• Title/Summary/Keyword: Steel Making

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Development of kW Class SOFC Systems for Combined Heat and Power Units at KEPRI

  • Lee, Tae-Hee;Choi, Jin-Hyeok;Park, Tae-Sung;Yoo, Keun-Bae;Yoo, Young-Sung
    • Journal of the Korean Ceramic Society
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    • v.45 no.12
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    • pp.772-776
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    • 2008
  • The Korea Electric Power Research Institute (KEPRI) has been developing planar solid oxide fuel cells (SOFCs) and power systems for combined heat and power (CHP) units. The R&D work includes solid oxide fuel cell (SOFC) materials investigation, design and fabrication of single cells and stacks, and kW class SOFC CHP system development. Anode supported cells composed of Ni-YSZ/FL/YSZ/LSCF were enlarged up to $15{\times}15\;cm^2$ and stacks were manufactured using $10{\times}10\;cm^2$ cells and metallic interconnects such as ferritic stainless steel. The first-generation system had a 37-cell stack and an autothermal reformer for use with city gas. The system showed maximum stack power of about $1.3\;kW_{e,DC}$ and was able to recover heat of $0.57{\sim}1.2\;kW_{th}$ depending on loaded current by making hot water. The second-generation system was composed of an improved 48-cell stack and a prereformer (or steam reformer). The thermal management subsystem design including heat exchangers and insulators was also improved. The second-generation system was successfully operated without any external heat source. Under self-sustainable operation conditions, the stack power was about $1.3\;kW_{e,DC}$ with hydrogen and $1.2\;kW_{e,DC}$ with city. The system also recuperated heat of about $1.1\;kW_{th}$ by making hot water. Recently KEPRI manufactured a 2kW class SOFC stack and a system by scaling up the second-generation 1kW system and will develop a 5kW class CHP system by 2010.

Using element-embedded rebar model in ANSYS for the study of reinforced and prestressed concrete structures

  • Lazzari, Bruna M.;Filho, Americo Campos;Lazzari, Paula M.;Pacheco, Alexandre R.
    • Computers and Concrete
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    • v.19 no.4
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    • pp.347-356
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    • 2017
  • ANSYS is a software well accepted by professionals and academics, since it provides a variety of finite elements, material constitutive models, and linear and nonlinear analysis of structures in general. For the concrete material, for instance, the software uses an elastoplastic model with the Willam-Warnke surface of rupture (1975). However, this model is only available for finite elements that do not offer the possibility of use of the element-embedded model for rebars, demanding a much larger amount of elements to discretize structures, making numerical solutions less efficient. This study is, therefore, about the development of a computational model using the Finite Element Method via ANSYS platform for nonlinear analysis of reinforced and prestressed concrete beams under plane stress states. The most significant advantage of this implementation is the possibility of using the element-embedded rebar model in ANSYS with its 2D eight-node quadratic element PLANE183 for discretization of the concrete together with element REINF263 for discretization of rebars, stirrups, and cables, making the solutions faster and more efficient. For representation of the constitutive equations of the steel and the concrete, a proposed model was implemented with the help of the UPF customization tool (User Programmable Features) of ANSYS, where new subroutines written in FORTRAN were attached to the main program. The numerical results are compared with experimental values available in the technical literature to validate the proposed model, with satisfactory results being found.

An Experimental Study on the Seismic Performance of Shear Connections and Rib Plate H Beam to Column Connections (전단접합 및 리브 플레이트로 보강한 H형 보-기둥 접합부의 내진성능에 관한 실험적 연구)

  • Oh, Kyung Hyun;Seo, Seong Yeon;Kim, Sung Yong;Yang, Young Sung;Kim, Kyu Suk
    • Journal of Korean Society of Steel Construction
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    • v.17 no.5 s.78
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    • pp.569-580
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    • 2005
  • The postbeam joint connection of the existing steel structure moment flexible frame system did not produce sufficient seismic resistance during the earthquakes in Northridge and Kobe, and it sustained brittle fracturing on the joint connection. This study was performed to execute the high-tensile bolt share connection of H-beams web and the full-scale experiment as a parameter of the existing reinforcement of H-flange rib, by making the shape of the existing joint connection. This experiment was performed to determine the extent of the decrease of the number of high-tensile bolts and how to improve workability of the two-phase shear connection of web beam. In addition, this study was performed to enhance the seismic resistant capacity through the enforcement of rib plates. As a result of the experiment of two-phase shear connection of H-beam web and of joint connection to be reinforced by rib plates, the results of this study showed that the initial stiffness, energy-dissipation capacity, and rotational capacity of plasticity was higher than the existing joint connection. As to the rate of increasing the strength and deformation capacity, there were differences between the tension side and compression side because of the position of shear tap. However, as a whole, they have shown excellent seismic resistant capacity. Also, all the test subjects exceeded 4% (rate of delamination), about 0.029 rad (total plastic capacity), and about 130% (maximum strength of joint connection) of fully plastic moment for the original section. Accordingly, this study was considered as it would be available in the design more than the intermediate-level of moment flexible frame.

Planarization of SUS310 Metal Substrate Used for Coated Conductor Substrate by Chemical Solution Coating Method (화학적인 용액 코팅방법에 의한 박막형 고온초전도체에 사용되는 SUS310 금속모재의 평탄화 연구)

  • Lee, J.B.;Lee, H.J.;Kim, B.J.;Kwon, B.K.;Kim, S.J.;Lee, J.S.;Lee, C.Y.;Moon, S.H.;Lee, H.G.;Hong, G.W.
    • Progress in Superconductivity
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    • v.12 no.2
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    • pp.118-123
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    • 2011
  • The properties of $2^{nd}$ generation high temperature superconducting wire, coated conductor strongly depend on the quality of superconducting oxide layer and property of metal substrate is one of the most important factors affecting the quality of coated conductor. Good mechanical and chemical stability at high temperature are required to maintain the initial integrity during the various process steps required to deposit several layers consisting coated conductor. And substrate need to be nonmagnetic to reduce magnetization loss for ac application. Hastelloy and stainless steel are the most suitable alloys for metal substrate. One of the obstacles in using stainless steel as substrate for coated conductor is its difficulties in making smooth surface inevitable for depositing good IBAD layer. Conventional method involves several steps such as electro polishing, deposition of $Al_2O_3$ and $Y_2O_3$ before IBAD process. Chemical solution deposition method can simplify those steps into one step process having uniformity in large area. In this research, we tried to improve the surface roughness of stainless steel(SUS310). The precursor coating solution was synthesized by using yttrium complex. The viscosity of coating solution and heat treatment condition were optimized for smooth surface. A smooth amorphous $Y_2O_3$ thin film suitable for IBAD process was coated on SUS310 tape. The surface roughness was improved from 40nm to 1.8 nm by 4 coatings. The IBAD-MgO layer deposited on prepared substrate showed good in plane alignment(${\Delta}{\phi}$) of $6.2^{\circ}$.

Development of the Fixed Slab Analogy Device for the Measurement of Stress Intensity Factor (응력확대계수 측정용 고정 슬랩상사 장치의 개발)

  • 정진석;최선호;황재석
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.16 no.11
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    • pp.1999-2010
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    • 1992
  • The fixed slab analogy device which can measure stress intensity factors(S.I.F) experimentally by slab analogy theory is developed in this paper. The margin of errors resulted from the new testing apparatus are between 0.02% and 8.25%. Therefore, it is assured that this one can be effectively used for the more accurate measurement of S.I.F.( $k_{I}$, $k_{I I}$) than conventional apparatus. The pitch of master grating used in this experiment is 0.1mm It is known that the ratio of the distance from crack tip to the crack length on obtaining the accurate stress intensity factor is between 0.4 and 0.7. The optimum curvature radius of slab is about 125mm. The thickness of slab(plate) used in the fixed slab analogy device is 0.05mm(P.V.C. ; E = 64 MN/ $m^{2}$, .nu.=0.38), which is proved to be suitable for the test. The optimum material for the frame(slab`s external boundary) is a alloy tool steel(SKS 5) plate and its thickness is 1mm. In this research, the rigid cracks are directly bonded to the slab surface by cyanoacrylate adhesive for the easiness of slab making and conformity to the practical crack figure. The material of rigid crack is thin steel plate. It is expected that the developed method can be used effectively for the analysis of $k_{I}$ and $k_{I I}$ of arbitrary shaped or distributed cracks.cks.

PEMOCVD of Ti(C,N) Thin Films on D2 Steel and Si(100) Substrates at Low Growth Temperatures

  • Kim, Myung-Chan;Heo, Cheol-Ho;Boo, Jin-Hyo;Cho,Yong-Ki;Han, Jeon-Geon
    • Proceedings of the Korean Vacuum Society Conference
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    • 1999.07a
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    • pp.211-211
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    • 1999
  • Titanium nitride (TiN) thin films have useful properties including high hardness, good electrical conductivity, high melting point, and chemical inertness. The applications have included wear-resistant hard coatings on machine tools and bearings, decorative coating making use of the golden color, thermal control coatings for widows, and erosion resistant coatings for spacecraft plasma probes. For all these applications as feature sizes shrink and aspect ratios grow, the issue of good step coverage becomes increasingly important. It is therefore essential to manufacture conformal coatings of TiN. The growth of TiN thin films by chemical vapor deposition (CVD) is of great interest for achieving conformal deposition. The most widely used precursor for TiN is TiCl4 and NH3. However, chlorine impurity in the as-grown films and relatively high deposition temperature (>$600^{\circ}C$) are considered major drawbacks from actual device fabrication. To overcome these problems, recently, MOCVD processes including plasma assisted have been suggested. In this study, therefore, we have doposited Ti(C, N) thin films on Si(100) and D2 steel substrates in the temperature range of 150-30$0^{\circ}C$ using tetrakis diethylamido titanium (TDEAT) and titanium isopropoxide (TIP) by pulsed DC plamsa enhanced metal-organic chemical vapor deposition (PEMOCVD) method. Polycrystalline Ti(C, N) thin films were successfully grown on either D2 steel or Si(100) surfaces at temperature as low as 15$0^{\circ}C$. Compositions of the as-grown films were determined with XPS and RBS. From XPS analysis, thin films of Ti(C, N) with low oxygen concentration were obtained. RBS data were also confirmed the changes of stoichiometry and microhardness of our films. Radical formation and ionization behaviors in plasma are analyzed by optical emission spectroscopy (OES) at various pulsed bias and gases conditions. H2 and He+H2 gases are used as carrier gases to compare plasma parameter and the effect of N2 and NH3 gases as reactive gas is also evaluated in reduction of C content of the films. In this study, we fond that He and H2 mixture gas is very effective in enhancing ionization of radicals, especially N resulting is high hardness. The higher hardness of film is obtained to be ca. 1700 HK 0.01 but it depends on gas species and bias voltage. The proper process is evident for H and N2 gas atmosphere and bias voltage of 600V. However, NH3 gas highly reduces formation of CN radical, thereby decreasing C content of Ti(C, N) thin films in a great deal. Compared to PVD TiN films, the Ti(C, N) film grown by PEMOCVD has very good conformability; the step coverage exceeds 85% with an aspect ratio of more than 3.

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Evaluation of PWHT cracking susceptibility of the Cr-Mo steel alloys (Cr-Mo 합금강의 후열처리 균열 감수성 평가)

  • Kim, Sang-Jin;Kim, Ki-Soo;Lee, Young-Ho
    • 대한공업교육학회지
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    • v.31 no.1
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    • pp.200-210
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    • 2006
  • This C-ring test, normally employed for evaluating susceptibility to stress-corrosion cracking, was determined to be a suitable small scale test to evaluate PWHT(Post-Weld Heat Treatment) cracking susceptibility. This test is possible to incorporate an actual weld, to introduce a notch into the coarse grained HAZ(Heat Affected Zone), to load the coarse grained HAZ any level of stress ad, most importantly, since the C-ring is an approximately constant strain type test, the stress decreases with time at temperature in a manner similar to that of an actual steel weldment. The procedure employed in making the C-ring was presented in the experimental procedure section, however, several points deserve further discussion. The walls of the weld groove are made along radial lines form the center of th var in order to obtain an HAZ which is oriented perpendicular to the walls of the machined C-ring. Therefore, the plane of maximum stress will be aligned through the HAZ and, therefore, crack propagation will not be forced to deviate form the plane of maximum stress in order to remain in the coarse grained HAZ as is the case with the Y groove test.

Basic Study on the Recycling of a Waste MgO-C Refractory Material as a Flux for EAF Steelmaking (전기로 폐 MgO-C계 내화재의 제강원료 활용 가능성 연구)

  • Wang, Jei-Pil;Kim, Hang-Goo;Go, Min-Seok;Lee, Dong-Hun
    • Resources Recycling
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    • v.30 no.6
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    • pp.53-60
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    • 2021
  • In EAF steelmaking industries, MgO content in slag increases due to the addition of dolomite flux to protect refractory lines of furnaces and improve the desulfurization capability of slag. In addition, coal powder is injected in the molten steel bath to increase the energy efficiency of the process. In this regard, the utilization of waste MgO-C refractory material as a flux was examined because it has high amounts of MgO (>70%) and graphite carbon (>10%). A series of experiments were carried out using industrial EAF slag with added light burnt dolomite and waste MgO refractory material from a Korean steel company. The results for the addition of the two fluxes were similar in terms of slag basicity; therefore, it is expected that waste MgO-C refractory material can successfully replace dolomite flux. In addition, when the waste MgO-C refractory material was added as flux, slag foaming phenomenon was demonstrated because of the reaction between the graphite from the refractory material and iron oxides in the slag.

Quantitative Deterioration and Maintenance Profiles of Typical Steel Bridges based on Response Surface Method (응답면 기법을 이용한 강교의 열화 및 보수보강 정량화 이력 모델)

  • Park, Seung-Hyun;Park, Kyung Hoon;Kim, Hee Joong;Kong, Jung-Sik
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.28 no.6A
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    • pp.765-778
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    • 2008
  • Performance Profiles are essential to predict the performance variation over time for the bridge management system (BMS) based on risk management. In general, condition profiles based on experts opinion and/or visual inspection records have been used widely because obtaining profiles based on real performance is not easy. However, those condition profiles usually don't give a good consistency to the safety of bridges, causing practical problems for the effective bridge management. The accuracy of performance evaluation is directly related to the accuracy of BMS. The reliability of the evaluation is important to produce the optimal solution for distributing maintenance budget reasonably. However, conventional methods of bridge assessment are not suitable for a more sophisticated decision making procedure. In this study, a method to compute quantitative performance profiles has been proposed to overcome the limitations of those conventional models. In Bridge Management Systems, the main role of performance profiles is to compute and predict the performance of bridges subject to lifetime activities with uncertainty. Therefore, the computation time for obtaining an optimal maintenance scenario is closely related to the efficiency of the performance profile. In this study, the Response Surface Method (RSM) based on independent and important design variables is developed for the rapid computation. Steel box bridges have been investigated because the number of independent design variables can be reduced significantly due to the high dependency between design variables.

Three-dimensional Numerical Modeling of Fluid Flow and Heat Transfer in Continuously Cast Billets (연속주조 빌렛의 3차원 열 및 유동해석)

  • Lee, Sung-Yoon;Lee, Sang-Mok;Park, Joong-Kil;Hong, Chun-Pyo
    • Journal of Korea Foundry Society
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    • v.20 no.5
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    • pp.290-299
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    • 2000
  • A three-dimensional model was developed in order to simulate heat and fluid flow of a continuous casting billet. The model was coded with the general-purpose CFD program FIDAP, using the finite element method. The present model consists of 2 individual calculation schemes, named model 1 and model 2. Mold region only was calculated to check the pouring stream through submerged nozzle with model 1. Entire region, which consists of mold, secondary cooling, radiation cooling was calculated to predict crater end position, temperature profile and solid shell profile(model 2). Standard $k-{\bullet}\hat{A}$ turbulence model has been applied to simulate the turbulent flow induced by submerged nozzle. Enthalpy method was adopted for the latent heat of solidification. Fluid flow in mushy zone was treated using variable viscosity approach. The more casting speed and superheat increased, the more metallurgical length increased. The shell thickness at the mold exit is proved to be mainly controlled by superheat by the present simulation. It may be concluded that the present model can be successfully applied far the prediction of heat and fluid flow behavior in the continuous casting process.

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