• Bulletin of the Korean Chemical Society
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• v.27 no.1
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• pp.150-152
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• 2006

• YAKHAK HOEJI
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• v.37 no.1
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• pp.36-40
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• 1993

The 4-(2'-(N-(l-methyl-3'-carbamylphenyl)-n-propyl))aminoethyl)-l- hydroxy-2-pyridone which has isoelectronic and isosteric structural similarity with dobutamine without having the Catechol-O- Methyltransferase(COMT) vulnerable m-hydroxy group was synthesized via 12 synthetic steps.

• Proceedings of the Materials Research Society of Korea Conference
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• 2006.11a
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• pp.32.2-32.2
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• 2006

• Bulletin of the Korean Chemical Society
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• v.22 no.11
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• pp.1280-1282
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• 2001

• Proceedings of the Korean Magnestics Society Conference
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• 2008.12a
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• pp.206.2-206.2
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• 2008

• Bulletin of the Korean Chemical Society
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• v.10 no.3
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• pp.321-322
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• 1989

• Bulletin of the Korean Chemical Society
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• v.34 no.7
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• pp.2016-2022
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• 2013

Ionically modified ${\beta}$-cyclodextrins, which have excellent water-solubility, have been interested in purification technology as well as drug carrier system. The present study summarizes the synthesis and characterization of cationic and anionic ${\beta}$-cyclodextrin (${\beta}$-CyD) products using by polycondensation. The oligo (${\beta}$-CyD)s are synthesized from ${\beta}$-CyD, epichlorohydrin (EP) and choline chloride (CC; for cationic polymer) or chloroacetic acid (CAA; for anionic polymer) through one step polycondenstaion process. Unlike the previous studies, we successfully purified the ionic ${\beta}$-CyD condensation products from the ${\beta}$-CyD reaction mixtures and accomplished a great level of structural analysis. The detailed structural analysis of these ionic ${\beta}$-CyD compounds is done by $^1H$ NMR, MALDI-TOF as well as GPC analysis and confirms the formation of oligomers with a few units of ${\beta}$-CyD. We found that the sequence of reactant addition also could effect on the molecular weight of the resulting product as well as the molar ratio of the reactants. Finally, we used the cationic and anionic ${\beta}$-CyD oligomers for fabricating multilayer films by layer-layer process.

• Journal of the Korean Society for Aeronautical & Space Sciences
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• v.32 no.6
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• pp.34-48
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• 2004

In this paper an optimization algorithm is suggested to reduce the huge computation time in the optimum design of large structures, especially in spacecraft structures. It combines the coupled load analysis model using a constrained mode of component mode synthesis and the modal transient analysis. The computer simulation code is developed and evaluated in optimizing spacecraft platforms. The developed algorithm can alleviate the computational load with adequate accuracy. From the optimization of a spacecraft structural member, the characteristics of each structural member can be understood.

• Journal of KSNVE
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• v.8 no.1
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• pp.180-186
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• 1998

Vibration test fixture is used in random vibration control testing. The specified reference spectrum should be transmitted equally to the specimen attachment points on the fixture. In most practical cases, however, spectrum at each of specimen attachment points may be quite different from the specified reference spectrum because of the dynamic characteristics of vibration test fixture. This paper proposes the method of experimental dynamic modification of fixture system for vibration test so that the reference spectrum can be transmitted to the specimen attachment points without distortion. The stiffness of mounts of specimen and the thickness of fixture are considered as design variables. The frequency response functions of specimen used for input data are obtained from vibration testing, and the frequency response functions of fixture are obtained from finite element modeling. The sensitivities of frequency response functions at specimen attachment points to the mount stiffness are derived from synthesis method of transfer function. And the sensitivities to the thickness of fixture are also derived from finite element modeling. The presented method is verified by computer simulation and vibration testing.

• Progress in Superconductivity and Cryogenics
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• v.26 no.2
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• pp.5-8
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• 2024

Recently, Lee et al. claimed that LK-99 isthe first room-temperature superconductor at ambient pressure, which quickly captured the attention of both the scientific community and the general public. We tried to replicate Pb_10-xCu_x(PO₄)₆O, called as LK-99, and characterized its physical properties by measuring the electrical resistance and Meissner effect. The electrical resistance results for different batches exhibited structural phase transitions at different temperatures, and the magnetic measurements indicated weak diamagnetism at 300 K, which is weaker than that of water. Taken together with the structural analysis, these results suggest that the resistivity transitions are incurred by Cu-S compound generated as a byproduct during the synthesis of LK-99 and LK-99 is not a room-temperature superconductor.