• Applied Chemistry for Engineering
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• v.33 no.4
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• pp.402-407
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• 2022

Statistical design of experiments was used to optimize the MOF-5 synthesis process. A mixture design was employed to optimize precursor concentration. The optimal composition of three chemical materials, terephthalic acid, zinc acetate dihydrate, and N,N-dimethylformamide for MOF-5 synthesis was determined by extreme vertices design methods as follows; 1 mol : 2.7 mol : 40 mol. A multilevel factorial design was selected to screen the significance of synthesis reaction conditions such as temperature, time, and stirring speed. Statistical analysis results suggested excluding stirring speed from further investigation. Using a central composition design, the synthesis time and temperature were optimized. The quadratic model equation was derived from 13 synthesis experiments. The model predicted that MOF-5 synthesized at 119 ℃ for 10.4 h had the highest crystallinity.

• Resources Recycling
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• v.32 no.6
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• pp.18-24
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• 2023

This study undertook initial investigations into the carbonation of chlorine bypass dust, aiming to apply it as a raw material for cement and as an admixture for concrete. Various experimental methods, including XRD(X-ray diffraction), XRF(X-ray fluorescence), and particle size distribution analyses, were employed to verify the physical and chemical properties of chlorine bypass dust, with and without water washing. The mineral carbonation extent of chlorine bypass dust was examined by considering the dust type, stirring temperature, and experiment duration. Notably, a higher degree of mineral carbonation was observed in water-washed bypass dust than its non-water-washed counterpart, indicating an elevated calcium content in the former. Furthermore, an augmented stirring temperature positively impacted the initial stages of mineral carbonation. However, divergent outcomes were observed over time, contingent upon the specific characteristics of dust types under consideration.

• Korean Journal of Materials Research
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• v.34 no.7
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• pp.341-354
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• 2024

Today, the principles of green chemistry are being fundamentally applied in the chemical industry, such as the nitrobenzene industry, which is an essential intermediate for various commercial products. Research on the application of response surface methodology (RSM) to optimize nitrobenzene synthesis was conducted using a sulfated silica (SO₄/SiO₂) catalyst and batch microwave reactor. The nitrobenzene synthesis process was carried out according to RSM using a central composite design (CCD) design for three independent variables, consisting of sulfuric acid concentration on the silica (%), stirring time (min), and reaction temperature (℃), and the response variable of nitrobenzene yield (%). The results showed that a three-factorial design using the response surface method could determine the optimum conditions for obtaining nitrobenzene products in a batch microwave reactor. The optimum condition for a nitrobenzene yield of 63.38 % can be obtained at a sulfuric acid concentration on the silica of 91.20 %, stirring time of 140.45 min, and reaction temperature of 58.14 ℃. From the 20 experiments conducted, the SO₄/SiO₂ catalyst showed a selectivity of 100 %, which means that this solid acid catalyst can potentially work well in converting benzene to nitrobenzene.

• Journal of the East Asian Society of Dietary Life
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• v.13 no.6
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• pp.586-592
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• 2003

This research used High Performance Liquid Chromatography(HPLC) to analyze and compare the content and the pattern of chlorophyll to find the difference in quality, water temperature, and the stirring time between the three different types of Korean and Japanese powder green tea, which were currently on the market. Chlorophyll contents of Japanese-made medium quality tea (S5: 8.34mg/g), and low quality tea (S6: 8.23mg/g) were relatively high, and that of Korean-made medium quality tea (S2 ; 4.87mg/g) was lower. The water temperature of 85$^{\circ}C$ and 95$^{\circ}C$ were high except in Korean-made medium and low quality powder green tea (S2 and S3). Japanese-made powder tea required 60 seconds of stirring time and Korean-made tea required 15 seconds, but 30 seconds seem to be the ideal stirring time for both of them. Chlorophyll a, b, pheophytin a, b, and pheophorbide were confirmed from the chlorophyll pattern. There were 1.5∼2 times more of chlorophyll a in Japanese-made one compared to that of Korean-made one; also 1.5∼2 times more of pheophytin a in Korean-made one than Japanese-made one. It might be concluded that Japanese-made powder green tea was higher in quality.

• Microbiology and Biotechnology Letters
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• v.23 no.6
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• pp.763-769
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• 1995

As a mean to recover photosynthetic bacterial(PSB) cells and its practical uses in food industrial wastewater treatment, various biodegradable polyelectrolytes were first investigated for flocculation of suspended colloids in the PSB treatment process of soybean curd wastewater. Anionic polyelectrolytes such as sodium alginate and carrageenan were not effective but a cationic polyelectrolyte chitosan isolated from Portunus trituberclatus showed very effective flocculation activity. The concentration of chitosan, pH and temperature of wastewater for maximal flocculation were 40 mg/l, pH 7 and room temperature, respectively. Test using deacetylated chitosan to various degree showed higher flocculating activities in samples deacetylated over 75% and time for maximum flocculation was 40 min by stirring slowly under the above optimal conditions. Chitosan was not only effective to flocculate cells but also removed COD and MLSS of the wastewater. COD of 42% and MLSS of 87% were removed by addition of chitosan to the soybean curd wastewater treated with PSB.

• Journal of Korea Foundry Society
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• v.32 no.4
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• pp.181-189
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• 2012

The microstructures of self-designed 7000 series Aluminium alloys added with Sc are observed. Moreover, the mechanical properties of the Sc-added Aluminium alloys are evaluated as a function of tensile temperature to establish the conditions of a following extrusion process. New casting conditions in the aluminium alloys added with Sc could be established by changing the casting speed and stirring time in the existing casting conditions of Aluminium alloys. The Sc addition results in $Al_3(Sc,Zr)$ precipitates in the cast alloys, and leads to the formation of equal-axed grains and fine grains. After homogenization heat treatment at $450^{\circ}C$, the Sc-added Aluminium alloys showed the highest elongation values in the temperature ranging from $300{\sim}400^{\circ}C$.

• Journal of Industrial Technology
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• v.21 no.A
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• pp.251-256
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• 2001

This research is focused on an improvement of additional value of high grade limestone. To obtain the basic data of precipitated calcium carbonate(PCC), studies of physical properties of limestone, calcination and hydration characteristics, the characteristics to manufacture quick lime, hydrated lime, ground calcium carbonate and precipitated calcium carbonate were performed. In the carbonation process, formation of rombohedral must be kept under $10^{\circ}C$ for reaction. Although the temperature of reaction of lime milk was limited under $30^{\circ}C$ for a colloidal PCC manufacture, over $50^{\circ}C$ for spindle type PCC. The recommended reaction conditions for colloidal PCC are $20^{\circ}C$ of reaction temperature, 4% of $Ca(OH)_2$ concentration, 1000rpm of stirring rate and 200ml/min of $CO_2$ gas flow rate.

• Journal of Environmental Health Sciences
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• v.28 no.2
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• pp.141-148
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• 2002

This study was performed to examine the effects of rice straw as bulking materials on temperature, pH, weight and volume reduction, porosity, C/N ratio, salinity, and conductivity in aerobic composting of food wastes. Volume ratios of food wastes to rice straw in reactor control, RS-1, RS-2, RS-2 and RS-4 were 4:0, 4:1. 4:2. 4:3 and 4:4, respectively. Reactors were operated for 24days with 1 hour stirring by lrpm and 2hours aeration per day. The values of pH of food wastes and rice straw were 4.39 and 7.4, respectively. The lowering of the volume ratio of food wastes to rice straw resulted in the high reaction temperature and the fast weight and volume reduction rates. C/N ratio in control was larger than that in rice straw containing reactors. Salinity and conductivity in reactors were condensed and increased by reaction days.

• Proceedings of the Korean Society for Technology of Plasticity Conference
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• 1997.06a
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• pp.16-27
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• 1997

A semi-solid forming has a lot of advantages compared to the die casting, squeeze costing and convenctional forging, therefore, semi-solid forming process are now becoming of industial interest for the production of metal components and metal matrix composites. However, the material behaviour in the semi-solid temperature range is not sufficiently known although it controls the whole process through forces and geometry evolutions bcause the behaviour of metal slurries is complex. The semi-solid materials(SSM) fabricated under electric-magnetic stirring condition is necessary to be applicate in forming process. A reheating conditions were studied with the reheating time, holing time and reheating temperatures. The microstructure of SSM (which specimen size:d 40${\times}$i60) on condition of heating time 10min and heating temperature 590$^{\circ}C$ is most globular and finest one. The microstructure of SSM(specimen size:d75${\times}$i60) reheated under the three step reheating conditions is most globular and finest.

• Particle and aerosol research
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• v.11 no.3
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• pp.77-85
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• 2015

A Belousov-Zhabotinsky reaction in a liquid-liquid system under microwave radiation was observed under non-stirring conditions. To control this non-equilibrium reaction, nano-particle, which is active under microwave irradiation, was added to the solution. Color changes of the solution during the oscillatory reaction were found to be influenced by the irradiation power although the droplet temperature was equal to the temperature of surrounding oil. During the irradiation, the period of oscillation became shorter because the reaction rate was faster. It could also be observed that there is possibility to eliminate oscillatory behaviors of the reaction using higher power of microwave. The possibility of controlling non-linear reaction using microwave was shown since microwave can easily travel through oil phase and reach water phase.