• Title/Summary/Keyword: Steel-surface layer

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A Study on the Characteristics of Electro Polishing and Utility Materials for Transit High Purity Gas (청정도 가스 이송용 재료의 특성과 전해연마에 관한 연구)

  • Lee, Jong-Hyung;Park, Shin-Kyu;Yang, Seong-Hyeon
    • Journal of the Korean Society of Industry Convergence
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    • v.7 no.3
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    • pp.259-263
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    • 2004
  • In the manufacture progress of LCD or semiconductor, there are used many kinds of gas like erosion gas, dilution gas, toxic gas as a progress which used these gas there are required high puritize to increase accumulation rate of semiconductor or LCD materials work progress of semiconductor or LCD it demand many things like the material which could minimize metallic dust that could be occured by reaction between gas and transfer pipe laying material, illumination of the surface, emition of the gas, metal liquation, welding etc also demand quality geting stricted. Material-Low-sulfur-contend (0.007-0010), vacuum-arc-remelt(VAR), seamless, high-purity tubing material is recommend for enhance welding lower surface defect density All wetted stainless steel surface must be 316LSS elecrto polishinged with ${\leq}0.254{\mu}m$($10.0{\mu}in$) Ra average surface finish, $Cr/Fe{\geq}1.1$ and $Cr_2O_3$ thickness ${\geq}25{\AA}$ From the AES analytical the oxide layer thickness (23.5~36 angstroms silicon dioxide equivalent) and chromum to iron ratios is similar to those generally found on electropolished stainless steel., molybdenum and silicon contaminants ; elements characteristic of stainless steel (iron, nickel and chromium); and oxygen were found on the surface Phosphorus and nitrogen are common contaminants from the electropolish and passivation steps.

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Effects of Proton Irradiation on the Microstructure and Surface Oxidation Characteristics of Type 316 Stainless Steel (양성자 조사가 316 스테인리스강의 미세조직과 표면산화 특성에 미치는 영향)

  • Lim, Yun-Soo;Kim, Dong-Jin;Hwang, Seong Sik;Choi, Min Jae;Cho, Sung Whan
    • Corrosion Science and Technology
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    • v.20 no.3
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    • pp.158-168
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    • 2021
  • Austenitic 316 stainless steel was irradiated with protons accelerated by an energy of 2 MeV at 360 ℃, the various defects induced by this proton irradiation were characterized with microscopic equipment. In our observations irradiation defects such as dislocations and micro-voids were clearly revealed. The typical irradiation defects observed differed according to depth, indicating the evolution of irradiation defects follows the characteristics of radiation damage profiles that depend on depth. Surface oxidation tests were conducted under the simulated primary water conditions of a pressurized water reactor (PWR) to understand the role irradiation defects play in surface oxidation behavior and also to investigate the resultant irradiation assisted stress corrosion cracking (IASCC) susceptibility that occurs after exposure to PWR primary water. We found that Cr and Fe became depleted while Ni was enriched at the grain boundary beneath the surface oxidation layer both in the non-irradiated and proton-irradiated specimens. However, the degree of Cr/Fe depletion and Ni enrichment was much higher in the proton-irradiated sample than in the non-irradiated one owing to radiation-induced segregation and the irradiation defects. The microstructural and microchemical changes induced by proton irradiation all appear to significantly increase the susceptibility of austenitic 316 stainless steel to IASCC.

Development of Conductive-Corrosion Resistive Stainless Steel for PEMFC Bipolar plate (고분자전해질 연료전지용 스테인리스 분리판 고내식/고전도성 표면개질 기술 개발)

  • Han, Jun-Hui;Jeong, Yeon-Su;Jeon, Yu-Taek
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2014.11a
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    • pp.278-278
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    • 2014
  • 저가형 고전도성/고내식 연료전지용 금속분리판 제작을 위해 다양한 조성 및 온도에서 표면개질을 시행하였다. 본 연구에 의해 제작된 시편의 표면분석 결과 Fe 선택적 용출 및 Cr-rich layer 형성이 이루어졌음을 확인하였으며, 성능 평가 결과 2015 DOE 목표를 만족시키는 것을 확인하였다.

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Innovative Development of Al-Zn-Si Coated Sheet Steels for Automotive Applications

  • Jong-Sang Kim;Suk-Kyu Lee;Doo-Jin Paik
    • Corrosion Science and Technology
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    • v.23 no.4
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    • pp.296-301
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    • 2024
  • Steels have excellent mechanical properties and weldability. They are also economically producible. Thus, they are widely applied in various industries. However, they have a disadvantage in that rust can occur after a certain period of time. To compensate for this, Zn, which has excellent sacrificial corrosion resistance, can be coated on steels. With global zinc consumption increasing at the current rate, depletion is expected in the near future. Recently, POSCO has developed innovative Al-Zn-Si alloy coated steel sheets with better corrosion resistance than Zn coating. In this study, corrosion resistance, weldability, friction characteristics, and so on were evaluated compared to GI steel sheets to evaluate their applicability to automotive steel sheets. It showed excellent corrosion resistance even at a lower coating weight compared to GI steel sheet. It was also excellent in terms of galling and welding LME. Its spot welding life, electrodeposition coating, and bendability were equally excellent. This is presumed to be related to the formation of the Al-Zn-Si alloy phase at the interface of the coating layer.

Development of Continuous Galvanization-compatible Martensitic Steel

  • Gong, Y.F.;Song, T.J.;Kim, Han S.;Kwak, J.H.;De Cooman, B.C.
    • Corrosion Science and Technology
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    • v.11 no.1
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    • pp.1-8
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    • 2012
  • The development of martensitic grades which can be processed in continuous galvanizing lines requires the reduction of the oxides formed on the steel during the hot dip process. This reduction mechanism was investigated in detail by means of High Resolution Transmission Electron Microscopy (HR-TEM) of cross-sectional samples. Annealing of a martensitic steel in a 10% $H_2+N_2$ atmosphere with the dew point of $-35^{\circ}C$ resulted in the formation of a thin $_{C-X}MnO.SiO_{2}$ (x>1) oxide film and amorphous $_{a-X}MnO.SiO_{2}$ oxide particles on the surface. During the hot dip galvanizing in Zn-0.13%Al, the thin $_{C-X}MnO.SiO_{2}$ (x>1) oxide film was reduced by the Al. The $_{a-X}MnO.SiO_{2}$ (x<0.9) and $a-SiO_{2}$ oxides however remained embedded in the Zn coating close to the steel/coating interface. No $Fe_{2}Al_{5-X}Zn_{X}$ inhibition layer formation was observed. During hot dip galvanizing in Zn-0.20%Al, the $_{C-X}MnO.SiO_{2}$ (x>1) oxide film was also reduced and the amorphous $_{a-X}MnO.SiO_{2}$ and $a-SiO_{2}$ particles were embedded in the $Fe_{2}Al_{5-X}Zn_{X}$ inhibition layer formed at the steel/coating interface during hot dipping. The results clearly show that Al in the liquid Zn bath can reduce the crystalline $_{C-X}MnO.SiO_{2}$ (x>1) oxides but not the amorphous $_{a-X}MnO.SiO_{2}$ (x<0.9) and $a-SiO_{2}$ oxides. These oxides remain embedded in the Zn layer or in the inhibition layer, making it possible to apply a Zn or Zn-alloy coating on martensitic steel by hot dipping. The hot dipping process was also found to deteriorate the mechanical properties, independently of the Zn bath composition.

Experimental study and numerical investigation of behavior of RC beams strengthened with steel reinforced grout

  • Bencardino, Francesco;Condello, Antonio
    • Computers and Concrete
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    • v.14 no.6
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    • pp.711-725
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    • 2014
  • The purpose of this study is to evaluate the behavior and the strength of SRG (Steel Reinforced Grout) externally strengthened Reinforced Concrete (RC) beams by using a nonlinear numerical analysis. The numerical simulation was carried out by using a three-dimensional (3D) finite element model. An interface element with a suitable damage model was used to model the connection between concrete surface and SRG reinforcing layer. The reliability of the finite element 3D-model was checked using experimental data obtained on a set of three RC beams. The parameters taken into consideration were the external configuration, with or without U-end anchorages, the concrete strength, the amount of internal tensile steel reinforcement. Conclusions were made concerning the strength and the ductility of the strengthened beams by varying the parameters and on the effectiveness of the SRG reinforcing system applied with two types of external strengthening configuration.

Characteristics of Ni-based Alloy Bond in Diamond Tool Using Vacuum Brazing Method

  • An, Sang-Jae;Song, Min-Seok;Jee, Won-Ho
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09b
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    • pp.1130-1131
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    • 2006
  • We found that the """interface reaction between Ni-based alloy bond, diamond, and steel core is very critical in bond strength of diamond tool. None element from metal bond diffuses into the steel core but the Fe element of steel core was easily diffused into the bond. This diffusion depth of Fe has a great effect on the bonding strength. The Cr in steel core accelerated the Fe diffusion and improved the bond strength, on the other hand, carbon decreased the strength. Ni-based alloy bond including Cr was chemically bonded with diamond by forming Cr carbide. However, the Cr and Fe in STS304 were largely interdiffused, the strength was very low. The Cr passivity layer formed at surface of STS304 made worse strength at commissure in brazing process.

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Analysis of Sliding Wear Properties for Arc-melted Intermetallic Compounds of Ni3Al, NiAl and TiAl (Arc melting으로 제조한 금속간화합물 Ni3Al, NiAl 및 TiAl의 미끄럼 마모특성 해석)

  • Lee, Han-Young;Kim, Tae-Jun;Cho, Yong-Jae
    • Korean Journal of Metals and Materials
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    • v.47 no.5
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    • pp.267-273
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    • 2009
  • Three types of structural intermetallic compounds, $Ni_3Al$, NiAl and TiAl, having each single phase structure without pores were produced by arc-melting process. Their sliding wear properties were investigated against a hardened tool steel. It was shown that the wear of the intermetallic compounds was hardly occurred against the hardened tool steel. TiAl compound showed the best wear resistance among them. In this case, wear was preferentially occurred on the surface of the hardened tool steel of the mating material which has higher hardness. It could be found that the wear mode on intermetallics without pores by arc-melting process was different from that on its porous layer coated on steel by combustion synthesis.

Surface Fracture Response of Glass Eabric/Epoxy Lamina-Bonded Glass Plates to Impact with a Small-Diameter Steel Ball (직물형 유리섬유/에폭시 복합재료로 피막된 판유리의 미소강구 충격에 의한 표면파괴거동)

  • 김형구;최낙삼
    • Composites Research
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    • v.13 no.4
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    • pp.75-82
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    • 2000
  • A small diameter steel-ball impact experiment was performed to study the impact resistance of the surface of glass plates bonded with glass fabric/epoxy lamina. Five kinds of materials were used in this study: soda-lime glass plates, glass/epoxy lamina(one layer)-bonded and unbonded glass plates, glass/epoxy lamina(three layers)-bonded and unbonded glass plates. The range of impact velocity was 40 120m/s. The maximum stress and absorbed fracture energy were measured on the back surface of glass plates. With increasing impact velocity, various types of surface cracks such as ring, cone, radial and lateral cracks took place in the interior near the impacted site of glass plates. The cracks drastically decreased with glass/epoxy lamina coating. The surface fracture behavior could be evaluated using the maximum stress and the absorbed fracture energy.

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Study on Improvement of Surface Properties of Low Carbon Steel Using Laser Cladding

  • Cheol-Woo Kim;Hyo-Sang Yoo;Jae-Yeol Jeon;Kyun-Taek Cho;Se-Weon Choi
    • Archives of Metallurgy and Materials
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    • v.66 no.4
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    • pp.1033-1036
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    • 2021
  • Laser cladding is a method that can be applied to repair the crack and break on the mold and die surfaces, as well as generate new attributes on the surface to improve toughness, hardness, and corrosion resistance. It is used to extend the life of the mold. It also has the advantages of superior bonding strength and precision coating on a local area compared with the conventional thermal spraying technology. In this study, we investigated the effect of cladding on low carbon alloy steel using 18%Cr-2.5%Ni-Fe powder (Rockit404), which showed high hardness on the die surface. The process conditions were performed in an argon atmosphere using a diode laser source specialized for 900-1070 nm, and the output conditions were 5, 6, and 10 kW, respectively. After the cladding was completed, the surface coating layer's shape, the hardness according to the cross-section's thickness, and the microstructure were analyzed.