• Corrosion Science and Technology
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• 제7권5호
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• pp.243-251
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• 2008

Magnesium alloys become popular research topic in last decade due to its light weight and relatively high strength-to-weight ratio in the energy aspiration age. Almost all structure materials are supposed to suspend stress. Magnesium is quite sensitive to corrosive environment, and also sensitive to environmental assisted cracking. However, so far we have the limited knowledge about the environmental sensitive cracking of magnesium alloys. The corrosion fatigue (CF) test was conducted. Many factors' effects, like grain size, texture, heat treatment, loading frequency, stress ratio, strain rate, chemical composition of environment, pH value, relative humidity were investigated. The results showed that all these factors had obvious influence on the crack initiation and propagation. Especially the dependence of CF life on pH value and frequency is quite different to the other traditional structural metallic materials. In order to interpret the results, the electrochemistry tests by polarization dynamic curve and electrochemical impedance spectroscopy were conducted with and without stress. The corrosion of magnesium alloys was also studied by in-situ observation in environmental scanning electron microscopy (ESEM). The corrosion rate changed with the wetting time during the initial corrosion process. The pre-charging of hydrogen caused crack initiated at $\beta$ phase, and with the increase of wetting time the crack propagated, implying that hydrogen produced by corrosion reaction participated in the process.

• 대한기계학회논문집A
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• 제24권1호
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• pp.156-162
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• 2000

Sensitized STS 304 stainless steel crack growth rate(CGR) in high temperature water was investigated under trapezoidal wave loading test using fracture mechanics techniques. The CGR, due to stress corrosion cracking(SCC), were systematically measured as a function of the stress intensity factor and stress. holding time under trapezoidal wave loading. In high temperature water, CGR was enhanced by a synergistic effects in combination with an aggressive environment and mechanical damage. The CGR, $(da/dN)_{env}$ was basically described as a summation of the environmentally assisted crack growth rate $(da/dN)_{SCC}$, $(da/dN)_{CF}$ and fatigue crack growth rate in air $(da/dN)air,. The CGR, $(da/dN)_{env}$, increased linearly with increasing stress holding time. The CGR, $(da/dN)_{SCC}$ decreased linearly with increasing stress holding time. Fracture surface mode varied from trans-granular cracking to inter-granular cracking with increasing stress holding time.

• 한국해양공학회지
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• 제2권2호
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• pp.122-129
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• 1988

Recently with the rapid development in marine and shipbuliding industries such as marine structures, ship and chemical plants, there occurs much interest in the study of corrosion fatigue characteristics which was closed up an important role in mechanical design. In this study, the 5086 Al-alloy was tested by use of rotary bending fatigue tester. The retardation effect of overload on the corrosion fatigue crack propagation in sea environment was quantitatively studied. 1) Retardation effect of corrosion fatigue crack propagation is most eminent when overload ratio is 1.52, overload magnitude corresponds to about 77% and 55% of yield strength and tensile strength respectively. 2) After overload ratio 1.52 was used, retardation of corrosion fatigue crack growth rate is largely retarded and quasi-threshold stress intensity factor range($\Delta\textrm{K}_{th}$) appears. 3) According to m of experimental constant, retardation effect of corrosion fatigue crack propagation corresponds to about 25% of constant stress amplitude when overload ratio is 1.52. 4) When overload ratio 1.52 was used, retardation parameter (RP) decreases to about 0.43 and corrosion sensitivity (S)decreses to about 2.1.

• 수산해양기술연구
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• 제25권2호
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• pp.87-104
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• 1989

Recently, with the tendency of more lightening, high-strength and high-speed in the marine industries such as marine structures, ships and chemical plants, the use of the aluminium Alloy is rapidly enlarge and there occurs much interest in the study of corrosion fatigue crack characteristics. In this paper, the initiation of surface crack and the propagation characteristics on the base metal and weld zone of 5086-H116 Aluminium Alloy Plate which is one of the Al-Mg serious alloy(A5000serious) used most when building the special vessels, were investigated by the plane bending corrosion fatigue under the environments of marine, air and applying cathodic protection. The effects of various specific resistances on the initiation, propagation behavior of corrosion fatigue crack and corrosion fatigue life in the base metal and heat affected zone were examined and its corrosion sensitivity was quantitatively obtained. The effects of corrosion on the crack depth in relation to the uniform surface crack length were also investigated. Also, the structural, mechanical and electro-chemical characteristics of the metal at the weld zone were inspected to verify the reasons of crack propagation behavior in the corrosion fatigue fracture. In addition, the effect of cathodic protection in the fracture surface of weld zone was examined fractographically by Scanning Electron Microscope(S.E.M.). The main results obtained are as follows; (1) The initial corrosion fatigue crack sensitibity under specific resistance of 25Ω.cm% show 2.22 in the base metal and 19.6 in the HEZ, and the sensitivity decreases as specific resistance increases (2) By removing reinforcement of weldment, the initiation and propagation of corrosion crack in the HAZ are delayed, and corrosion fatigue life increases. (3) As specific resistance decreases, the sensitivity difference of corrosion fatigue life in the base metal and HAZ is more susceptible than that of intial corrosion fatigue crack. (4) Experimental constant, m(Paris' rule) in the marine environment is in the range of about 3.69 to 4.26, and as specific resistance increases, thje magnitude of experimental constant, also increases and the effect by corrosion decreases. (5) Comparing surface crack length with crack depth, the crack depth toward the thickness of specimen in air is more deeply propagated than that in corrosion environment. (6) The propagation particulars of corrosion fatigue crack for HAZ under initial stress intensity factor range of $\Delta$k sub(li) =27.2kgf.mm super(-3/2) and stress ratio of R=0 shows the retardative phenomenon of crack propagation by the plastic deformation at crack tip. (7) Number of stress cycles to corrosion fatigue crack initiation of the base metal and the welding heat affected zone are delayed by the cathodic protection under the natural sea water. The cathodic protection effect for corrosion fatigue crack initiation is eminent when the protection potential is -1100 mV(SCE). (8) When the protection potential E=-1100 mV(SCE), the corrosion fatigue crack propagation of welding heat affected zone is more rapid than that of the case without protection, because of the microfissure caused by welding heat cycle.

• Journal of Welding and Joining
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• 제6권2호
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• pp.56-63
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• 1988

The effects of PWHT (poste weld heat treatment) and stress simulating the residual stress during PWHT in weld HAZ of low and high strength steels on corrosion fatigue crack growth were evaluated. The obtained results are summarized as follows. 1. Fatigue crack growth rate of HAZ in air and 3.5% NaCl solution was slower than that of parent due to the signgularity in weld HAZ. 2. In the case of HT-80, 3.5% NaCl solutio nacts to accelerate the crack growth for all specimens, and the sensitivity of as-weld to corrosion environment was the greatest among other PWHT specimens. 3. Corrosion fatigue crack growth of parent, as-weld and PWHT speciments ofr SS41 as well as SM53B was retarded in comparison with the fatigue crack growth in air. 4. There was a tendency that crack growth of PWHT specimens subjected $10kg/mm^2$ was faster than that of PWHT specimens without stress during PWHT. 5. The retardation phenomenon of crack growth in corrosion environment is attributed to the crack branching decreased .DELTA.K due to the corrosion products and multi-cracks.

• 대한조선학회논문집
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• 제44권4호
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• pp.417-424
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• 2007

With regard to corrosion fatigue crack initiation life (Nc), it has been treated ambiguously for the member which doesn't have stress concentration area. In this research, in order to clarify the corrosion fatigue crack initiation life (Nc), corrosion fatigue tests were carried out. Reasonable and universal corrosion fatigue crack initiation life (Nc) was defined and corrosion fatigue crack initiation/propagation model was suggested also. As the fatigue crack which emanates from the pit is usually small, accordingly it is treated as a small crack. In addition, the observation of the corrosion fatigue fracture surfaces using SEM was conducted. And the fracture mechanics analysis using an intrinsic crack model was conducted for the treatment of the small crack. Finally, the followings were obtained. When there is no clear stress concentration point which seems to fall into a corrosion fatigue crack initiation life, the significance of the definition and suggestion of the moment of the reasonable and universal corrosion fatigue crack initiation life (Nc), at which the fatigue crack propagation rate becomes faster than the corrosion pit growth rate so that the fatigue crack initiates from the pit and propagates in earnest, has been clarified.

• 한국자동차공학회논문집
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• 제14권3호
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• pp.88-94
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• 2006

The compressive residual stress, which is induced by shot peening process, has the effect of increasing the intrinsic fatigue strength of surface and therefore would be beneficial in reducing the probability of fatigue damage. However, the effect of shot peening in corrosion environment was not known. In this study, investigated is the effect of shot peening on corrosion fatigue crack growth of SAE 5155 steel immersed in 6% $FeCl_3$ solution and corrosion characteristics with considering fracture mechanics. The results of the experimental study corrosion fatigue characteristics of SAE 5155 are as follows; the fatigue crack growth rate of the shot peening material was lower than that of the non-peening material. And fatigue life shows more improvement in the shot peening material than in non-peening material. This is due to the compressive residual stress of surface increases resistance of corrosion fatigue crack propagation. It is assumed that the shot peening process improve corrosive resistance and mechanical property.

• Corrosion Science and Technology
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• 제6권4호
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• pp.170-176
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• 2007

Iodine-induced stress corrosion cracking (ISCC) properties and the associated ISCC process of Zircaloy-4 and an Nb-containing advanced nuclear fuel cladding were evaluated. An internal pressurization test with a pre-cracked specimen was performed with a stress-relieved (SR) or recrystallized (RX) microstructure at $350^{\circ}C$, in an iodine environment. The results showed that the $K_{ISCC}$ of the SR and RX Zircaloy-4 claddings were 3.3 and 4.8MPa\;m^{0.5}, respectively. And the crack propagation rate of the RX Zircaloy-4 was 10 times lower than that of the SR one. The chemical effect of iodine on the crack propagation rate was very high, which was increased $10^4$ times by iodine addition. Main factor affecting on the micro-crack nucleation was a pitting formation and its agglomeration along the grain boundary. However, this pitting formation on the grain-boundary was suppressed in the case of an Nb addition, which resulted in an increase of the ISCC resistance when compared to Zircaloy-4. Crack initiation and propagation mechanisms of fuel claddings were proposed by a grain boundary pitting model and a pitting assisted slip cleavage model and they showed reasonable results.

• 수산해양기술연구
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• 제24권2호
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• pp.94-100
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• 1988

평면 굽힘부식피로 시험기를 사용하여 선박용 알루미늄합금재의 부식피로파양에 관한 연구를 한 결과 다음과 같은 결론을 얻었다. 1. 비저항이 증가함에 따라서 초기 부식피로균열발생까지의 반복회수는 지연되고, 그 부식감수성은 감소하는 양상을 나타낸다. 2. 비저항이 감소할수록 Paris rule의 실험상수 m 값은 작아지면서 응력강도 계수값에 비해 부식에 의한 영향이 더욱 민감해 진다. 3. 알루미늄 5086 합금의 부식피로균열은 입계균열파양의 양상을 보이고 있다. 4. 응력강도계수값이 증가함에 따라 부식감수성은 감소되어지고 응력강도계수값이 40kg.mm super(-3/2) 이상일 때 부식감수성은 거의 균일하게 된다.

• Corrosion Science and Technology
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• 제7권6호
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• pp.307-314
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• 2008

The influence of a moist atmosphere on $90^{\circ}$ domain switching under a sustained electric field, stress corrosion cracking of an indentation crack in water and an aggressive solution, and the relation between penetrating crack propagation and domain switching were studied using $BaTiO_3$ single crystal. The results indicate that enlarging the domain switching zone and crack propagation could be facilitated by a moist atmosphere or an aggressive solution due to the indentation residual stress. A moist atmosphere exerts remarkable influence upon the polarization of $BaTiO_3$ single crystal under a sustained electric field, and the surface energy of the c domain was much lower than that of the a domain. Domain switching ahead of a penetrating indentation crack tip was an essential requirement for crack propagation under constant stress.