• Title/Summary/Keyword: Steam cleaning

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Chemically enhanced steam cleaning for the control of ceramic membrane fouling caused by manganese and humic acid (망간과 휴믹산에 의한 세라믹 막 오염의 제어를 위한 약품 스팀세정의 적용)

  • An, Sun-A;Park, Cheol-Gyu;Lee, Jin-San;Kim, Han-Seung
    • Journal of Korean Society of Water and Wastewater
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    • v.35 no.6
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    • pp.425-436
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    • 2021
  • In this study, chemically enhanced steam cleaning(CESC) was applied as a novel and efficient method for the control of organic and inorganic fouling in ceramic membrane filtration. The constant filtration regression model and the resistance in series model(RISM) were used to investigate the membrane fouling mechanisms. For total filtration, the coefficient of determination(R2) with an approximate value of 1 was obtained in the intermediate blocking model which is considered as the dominant contamination mechanism. In addition, most of the coefficient values showed similar values and this means that the complex fouling was formed during the filtration period. In the RISM, R c/R f increased about 4.37 times in chemically enhanced steam cleaning compared to physical backwashing, which implies that the internal fouling resistance was converted to cake layer resistance, so that the membrane fouling hardly to be removed by physical backwashing could be efficiently removed by chemically enhanced steam cleaning. The results of flux recovery rate showed that high-temperature steam may loosen the structure of the membrane cake layer due to the increase in diffusivity and solubility of chemicals and finally enhance the cleaning effect. As a consequence, it is expected that chemically enhanced steam cleaning can drastically improve the efficiency of membrane filtration process when the characteristics of the foulant are identified.

Development of Steam Cleaning Technique to Improve Removal Efficiency of Membrane Fouling Matter in Water Treatment Process Using Ceramic Membrane (정수처리용 세라믹 분리막의 막오염 물질의 제거 효율 향상을 위한 스팀세정 기법 개발)

  • Kang, Joon-Seok;Park, Seo Gyeong;Lee, Jeong Eun;Kang, So Yeon;Lee, Jeong Jun;Quyen, Vo Thi Kim;Kim, Han-Seung
    • Journal of Korean Society of Water Science and Technology
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    • v.26 no.6
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    • pp.99-107
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    • 2018
  • This research has developed a high temperature steam cleaning technology using a ceramic membrane with durability against temperature and pressure conditions. In steam cleaning, steam of $120^{\circ}C$ is injected into the ceramic membrane to induce pyrolysis by the endothermic reaction to remove fouling from the membrane. The water quality of raw water was adjusted to turbidity 10, 25 NTU and DOC 2.5 mg/L, and the membrane was uniformly fouled by constant pressure operation at 100, 200, and 300 kPa. Physical backwashing was performed with water and air at a pressure of 500 kPa and steam at $120^{\circ}C$ was injected for 0 to 5 minutes. As the turbidity concentration and the operating pressure increased, the flux decreased by 0.7 to 14.4%. It is confirmed that 10.7 to 53.8% recovery is possible than physical cleaning at the injection of steam for 3 minutes, so it is considered that the steam cleaning of the ceramic membrane is effective. Compared with CEB after NaOCl (300 mg/L) filtration at 25 NTU and 300 kPa of turbidity, the steam cleaning result for 3 minutes was similar to 46.7% of CEB for 3 hours. It has been confirmed that steam cleaning is suitable for a ceramic membrane having excellent heat resistance against high temperature. It was considered to have better cleaning efficiency as compared with general physical backwashing.

Effect of 20 % EDTA Aqueous Solution on Defective Tubes (Alloy600) in High Temperature Chemical Cleaning Environments (고온화학세정환경에서 20 % EDTA 용액이 결함 전열관 (Alloy600)에 미치는 영향)

  • Kwon, Hyuk-chul
    • Corrosion Science and Technology
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    • v.15 no.2
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    • pp.84-91
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    • 2016
  • The transport and deposition of corrosion products in pressurized water nuclear reactor (PWR) steam generators have led to corrosion (SCC, denting etc.) problems. Lancing, mechanical cleaning and chemical cleaning have been used to reduce these problems. The methods of lancing and mechanical cleaning have limitations in removing corrosion products due to the structure of steam generator tubes. But high temperature chemical cleaning (HTCC) with EDTA is the most effective method to remove corrosion products regardless of the structure. However, EDTA in chemical cleaning aqueous solution and chemical cleaning environments affects the integrity of materials used in steam generators. The nuclear power plants have to perform the pre-test (also called as qualification test (QT)) that confirms the effect on the integrity of materials after HTCC. This is one of the series studies that assess the effect, and this study determines the effects of 20 % EDTA aqueous solution on defective tubes in high temperature chemical cleaning environments. The depth and magnitude of defects in steam generator (SG) tubes were measured by eddy current test (ECT) signals. Surface analysis and magnitude of defects were performed by using SEM/EDS. Corrosion rate was assessed by weight loss of specimens. The ECT signals (potential and depth %) of defective tubes increased marginally. But the lengths of defects, oxides on the surface and weights of specimens did not change. The average corrosion rate of standard corrosion specimens was negligible. But the surfaces on specimens showed traces of etching. The depth of etching showed a range on the nanometer. After comprehensive evaluation of all the results, it is concluded that 20 % EDTA aqueous solution in high temperature chemical cleaning environments does not have a negative effect on defective tubes.

Cleaning System Design using Supper Heating Steam (과열 수증기를 이용한 세정 시스템 설계)

  • Cho, Do-Hyeoun
    • 전자공학회논문지 IE
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    • v.48 no.2
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    • pp.47-51
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    • 2011
  • In this paper, we propose the cleaning process system to remove micro-particles, various impurities, unnecessary residues, etc. for liquid crystal display manufacturing processes. This system is structured with cleaning, rinse and drying process using the chemical cleaning of alkaline water and the physical cleaning of SHS(supper heating steam). And we shows cleaning effects of alkaline water and remove effects of SHS.

Analysis of Chemical Cleaning for the Top-of-Tubesheet of NPP's Steam Generator (원전 증기발생기 관판 상단 화학세정 결과 분석)

  • Lee, Han-Chul;Sung, Ki-Bang
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.14 no.4
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    • pp.2043-2048
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    • 2013
  • OPR-1000 CE Steam Generator, of which tube material is composed of Alloy-600 HTMA in nuclear power plant, secondary side is generated ODSCC(Outside Diameter Stress Corrosion Cracking) due to the accumulated sludge. ODSCC is centered around the tube sheet and is being affected depending on the height of the sludge. Chemical cleaning was carried out for a top-of-the-tube sheet(TTS) of Steam Generator in order to decrease corrosive condition of the secondary side of Steam Generator tubes and suppress the occurrence of stress corrosion cracking. The amount of sludge removal was 259.2kg. The height of the accumulated sludge was reduced from 0.71 to 0.34 inches. Corrosion rate as the maximum 2.34 mils was satisfied to within EPRI (Electric Power Research Institute) recommendation(10 mils).

Ultrasonic Immersion-steam Cleaning and High Temperature Drying Process for Removing Cutting Oil on Titanium Turning Scraps (타이타늄 터닝 스크랩 내 절삭유 제거를 위한 초음파 침지-스팀 및 고온 건조 공정)

  • Chae, Jikwang;Yoo, Suhwan;Oh, Jung-Min;Lim, Jae-Won
    • Resources Recycling
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    • v.30 no.1
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    • pp.60-65
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    • 2021
  • The recycling of titanium turning scraps requires the removal of cutting oil and other contaminants remaining on the surface. In this study, an experiment was conducted in which titanium scraps were cleaned by a combination of ultrasonic immersion-steam cleaning and subsequent drying at high temperature. To determine the removal mechanism of cutting oil, the contact angle between titanium surface and cutting oil was measured. The result confirmed the optimum condition of the immersion solution of the titanium turning scraps. In the case of immersion cleaning of Na4P2O7 aqueous solution, the degree of carbon removed in the cutting oil was the highest at 50℃, and it was confirmed that the carbon content obtained from the combination of steam cleaning and ultrasonic immersion-steam cleaning was lower than that from steam cleaning after ultrasonic immersion. The oxidation and decomposition behaviors of cutting oil were investigated using Thermogravimetric analysis (TGA) and the result was applied in the high temperature drying process. From the results of the high temperature drying tests, it was concluded that 200℃ is the optimal drying temperature.

Phase transition of Zirconia by surface treatments (지르코니아 표면 가공에 따른 상변이)

  • Lee, Jung-Soo;Shim, Jeong-Seok;Jung, Hyung-Ho
    • Journal of Technologic Dentistry
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    • v.32 no.2
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    • pp.57-63
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    • 2010
  • Purpose : This study aimed to find out the effects of treatments on the surface of Zirconia. Methods : To this end, we selected six treatments that have been used widely: steam cleaning, 2bar & 6bar sand blasting, grinding by green stone point, grinding by diamond bur, and grinding by diamond bur with water spray. Results : The results of our study showed that monoclinic rate increased from all six treatments. Monoclinic rate varied by treatments, ranged from 0.6% (steam cleaning) to 6.5% (6bar sand blasting). These values from all six treatments were below ISO 13356 standard, which is 25%. Also, we found that two treatments (green stone point and diamond bur) increased roughness of surface of Zirconia. Conclusion : This study concluded that phase changes of Zirconia were not significant by using six treatments we employed.

DEVELOPMENT OF A STEAM GENERATOR LANCING SYSTEM

  • Jeong Woo-Tae;Kim Seok-Tae;Hong Sung-Yull
    • Nuclear Engineering and Technology
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    • v.38 no.4
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    • pp.391-398
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    • 2006
  • It is recommended to clean steam generators of nuclear power plants during plant outages. Under normal operations, sludge is created and constantly accumulates in the steam generators. The constituents of this sludge are different depending on each power plant characteristics. The sludge of the Kori Unit 1 steam generator, far example, was found to be composed of 93% ferrous oxide, 3% carbon and 1% of silica oxide and nickel oxide each. The research to develop a lancing system that would remove sludge deposits from the tubesheet of a steam generator was started in 1998 by the Korea Electric Power Research Institute (KEPRI) of the Korea Electric Power Corporation (KEPCO). The first commercial domestic lancing system in Korea, the $KALANS^(R)-I$ Lancing System, was completed in 2000 for Kori Unit 1 for cleaning the tubesheet of its Westinghouse Delta-60 steam generator. Thereafter, the success of the development and site implementation of the $KALANS^(R)-I$ lancing system for YGN Units 1&2 and Ulchin Units 3&4 was also realized in 2004 for sludge removal at those sites. The upper bundle cleaning system for Westinghouse model F steam generators is now under development.