• Title/Summary/Keyword: Steel corrosion

Search Result 2,693, Processing Time 0.03 seconds

An Evaluation of Flexural Strength of Hollow Concrete Filled FRP Tube Piles (중공형 콘크리트 충전 FRP Tube 말뚝의 휨강도 산정)

  • Kim, Hyung-Joon;Chung, Heung-Jin
    • Journal of the Korea institute for structural maintenance and inspection
    • /
    • v.26 no.6
    • /
    • pp.204-211
    • /
    • 2022
  • In this study, Hollow Concrete Filled FRP Tube Pile(HCFFT Pile) was proposed as a model to utilize the advantages of composite piles and solve the problem of corrosion, which is a disadvantage of CFT piles, and a numerical analysis model was developed to analyze their behavior. The strain compatibility method was applied considering the damage plastic behavior of concrete, the yield plastic behavior of steel, and the elastic behavior of FRP. The flexural strength calculation equation of HCFFT piles was proposed considering the change of the FRP tube section according to the distance from the neutral axis. The flexural strength calculation equation, numerical analysis results, and experimental results were compared and analyzed to verify their adequacy. The results of this study can be used as basic data for the optimal design of various HCFFT piles using FRP.

Chromate Conversion Coating on 3D Printed Aluminum Alloys (3D 프린팅으로 제조한 알루미늄 합금의 크로메이트 코팅)

  • Shin, Hong-Shik;Kim, Hyo-Tae;Kim, Ki-Seung;Choi, Hye-Yoon
    • Journal of the Korean Society of Manufacturing Process Engineers
    • /
    • v.21 no.2
    • /
    • pp.109-115
    • /
    • 2022
  • The demand for metal 3D printing technology is increasing in various industries. The materials commonly used for metal 3D printing include aluminum alloys, titanium alloys, and stainless steel. In particular, for applications in the aviation and defense industry, aluminum alloy 3D printing parts are being produced. To improve the corrosion resistance in the 3D printed aluminum alloy outputs, a post-treatment process, such as chromate coating, should be applied. However, powdered materials, such as AlSi7Mg and AlSi10Mg, used for 3D printing, have a high silicon content; therefore, a suitable pretreatment is required for chromate coating. In the desmut step of the pretreatment process, the chromate coating can be formed only when a smut composed of silicon compounds or oxides is effectively removed. In this study, suitable desmut solutions for 3D printed AlSi7Mg and AlSi10Mg materials with high silicon contents were presented, and the chromate coating properties were studied accordingly. The smut removal effect was confirmed using an aqueous desmut solution composed of sulfuric, nitric, and hydrofluoric acids. Thus, a chromate coating was successfully formed. The surfaces of the aluminum alloys after desmut and chromate coating were analyzed using SEM and EDS.

Development of Chloride Penetration Analysis Program Considering Environmental Conditions (환경조건을 고려한 염소이온 침투해석 프로그램 개발)

  • Kim, Ki Hyun;Jang, Seung Yup;Cha, Soo Won;Chang, Sung Pil
    • KSCE Journal of Civil and Environmental Engineering Research
    • /
    • v.28 no.5A
    • /
    • pp.709-718
    • /
    • 2008
  • Developed is a chloride penetration analysis program in which changes of environmental conditions such as temperature, humidity and external chloride concentration, and the diffusion, convection and binding of chlorides are considered. In order to consider the changes of environmental conditions, analyses for temperature and moisture distribution are implemented simultaneously, and variation of diffusion coefficients due to temperature, humidity and age is also considered. By comparing the calculated total chloride contents with some experimental data, it has been confirmed that the proposed analysis program can trace measured chloride distribution well. Also, through some example analyses, the mechanism of accumulation of chlorides at near surface and acceleration of corrosion of steel reinforcement in case that the moisture distribution changes according to repeated drying and wetting cycles have been verified.

Temperature-dependent Diffusion Coefficient of Chloride Ion in UAE Concrete (UAE 콘크리트에 대한 염화물 확산의 온도의존성)

  • Ji-Won Hwang;Seung-Jun Kwon
    • Journal of the Korea institute for structural maintenance and inspection
    • /
    • v.28 no.4
    • /
    • pp.48-54
    • /
    • 2024
  • NPP (Nuclear power plant) structures have been constructed near to the sea shore line for cooling water and exposed to steel corrosion due to chloride attack. Regarding NPP structures built in the UAE, chloride transport may be more rapid than those in the other regions since the temperature near to the coast is high. In this study, concrete samples with 5,000psi (35MPa) design strength grade were manufactured with the materials and mix proportions, which were the same as used in the UAE NPP structures, then chloride diffusion coefficients were evaluated considering temperature and curing age. The compressive strength and the diffusion coefficient were evaluated and analyzed for the samples with 28 and 91 curing days. In addition, chloride diffusion tests for 91-day-cured condition were carried out in the range of 20℃ to 50℃. The activation energy was obtained through converting the temperature slope to a logarithmic function and it was compared with the previous studies. The proposed activation energy can be useful for a reasonable durability design by using actual temperature-dependent chloride diffusion coefficient.

A Study on Survey of Carbonation for Sound, Cracked, and Joint Concrete in RC Column in Metropolitan City (국내 도심지 콘크리트 교각 취약부의 탄산화 조사에 대한 연구)

  • Kwon, Seung Jun;Park, Sang Sun;Nam, Sang Hyuk;Cho, Ho Jin
    • Journal of the Korea institute for structural maintenance and inspection
    • /
    • v.11 no.3
    • /
    • pp.116-122
    • /
    • 2007
  • The concrete structures in Metropolitan city are usually exposed to carbonation and corrosion of embedded steel occurs due to the carbonation. In inspection and diagnosis of concrete structures, carbonation depth in sound concrete is mainly evaluated and service life for concrete structure is predicted based on the result. Generally, however, mass concrete structures such as columns have construction joint for suitable placing and also have cracks in early-age. In this study, carbonation depth in RC columns used for 20 years in metropolitan city is evaluated and also analyzed by considering the local conditions like sound, cracked, and joint area. The carbonation depth in cracked and joint area is more rapid than that in sound area, and it is thought to be more desirable to consider this effect in concrete structures with small cover depth. Furthermore, the technique for carbonation prediction in cracked concrete is derived in terms of crack width and the results from this technique are verified by comparing those from previous research.

Stellite bearings for liquid Zn-/Al-Systems with advanced chemical and physical properties by Mechanical Alloying and Standard-PM-Route

  • Zoz, H.;Benz, H.U.;Huettebraeucker, K.;Furken, L.;Ren, H.;Reichardt, R.
    • Proceedings of the Korean Powder Metallurgy Institute Conference
    • /
    • 2000.04a
    • /
    • pp.9-10
    • /
    • 2000
  • An important business-field of world-wide steel-industry is the coating of thin metal-sheets with zinc, zinc-aluminum and aluminum based materials. These products mostly go into automotive industry. in particular for the car-body. into building and construction industry as well as household appliances. Due to mass-production, the processing is done in large continuously operating plants where the mostly cold-rolled metal-strip as the substrate is handled in coils up to 40 tons unwind before and rolled up again after passing the processing plant which includes cleaning, annealing, hot-dip galvanizing / aluminizing and chemical treatment. In the liquid Zn, Zn-AI, AI-Zn and AI-Si bathes a combined action of corrosion and wear under high temperature and high stress onto the transfer components (rolls) accounts for major economic losses. Most critical here are the bearing systems of these rolls operating in the liquid system. Rolls in liquid system can not be avoided as they are needed to transfer the steel-strip into and out of the crucible. Since several years, ceramic roller bearings are tested here [1.2], however, in particular due to uncontrollable Slag-impurities within the hot bath [3], slide bearings are still expected to be of a higher potential [4]. The today's state of the art is the application of slide bearings based on Stellite\ulcorneragainst Stellite which is in general a 50-60 wt% Co-matrix with incorporated Cr- and W-carbides and other composites. Indeed Stellite is used as the bearing-material as of it's chemical properties (does not go into solution), the physical properties in particular with poor lubricating properties are not satisfying at all. To increase the Sliding behavior in the bearing system, about 0.15-0.2 wt% of lead has been added into the hot-bath in the past. Due to environmental regulations. this had to be reduced dramatically_ This together with the heavily increasing production rates expressed by increased velocity of the substrate-steel-band up to 200 m/min and increased tractate power up to 10 tons in modern plants. leads to life times of the bearings of a few up to several days only. To improve this situation. the Mechanical Alloying (MA) TeChnique [5.6.7.8] is used to prOduce advanced Stellite-based bearing materials. A lubricating phase is introduced into Stellite-powder-material by MA, the composite-powder-particles are coated by High Energy Milling (HEM) in order to produce bearing-bushes of approximately 12 kg by Sintering, Liquid Phase Sintering (LPS) and Hot Isostatic Pressing (HIP). The chemical and physical behavior of samples as well as the bearing systems in the hot galvanizing / aluminizing plant are discussed. DependenCies like lubricant material and composite, LPS-binder and composite, particle shape and PM-route with respect to achievable density. (temperature--) shock-reSistibility and corrosive-wear behavior will be described. The materials are characterized by particle size analysis (laser diffraction), scanning electron microscopy and X-ray diffraction. corrosive-wear behavior is determined using a special cylinder-in-bush apparatus (CIBA) as well as field-test in real production condition. Part I of this work describes the initial testing phase where different sample materials are produced, characterized, consolidated and tested in the CIBA under a common AI-Zn-system. The results are discussed and the material-system for the large components to be produced for the field test in real production condition is decided. Outlook: Part II of this work will describe the field test in a hot-dip-galvanizing/aluminizing plant of the mechanically alloyed bearing bushes under aluminum-rich liquid metal. Alter testing, the bushes will be characterized and obtained results with respect to wear. expected lifetime, surface roughness and infiltration will be discussed. Part III of this project will describe a second initial testing phase where the won results of part 1+11 will be transferred to the AI-Si system. Part IV of this project will describe the field test in a hot-dip-aluminizing plant of the mechanically alloyed bearing bushes under aluminum liquid metal. After testing. the bushes will be characterized and obtained results with respect to wear. expected lifetime, surface roughness and infiltration will be discussed.

  • PDF

A COMPARATIVE STUDY ON THE PHYSICAL PROPERTIES OF ORTHODONTIC PLIERS ACCORDING TO TYPES OF STERILIZATION (멸균 방법에 따른 교정용 플라이어의 물성 변화에 대한 비교 연구)

  • Cho, Il-Je;Son, Woo-Sung
    • The korean journal of orthodontics
    • /
    • v.28 no.2 s.67
    • /
    • pp.329-341
    • /
    • 1998
  • Sterilization has received much attention in orthodontic practices over the past several years. The present study was undertaken to investigate the effects of sterilization on the physical properties of orthodontic pliers-AEZ, Unitek, and Dentronix ligature cutters. This study was designed to examine the tips of ligature cutters before and after 200 and 400 sterilization cycles using the Bowmar RHT-1000, the Dentronix DDS-5000, and the Eschmann SES-2000. The tip surface and the fracture surface were observed with a scanning electron microscope. The microstructure was observed with an optical microscope. The hardness test was carried out with the mic개-Vickers hardness tester and the Rockwell C Scale hardness tester. The chemical composition was analyzed by energy dispersive X-ray spectrometer. The results of this study were as follows : 1. The number and the size of corrosion products on the tip surface and the proportion of cleavage planes in fractured specimen increased, but the hardness of the tip decreased in proportion to sterilization cycles. From these observations, it was considered that mechanical properities decreased in proportion to sterilization cycles. 2. The number and the size of chromium carbides increased in proportion to sterilization cycles. Coarse microstructure decreased mechanical properities. 3. The AEZ and Unitek ligature cutters were Fe-Cr stainless steels, but the Dentronix ligature cutter was Co-Cr alloy. There were many differences among manufactures, but the chemical composition was .not changed after sterilization cycles. 4. The tip edge of ligature cutter used in a clinic revealed microcracks with the SEM observation. Clinical experience confirmed that ligature cutters were gradually degraded by sterilization.

  • PDF

Analysis Technique for Chloride Behavior Using Apparent Diffusion Coefficient of Chloride Ion from Neural Network Algorithm (신경망 이론을 이용한 염소이온 겉보기 확산계수 추정 및 이를 이용한 염화물 해석)

  • Lee, Hack-Soo;Kwon, Seung-Jun
    • Journal of the Korea Concrete Institute
    • /
    • v.24 no.4
    • /
    • pp.481-490
    • /
    • 2012
  • Evaluation of chloride penetration is very important, because induced chloride ion causes corrosion in embedded steel. Diffusion coefficient obtained from rapid chloride penetration test is currently used, however this method cannot provide a correct prediction of chloride content since it shows only ion migration velocity in electrical field. Apparent diffusion coefficient of chloride ion based on simple Fick's Law can provide a total chloride penetration magnitude to engineers. This study proposes an analysis technique to predict chloride penetration using apparent diffusion coefficient of chloride ion from neural network (NN) algorithm and time-dependent diffusion phenomena. For this work, thirty mix proportions with the related diffusion coefficients are studied. The components of mix proportions such as w/b ratio, unit content of cement, slag, fly ash, silica fume, and fine/coarse aggregate are selected as neurons, then learning for apparent diffusion coefficient is trained. Considering time-dependent diffusion coefficient based on Fick's Law, the technique for chloride penetration analysis is proposed. The applicability of the technique is verified through test results from short, long term submerged test, and field investigations. The proposed technique can be improved through NN learning-training based on the acquisition of various mix proportions and the related diffusion coefficients of chloride ion.

An Experimental Study for the Effective Use Scheme of Snow Removal Materials on Road (도로 제설재의 효과적 사용방안에 관한 실험적 연구)

  • Do, Jongnam;Kim, Taesoo;Lee, Chanbok;Kim, Yeonjoong;Chun, Byungsik
    • Journal of the Korean GEO-environmental Society
    • /
    • v.13 no.2
    • /
    • pp.5-17
    • /
    • 2012
  • The amount of snow due to global warming and climate change has recently increased. The effective management of snow removal materials will be required. First, on the basis of domestic winter temperature, it is not necessary to get a baseline to less than the freezing point of $-52^{\circ}C$ for the calcium chloride($CaCl_2$) of 30%.. In terms of cost comparison between calcium chloride($CaCl_2$) and sodium chloride($NaCl$), the calcium chloride($CaCl_2$) is 2 to 3 times more expensive, and the supply of the calcium chloride($CaCl_2$) is not produced in domestic country and is in the conditions that have to imports all needed. Accordingly, the effective use scheme of snow removal materials should be considered to multifaceted ways. Thus, the objective of this study is to develop effective method and to replace from calcium choride($CaCl_2$) to sodium chloride($NaCl$) solution in the current snow removal operating system that uses a pre-wetted salt spreading method. The effective method that equals to the quality of the existing snow removal materials was developed in this study through performance tests for deicing chemicals, corrosion test of steel and freezing and thawing tests of concrete.

Influence of Temperature on Chloride Ion Diffusion of Concrete (콘크리트의 염화물이온 확산성상에 미치는 온도의 영향)

  • So, Hyoung-Seok;Choi, Seung-Hoon;Seo, Chung-Seok;Seo, Ki-Seog;So, Seung-Young
    • Journal of the Korea Concrete Institute
    • /
    • v.26 no.1
    • /
    • pp.71-78
    • /
    • 2014
  • The long term integrity of concrete cask is very important for spent nuclear fuel dry storage system. However, there are serious concerns about early deterioration of concrete cask from creaking and corrosion of reinforcing steel by chloride ion because the cask is usually located in seaside, expecially by combined deterioration such as chloride ion and heat, carbonation. This study is to investigate the relation between temperature and chloride ion diffusion of concrete. Immersion tests using 3.5% NaCl solution that were controlled in four level of temperature, i.e. 20, 40, 65, and $90^{\circ}C$, were conducted for four months. The chloride ion diffusion coefficient of concrete was predicted based on the results of profiles of Cl- ion concentration with the depth direction of concrete specimens using the method of potentiometric titration by $AgNO_3$. Test results indicate that the diffusion coefficient of chloride ion increases remarkably with increasing temperature, and there was a linear relation between the natural logarithm values of the diffusion coefficients and the reciprocal of the temperature from the Arrhenius plots. Activation energy of concrete in this study was about 46.6 (W/C = 40%), 41.7 (W/C = 50%), 30.7 (W/C = 60%) kJ/mol under a temperature of up to $90^{\circ}C$, and concrete with lower water-cement ratio has a tendency towards having higher temperature dependency.