• Title/Summary/Keyword: Strength degradation

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Persistence of Fungicide Pencycuron in Soils (토양 중 살균제 Pencycuron의 잔류 특성)

  • An, Xue-Hua;An, Wen-Hao;Im, Il-Bin;Lee, Sang-Bok;Kang, Jong-Gook
    • The Korean Journal of Pesticide Science
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    • v.10 no.4
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    • pp.296-305
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    • 2006
  • The adsorption and persistence of pencycuron {1-(4-chlorobenzyl) cyclopentyl-3-phenylurea} in soils were investigated under laboratory and field conditions to in order to assess the safety use and environmental impact. In the adsorption rate experiments, a significant power function of relation was found between the adsorbed amount of pencycuron and the shaking time. Within one hour following the shaking, the adsorption amounts in the SCL and the SiCL were 60 and 65% of the maximum adsorption amounts, respectively. The adsorption reached a quasi-equilibrium 12 hours after shaking. The adsorption isotherms followed the Freundlich equation. The coefficient (1/n) indicating adsorption strength and degree of nonlinearity was 1.45 for SCL and 1.68 to SiCL. The adsorption coefficients ($K_d$) were 2.31 for SCL and 2.92 to SiCL, and the organic carbon partition coefficient, $K_{oc}$, was 292.9 in SCL and 200.5 inSiCL. In the laboratory study, the degradation rate of pencycuron in soils followed a first-order kinetic model. The degradation rate was greatly affected by soil temperature. As soil incubation temperature was increased from 12 to $28^{\circ}C$, the residual half life was decreased from 95 to 20 days. Arrhenius activation energy was 57.8 kJ $mol^{-1}$. Furthermore, the soil moisture content affected the degradation rate. The half life in soil with 30 to 70% of field moisture capacity was ranged from 21 to 38 days. The moisture dependence coefficient, B value in the empirical equation was 0.65. In field experiments, the half-life were 26 and 23 days, respectively. The duration for period of 90% degradation was 57 days. The difference between SCL and SiCL soils varied to pencycuron degradation rates were very limited, particularly under the field conditions, even though the characteristics of both soils are varied.

An innovative experimental method to upgrade performance of external weak RC joints using fused steel prop plus sheets

  • Kheyroddin, Ali;Khalili, Ali;Emami, Ebrahim;Sharbatdar, Mohammad K.
    • Steel and Composite Structures
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    • v.21 no.2
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    • pp.443-460
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    • 2016
  • In this paper, the efficiency and effectiveness of two strengthening methods for upgrading behavior of the two external weak reinforced concrete (RC) beam-column joints were experimentally investigated under cyclic loading. Since two deficient external RC joints with reduced beam height and low strength concrete were strengthened using one-way steel prop and curbs with and without steel revival sheets on the beam. The cyclic performance of these strengthened specimens were compared with two another control external RC beam-column joints, one the standard RC joint that had not two mentioned deficiencies and another had both. Therefore, four half-scale RC joints were tested under cyclic loading.The experimental results showed that these innovative strengthening methods (RC joint with revival sheet specially) surmounted the deficiencies of weak RC joints and upgraded their performance and bearing capacity, stiffness degradation, energy absorption, up to those of standard RC joint. Also, results exhibited that the prop at joint acted as a fuse element due to adding steel revival sheets on the RC beam and showed better behavior than that of the specimen without steel revival sheets. In other words by stiffening of beam, the prop collected all damages due to cyclic loading at itself and acted as the first line of defense and prevented from sever damages at RC joint.

Design by Topology Optimization and Performance Test of Ultrasonic Bonding Module for Flip-Chip Packaging (초음파 플립칩 접합 모듈의 위상최적화 설계 및 성능 실험)

  • Kim, Ji Soo;Kim, Jong Min;Lee, Soo Il
    • Journal of Welding and Joining
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    • v.30 no.6
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    • pp.113-119
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    • 2012
  • Ultrasonic bonding is the novel packaging method for flip-chip with high yield and low-temperature bonding. The bonding module is a core part of the bonding machine, which can transfer the ultrasonic energy into the bonding spot. In this paper, we propose topology optimization technique which can make new design of boding modules due to the constraints on resonance frequency and mode shapes. The designed bonding module using topology optimization was fabricated in order to evaluate the bonding performance and reliable operation during the continuous bonding process. The actual production models based on the proposed design satisfied the target frequency range and ultrasonic power. The bonding test was performed using flip-chip with lead-free Sn-based bumps, the results confirmed that the bonding strength was sufficient with the designed bonding modules. Also the performance degradation of the bonding module was not observed after the 300-hour continuous process with bonding conditions.

Evaluation of corrosion resistance by electrochemical method for Ni-Cr-Mo-V steel (Ni-Cr-Mo-V강의 전기화학적 방법에 의한 내식성 평가)

  • Kwon, Jae-Do;Moon, Yun-Bae
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.21 no.9
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    • pp.1422-1431
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    • 1997
  • When the structures are exposed to their own an application for a long period, a number of variables such as strength properties and corrosion resistance, so on are expected to change. In the present investigation the corrosion behavior and resistance for the original and degraded materials of Ni-Cr-Mo-V steel were evaluated under the conditions of pH 3, 6, 9 and 12 in a distilled water environment. The electrochemical polarization technique was employed in this investigation. Based upon the experimental results obtained, the following conclusions were drawn. A severe and uniform corrosion was observed for both original and degraded materials under the condition of pH 3. At pH 6 and pH 9, these materials showed the degradation by a pitting corrosion. The materials under pH 12 environment were degraded by a uniform corrosion. The corrosion rate per year were the highest in the pH 3 environment, followed by pH 12, pH 6 and pH 9 environment in order. The corrosion resistance was decreased from the original material, slow cooled material (10.deg. C/hr) and step cooled material in order.

Weathering and Degradation Assessment of Rock Properties at the West Stone Pagoda, Gameunsaji Temple Site, Korea

  • Lee, Chan Hee;Lee, Myeong Seong;Kim, Jiyoung
    • Conservation and Restoration of Cultural Heritage
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    • v.1 no.1
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    • pp.29-37
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    • 2012
  • The West Stone Pagoda at Gameunsaji Temple Site constructed in the 7th century is mainly composed of dark grey dacitic tuff bearing small numerous dioritic xenoliths. These xenoliths resulted in small holes due to differential weathering process from the host rocks. Physical strength of the pagoda was decreased due to weathering and damage caused by petrological, biological and coastal environmental factors. The southeastern part of the pagoda was extremely deteriorated that the rock surface showed exfoliation, fracture, open cavity, granular decomposition of minerals and salt crystallization by seawater spray from the eastern coast. The stone blocks were intersected by numerous cracks and contaminated by subsequent material such as cement mortar and iron plates. Also, the pagoda was colonized by algae, fungi, lichen and bryophytes on the roof rock surface and the gaps between the blocks. As a result of ultrasonic test, the rock materials fell under Highly Weathered Grade (HW) or Completely Weathered Grade (CW). Thus, conservational intervention is essentially required to prevent further weakening of the rock materials.

Resonant Wavelength Characteristics of Arc-Induced Long-Period Fiber Gratings (아크 유도 장주기 광섬유 격자의 공진 파장 특성)

  • Chung, Chul;Lee, Ho-Joon
    • Journal of the Institute of Electronics Engineers of Korea SD
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    • v.39 no.10
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    • pp.48-56
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    • 2002
  • A fabrication method of long--period fiber gratings (LPFGs) that can be easily controlled resonance wavelength and losses is introduced. We used the superposition method that core and cladding diameter are modulated by applying a number of small electric-arc to the normal fiber. We derived an equation of resonance wavelength change according to core diameter variation using the phase matching condition and showed the results are well matched with experiments. The measured resonant wavelengths of arc-induced superposition LPFGs according to grating period are well coincident with that of phase matching condition. The resonance wavelength is measured for the temperature changes and a slight mechanical strength degradation of arc-induced LPFGs is observed by increasing arc times.

Modification of EPDM Rubbers for Enhancement of Environmental Durability of Aerator Membrane (산기관용 멤브레인 고무판의 환경내구성 향상을 위한 EPDM 고무의 개질)

  • Ahn, Won-Sool
    • Journal of Environmental Science International
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    • v.17 no.1
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    • pp.107-112
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    • 2008
  • A study on the enhancement of environmental durability of EPDM rubber materials for the aerator membrane was performed using a butyl rubber as a modifier. A conventional EPDM rubber formulation was evaluated as having about 26.0 wt% or more oil content from the chloroform immersion test. These oils would be gradually and continuously deleted from the aerator membrane when directly exposed to a waste-water or chemically corrosive fluids, making the membrane less flexible and the performance worse. To improve this, a butyl rubber (IIR) was utilized as the modifier for a low-ENB type of EPDM rubber formulation with low-oil content. The environmental durability of the IIR-modified EPDM rubber material was expected to be greatly enhanced compared to the conventional one. However, the mechanical and performance properties such as elongation, tensile strength, and air bubble size, etc. were still maintained as good as in the conventional one. Furthermore, TGA analysis of the IIR-modified EPDM material showed that there would be partially compatible between IIR and EPDM. It also showed that the initial degradation temperature of the IIR-modified EPDM could be somewhat increased, exhibiting the enhanced compatibility among the components and, thereby, more enhanced environmental durability.

Moment Magnifier Method for Long-Term Behavior of Flat Plate Subjected to In-Plane Compressive and Transverse Loads (바닥하중과 압축력을 받는 플랫 플레이트의 장기거동을 고려한 모멘트 증대법)

  • 최경규;박홍근
    • Journal of the Korea Concrete Institute
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    • v.13 no.1
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    • pp.38-45
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    • 2001
  • Numerical studies were carried out to develop the moment magnifier method for long-term behavior of flat plates, subjected to combined in-plane compressive and transverse loads. Nonlinear finite element analyses were performed for the numerical studies. Through the numerical studies, the long term behavior of the flat plate subjected to uniform or nonuniform floor load was investigated, and creep effects on the degradation of strength and stiffness of the slabs were examined. As a result, the creep factor was implemented to describe the creep effect on the flat plate. The moment magnifier method using the creep factor was developed for long-term behavior of flat plates. Also, the design examples were shown for the verification of the proposed design method.

Mechanical Properties of the Ceramics of the System Al2O3-ZrO2-Y2O3 Prepared by the Precipitation Method (침전법에 의한 Al2O3-ZrO2-Y2O3계 세라믹스의 기계적 특성)

  • 김준태;이홍림
    • Journal of the Korean Ceramic Society
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    • v.25 no.4
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    • pp.364-372
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    • 1988
  • The mechanical properties and microstructure of ceramics of the system Al2O3-ZrO2-Y2O3 sintered at 1$650^{\circ}C$ for 2h after powder preparation by the precipitation method from Al2(SO4)3.18H2O, ZrOCl2.8H2O and YCl3.6H2O were investigated. The Al2O3-ZrO2-Y2O3 ceramics sintered at 1$650^{\circ}C$ for 2h after mixing alpha-Al2O3 and ZrO2-Y2O3 powders, both were separately precipitated and calcined, were found to have the relative density higher than 97.5% so that the strengthening and toughening mechanisms could be explained mainly as the stress-induced phase transformation. On the other hand, the sintered bodies prepared by co-precipitating the three starting materials were measured to have the relative density lower than 85% so that the degradation of strength were observed above 15 vol% ZrO2 contents due to the high porosity by which the effect of stress-induced phase transformation was assumed to be depressed.

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An Experimental Study on the Properties of Ultra Rapid Hardening Mortar Using Magnesia-Phosphate Cement (마그네시아 인산염 시멘트를 사용한 보수용 초속경 모르타르의 특성에 관한 실험적 연구)

  • Ahn, Moo-Young;Jung, Sang-Jin
    • Journal of the Korea Institute of Building Construction
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    • v.7 no.4
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    • pp.109-116
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    • 2007
  • Building structures are generally large in size and have a long life, and the construction of such structures requires the investment of a huge amount of money and social infrastructure. Furthermore, building structures are closely related to people's life. Recently, however, the rapid development of society has been worsening air pollution, which is in turn accelerating the degradation of building structures. Thus, the safety of building structure is emerging as a critical issue. To cope with this problem, the government enacted "The Special Act on Safety Control for Infrastructure" but we need engineers' higher concern over the maintenance and reinforcement of existing structures. Recently researches are being made actively on repair mortar using ultra rapid hardening cement for recovering the performance of structures. The present study conducted an experiment on the basic physical properties of ultra rapid hardening mortar for repairing and reinforcing building structures using magnesia cement and mono-ammonium phosphate. In the experiment, we changed the water-cement ratio and carried out replacement at different ratio of MAP/MgO(%). We used retarder to have working life, and made comparative analysis through evaluating working life and fluidity and measuring strength by age.