of cutout hole. In this study, a comparative experiment is carried out with two types of cutout hole, the circular arc transition and the vertical transition. The fatigue life estimation of specimens is investigated with the application of the structural hot spot stress approach by finite element analyses. The results are compared with the ones of the fatigue tests which are carried out on these full-scale specimens. Factors affecting the stress range are also studied.

• Journal of the Korean Ceramic Society
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• v.28 no.6
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• pp.465-470
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• 1991

AlN powder was synthesized by carbothermal reduction and nitridation of aluminum hydroxides precipitated in 5∼11 pH range from Al2(SO4)3$.$18H2O aqueous solution. Nitridation reactivity of hydroxide, which depends on precipitation pH, reaction temperature and time, was examined by XRD analysis at 1200∼1350$^{\circ}C$ and compared with that of commercial ${\alpha}$-Al2O3. Hydroxides obtained at higher pH could be more easily nitridated and, considering DTA/TG and BET results, the reason seems to be specific surface area difference of reactants depending on the content of decomposed structural water and the transition rate from transition-Al2O3 to ${\alpha}$-Al2O3.

• Proceedings of the KSME Conference
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• 2004.11a
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• pp.1158-1161
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• 2004

Shell shaped hollow carbon nanoparticles are synthesized in the oxygen-hydrogen diffusion flame with $C_{2}H_{2}$ as precursor when it is irradiated with $CO_{2}$ laser of certain power. Below this power of laser, we couldn't get any other but amorphous soot. This shell shaped hollow carbon nanoparticles shows outer wall of high degree of crystallinity with void space inside of itself. And size distribution of these nanoparticles is measured with TEM image analysis. Also the structural comparison between this carbon nanoparticle and soot is done by Raman and XRD measurement. These results show this carbon nanoparticles are of grapheme structure, which means it has good crystallinity when compared with soot.

• Journal of the Korean Society for information Management
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• v.6 no.2
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• pp.21-44
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• 1989

This study investigates author cocitation and author transition analysis which are two techniques to be used to construct author and concept networks by using a test collection of 4, 598 documents on the subject of chemistry. The author and concept networks can be used to understand the structual Knowledge of terms as well as intellectual structure of science. So, these networks could be basic data of knowledge base for subject literature.

• Structural Engineering and Mechanics
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• v.43 no.4
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• pp.449-458
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• 2012

Finite element buckling analysis of insulated transition flue ducts is carried out to determine the critical buckling load multipliers when subjected to axial compression for design process. Through this investigation, the results of numerical computations to examine the buckling strength for different possible duct shapes (cylinder, and circular-to-square) are presented. The load multipliers are determined through detailed buckling analysis taking into account the effects of geometrical construction and duct plate thickness which have great influence on the buckling load. Enhancement in the buckling capacity of such ducts by the addition of horizontal and vertical stiffeners is also investigated. Several models with varying dimensions and plate thicknesses are examined to obtain the linear buckling capacities against duct dimensions. The percentage improvement in the buckling capacity due to the addition of vertical stiffeners and horizontal Stiffeners is shown to be as high as three times for some cases. The study suggests that the best location of the horizontal stiffener is at 0.25 of duct depth from the bottom to achieve the maximum buckling capacity. A design equation estimating the buckling strength of geometrically perfect cylindrical-to-square shell is developed by using regression analysis accurately with approximately 4% errors.

• Structural Engineering and Mechanics
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• v.3 no.4
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• pp.325-340
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• 1995

The iterative procedure to use the nonconforming elements in elasto-plastic problems is established and applied to the variable node transition solid element developed for the automated three-dimensional local mesh refinement. Through numerical tests, the validity and performance of the element are examined. As the nonlinear iterative procedure presented in this paper is accomplished for the general three-dimensional case, it can also be easily applied to the two-dimensional elements such as membranes, plates and shells.

• Macromolecular Research
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• v.8 no.5
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• pp.231-237
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• 2000

The polymerization of 3-ethynylphenol, phenylacetylene having hydroxy functionality, was carried out by tungsten and molybdenum-based transition metal catalysts. The polymerization proceeded to give a moderate yield of polymer. The effects on the mole ratio of monomer to catalyst (M/C), initial monomer concentration ((Mb), and the polymerization temperature for the polymerization of 3-ethynylphenol were investigated. The catalytic activity of W-based catalysts was found to be greater than that of Mo-based catalysts. The resulting polymers were brown or black powders and mostly insoluble in organic solvents. Structural analysis of the polymer by instrumental methods revealed the conjugated polymer backbone structure carrying hydroxyphenyl moieties. Thermal and morphological properties of the resulting poly(3-ethynylphenol) were also discussed.