• Archives of Pharmacal Research
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• v.5 no.2
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• pp.109-110
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• 1982

Conveersion of vinylogous glycidic ester 1 to 2 by a stereoselective acyclic allylic epoxidation will be presented.

• Bulletin of the Korean Chemical Society
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• v.23 no.9
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• pp.1185-1186
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• 2002

• Archives of Pharmacal Research
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• v.15 no.4
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• pp.374-375
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• 1992

The marine sterol (22R, 23R)-methylenecholesterol 1 has been synthesized from readily available C-22 steroidal ester 2 utilizing an intermolecular acyclic ester enolate alkylation as the key step.

• Bulletin of the Korean Chemical Society
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• v.26 no.11
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• pp.1677-1681
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• 2005

Aldol condensation of 2-acetylthiophene, 2-acetylpyrrole and 2-acetylpyridine with different aromatic aldehydes were carried out in water in heterogeneous phases in the presence of cetyltrimethylammonium bromide as cationic surfactant at room temperature. All the reactions occur in a short time with excellent yields of steroselective hetarylpropanones in water as environmental friendly solvent.

• Bulletin of the Korean Chemical Society
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• v.30 no.11
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• pp.2608-2612
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• 2009

The unequivocal solid-state structure and stereochemistry of the hetaryl leuco-TAM dye, 2,2’-(2-phenyl propane- 1,3-diylidene) bis(1,3,3- trimethylindoline) derivatives were established using X-ray single crystal analysis. The X-ray crystal analysis showed that the (Z, E)-isomers only formed stereoselectively, with a so-called “threebladed propeller” conformation, from the reaction of a Fischer base and benzaldehyde derivatives. These isomers were stacked in a juxtaposition to form a dimer or a double dimer, adopting either a triclinic, with P-1, or monoclinic crystal system with a space group P21/n in the unit cell of the crystal.