• 한국연소학회:학술대회논문집
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• 2001.11a
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• pp.17-26
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• 2001

Self flue gas recirculation flow is an effective method for low NOx emission in the regenerative low NOx burner. The object of this study is to analyze the self flue gas recirculating flow by varying jet velocity of the combustion air. Fuel and air flow rates are fixed and combustion air jet nozzle diameters are 13, 6.5 and 5mm. The stoichiometric line is obtained from the concentration of the fuel using an acetone PLIF technique. It is found that the self flue gas recirculating flow is entrained into that line using a two color PIV technique. As the jet velocity of combustion air is increased, the flue gas entrainment rate into the stoichiometric line is increased. This result suggests that NOx emission can be reduced due to the effects of flue gas which is lowering the flame temperatures.

• Proceedings of the KIEE Conference
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• 1989.07a
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• pp.329-332
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• 1989

Lead titanate thin films were deposited on titanium substrates by a chemical vapour deposition(CVD) process involving the application of vapour mixtures of Pb, ethyl titanate( Ti($C_2H_5O_4$)), and oxygen. The lead titanate having a stoichiometric composition has a dc conductivity of $3.2{\times}10^{-12}{\Omega}^{-1}{\cdot}cm^{-1}$ at room temperature. The nonsaturating loops observed in present investigation may be attributed to the $TiO_2$ and TiO layers between the conductive substrate and the $PbTiO_3$ ferroelectric film. The ferroelectric properties of the stoichiometric $PbTiO_3$ film included a remanent polarization of 14.1 ${\mu}C/cm^2$ and a coercive field of 20.16 kV/cm.

• Journal of Advanced Marine Engineering and Technology
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• v.29 no.6
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• pp.645-653
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• 2005

The effects of a WI(Water Injection) at the intake Pipe and an urea injection at the exhaust pipe for a 4-cylinder DI(Direct Injection) diesel engine were investigated experimentally The water quantity was controlled by temperature of intake manifold and MAF(Manifold Air Flow). In addition, the urea quantify was controlled by NOx quantify and MAF. Effects of WI system, urea-SCR system and tandem system were investigated for with and without EGR(Exhaust Gas Recirculation). As the results. the SUF(Stoichiometric Urea Flow) and NOx map were obtained. In addition, NOx results can be visualized with engine speed and engine load. It was concluded. therefore, that the NOx reduction effects of the tandem system without the EGR were more than those with the EGR base engine.

• Proceedings of the Korean Environmental Sciences Society Conference
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• 2003.11a
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• pp.208-211
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• 2003

Characteristics of biosorption of lead by marine algae, Laminaria japonica, were examined. The biosorption capacity of lead by L. japonica was achieved up to 30％ of its own weight and proportional to the initial lead concentration. However, the opposite result was shown in different initial weight of biomass. Ion exchange reaction between lead ions and calcium ions was observed on lead biosorption with Ca-Ioaded biomass. Stoichiometric coefficient, which can represent the exchange ratio between metal ions and protons during elution process, was determined as 1.39. Therefore, it was concluded that the reaction between lead ions already attached in biomass and protons in bulk solution was not fully stoichiometric ion exchange relation at elution process.

• Journal of Hydrogen and New Energy
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• v.15 no.3
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• pp.175-186
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• 2004

In this paper, we developed the dynamic model of a fuel cell system suitable for controller design and system operation. The transient phenomena captured in the model include the flow characteristics and inertia dynamics of the compressor, the intake manifold filling dynamics, oxygen partial pressures and membrane humidity on the fuel cell voltage. In the simulations, we paid attention to the transient behavior of stack voltage and compressor pressure, stoichiometric ratio. Simulation results are presented to demonstrate the model capability. For load current following, stack voltage dynamic characteristics are plotted to understand the Electro-chemistry involved with the fuel cell system. Compressor pressure and stoichiometric ratio are strongly coupled, and independent parameters may interfere with each other, dynamic response, undershoot and overshoot.

• Journal of the Korean Institute of Gas
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• v.15 no.4
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• pp.44-50
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• 2011

Explosion limit is one of the major combustion properties used to determine the fire and explosion hazards of the flammable substances. In this study, the lower explosion limit(LEL) and upper explosion limit(UEL) of ethers were predicted by using the heat of combustion and stoichiometric coefficients. The values calculated by the proposed equations agreed with literature data within a few percent. From the given results, using the proposed methodology, it is possible to predict the explosion limits of the other flammable ethers.

• Proceedings of the KSME Conference
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• 2000.04b
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• pp.422-427
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• 2000

Propagation characteristics of tribrachial flames have been investigated experimentally in both two-dimensional and axisymmetric counterflows. Mixture fraction gradient at stoichiometric location is controlled by varying equivalence ratios at the two nozzles, one of which maintains rich while the other lean premixture. Tribrachial flames propagating through these mixtures are investigated. The propagation speed of tribrachial flames in two-dimensional counterflow decreases with fuel concentration gradient and has much higher speed than the maximum speed predicted previously in two-dimensional mixing layers. From an analogy with premixed flame propagation, this excessively large propagation speed can be attributed to the tribrachial flame propagating with respect to burnt gas. Corresponding maximum speed in the limit of small mixture fraction gradient is estimated and extrapolated experimental results substantiate this limiting speed. As mixture fraction gradient approaches zero, a transition in propagation characteristics occurs, such that the propagation speed of tribrachial flame approaches stoichiometric laminar burning velocity with respect to burnt gas. Similar behavior has been obtained for tribrachial flames propagating in axisymmetric counterflow.

• Journal of the korean Society of Automotive Engineers
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• v.8 no.4
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• pp.13-23
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• 1986

The power of an international combustion engine depends on its ability to inhale air whether it is naturally aspirated or turbocharged. The use of fuel injection allows engine efficiency to be increased through a more even distribution of the air/fuel ratio throughout the engine's operation range. The theoretical value for complete combustion in an engine is commonly refered to as stoichiometric, which means that we require 14.7 parts of air to 1 part of gasoline. This stoichiometric ratio can be more closely maintained with electronically controlled fuel injection than it can with carburetion. Because of the greater efficiency of the engine using fuel injection, a horse power increase of at least 10% is produced over its carburetor version. In addition, better fuel economy and less exhaust emissions are also obtained.

• Transactions of the Korean Society of Automotive Engineers
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• v.13 no.5
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• pp.57-63
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• 2005

The effects of an urea injection at the exhaust pipe for a 4-cylinder DI(Direct Injection) diesel engine were investigated with the parameters such as urea-SCR(Selective Catalytic Reduction) and EGR system. The urea quantity was controlled by NOx quantity and MAF(Manifold Air Flow). The urea injection quantity can be controlled with the urea syringe pump, precisely. The effects of NOx reduction for the urea-SCR system were investigated with and without ECR engine, respectively. It was concluded that the SUF(Stoichiometric Urea Flow) is calculated and the NOx results are visualized with engine speed and load. Furthermore, the NOx map is made from this experimental results. It was suggested, therefore, that NOx reduction effects of the urea-SCR system without the EGR engine were better than that with the EGR engine except of low load and low speed.

• Carbon letters
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• v.4 no.4
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• pp.175-179
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• 2003

It is well established that halogenated fullerene derivatives act as synthetic intermediates for further substitution via replacement with nucleophlies. In the present work, systematic studies were carried out on the synthesis of bromofullerenes under different experimental conditions. The effect of reaction time on the product formed was observed. We observed the formation of new compound of bromofullerenes in a different stoichiometric ratio i.e., $C_{60}Br_{14}$; in addition to previous reported bromofullerenes in the stoichiometric ratio of $C_{60}Br_6$, $C_{60}Br_8$, and $C_{60}Br_{24}$. The new derivative of bromofullerene was isolated and well characterized by various analytical techniques like FT-IR, TGA, DSC, and elemental analysis. In this paper, detail of the synthesis and characterization of the bromofullerene prepared are described. The yields obtained were better than those reported previously.