• Applied Microscopy
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• v.45 no.3
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• pp.177-182
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• 2015

The boiler tubes of X20CrMoV12.1 used in fossil-fired power plants were obtained and analyzed for the effect of water treatment on the steam corrosion-induced oxide scale in an effort to better understand the oxide formation mechanism, as well as pertinent method of maintenance and lifetime extension. The specimens were analyzed using various microscopy and microanalysis techniques, with focuses on the effect of water treatment on the characters of scale. X-ray diffraction analysis showed that the scales of specimens were composed of hematite ($Fe_2O_3$), magnetite ($Fe_3O_4$), and chromite ($FeCr_2O_4$). Electron backscatter diffraction analysis showed that the oxides were present in the following order on the matrix: outer $Fe_2O_3$, intermediate $Fe_3O_4$, and inner $FeCr_2O_4$. After all volatile treatment or oxygenated treatment, a dense protective $Fe_2O_3$ layer was formed on the $Fe_3O_4$ layer of the specimen, retarding further progression of corrosion.

• Transactions of the Korean Society of Automotive Engineers
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• v.22 no.3
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• pp.1-11
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• 2014

The aim of this study is to investigate the effect of SCR reactor on the exhaust emissions characteristics in order to develop a urea-SCR aftertreatment system for reducing $NO_x$ emissions. The experiments are conducted by using a flue tube LPG steam boiler with the urea-SCR aftertreatment system. The urea-SCR aftertreatment system utilizes the ammonia converted from 17% aqueous urea solution injected in front of SCR catalyst as a reducing agent for reducing $NO_x$ emissions. The equivalence ratio, urea injection amount, ammonia slip and $NO_x$ conversion efficiency relative to boiler load are applied to discuss the experimental results. In this experiment, the average equivalence ratio is calculated by changing only the fuel consumption rate while the intake air amount is constantly fixed at $25,957.11cm^3/sec$. The average equivalence ratios are 1.38, 1.11, 0.81 and 0.57 when boiler loads are 100, 80, 60 and 40%. The $NO_x$ conversion efficiency is raised with increasing urea injection amount, and $NH_3$ slip is also boosted at the same time. Consequently, the $NO_x$ conversion efficiency relative to boiler load should be examined in combination with urea injection amount and $NH_3$ slip. The results are calculated by 89, 85, 77 and 79% for the boiler loads of 100, 80, 60 and 40%. The appropriate amount of urea injection for the respective boiler load can be not discussed by only $NO_x$ emissions, and should be determined by considering the $NO_x$ conversion efficiency, $NH_3$ slip and reactive activation temperature simultaneously. In this study, the urea amounts of 230, 235, 233 and 231 mg/min are injected at the boiler loads of 100, 80, 60 and 40%, and the final $NH_3$ slips are measured by 8.48, 5.58, 11.97 and 11.34 ppm at the same conditions. THC emission is affected by the SCR reactor under other experimental conditions except 100% engine load, and CO emission at only 40% engine load. The rest of exhaust emissions are not affected by the SCR reactor under all experimental conditions.

• Journal of Hydrogen and New Energy
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• v.21 no.5
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• pp.452-459
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• 2010

This study is aimed to investigate changes of combustion characteristics and heat efficiency when syngas from gasification process using low-rank fuel such as waste and/or biomass is applied partially to an industrial boiler. An experimental study on syngas co-combustion was performed in a 0.7 MW (1 ton steam/hr) water tube boiler using heavy oil as a main fuel. Three kinds of syngas were used as an alternative fuel: mixture gas of pure carbon monoxide and hydrogen, syngas of low calorific value generated from an air-blown gasification process, and syngas of high calorific value produced from an oxygen-blown gasification process. Effects of co-combustion ratio (0~20%) for each syngas on flue gas composition were investigated through syngas injection through the nozzles installed in the side wall of the boiler and measuring $O_2$, $CO_2$, CO and NOx concentrations in the flue gas. When syngas co-combustion was applied, injected syngas was observed to be burned completely and NOx concentration was decreased because nitrogen-containing-heavy oil was partially replaced by the syngas. However, heat efficiency of the boiler was observed to be decreased due to inert compounds in the syngas and the more significant decrease was found when syngas of lower calorific value was used. However, the decrease of the efficiency was under 10% of the heat replacement by syngas.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.21 no.3
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• pp.157-166
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• 2009

The pulverized coal combustion behavior in the coal fired utility boiler has been investigated with the CFD and process analysis techniques. The used commercial software were CFX and PROATES, and these were coupled each other to get more reliable boundary condition set-up, resulting in more reliable solution. For two cases which were the actual operation condition of A power plant, the calculated values from the coupled CFD and process analysis for thermal energy system were compared with the plant data, and the good agreements were obtained for Case 1 and 2. The calculated temperature distributions on the surface of heat exchangers were compared with the plant data for the steam temperatures across heat exchangers, and these explained the actual operating situation very well. The temperature deviation across the final superheater tube, which was believed to be the main cause of the frequent tube failure, were also explained very well with the calculated distributions of gas temperature and radiation on the plane of the final superheater.

• 한국연소학회:학술대회논문집
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• 2006.10a
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• pp.276-281
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• 2006

Although fireside corrosion of heat transfer surfaces in coal fired steam generators has been a problem to some extent for a number of tears, with the advent of low NOx firing systems these surfaces can be exposed to conditions that will exacerbate wastage rates. Numerous reports of waterwall wastage in coal fired boilers have appeared in the literature. It is believed that wastage results both from gaseous phase attack of metal surfaces and from deposition of ash and unburned fuel. Gaseous phase attack is known to occur in the presence of reducing sulfur species such as $H_2S$ and in the presence of fuel chlorine. The highest wastage rates are thought to be due to deposition of unoxidized material and the presence of fuel chlorine. Localized wall and near wall conditions that may exacerbate wastage include reducing conditions, high temperatures, high heat fluxes, and a high fraction of unoxidized material deposited. So, this study is directed at developing an advanced corrosion model in coal-fired utility boilers.

• Proceedings of the KIEE Conference
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• 2008.07a
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• pp.1663-1664
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• 2008

Many years ago, most of thermal power plants built in this country were of subcritical pressure, of medium or small size, of constant pressure operations and of drum type steam generators with circulation type boilers. But, nowadays almost all of them were of high efficiency, of supercritical pressure, of big capacity, of sliding pressure operations, and of once through type steam generators. Presently built once through boilers introduce turbine bypass systems to variable pressure operation which eliminates unexpected materials in boiler tube during startup, minimizes fuel loss by short startup period and eventually improve both total efficiency and power system stability.

• Journal of the Korean Society of Fisheries and Ocean Technology
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• v.34 no.2
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• pp.200-211
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• 1998

Heat transfer performance improvement by fin and groovs is studied for condensation of R-11 on integral-fin tubes. Eight tubes with trapczodially shaped integral-fins having fin density from 748 to 1654fpm(fin per meter) and 10, 30 grooves are tested. A plain tube having the same diameter as the finned tubes is also used for comparison. R-11 condensates at saturation state of 32 $^{\circ}C$ on the outside tube surface coded by inside water flow. All of test data are taken at steady state. The heat transfer loop is used for testing singe long tubes and cooling is pumped from a storage tank through filters and folwmeters to the horizontal test section where it is heated by steam condensing on the outside of the tubes. The pressure drop across the test section is measured by menas pressure gauge and manometer. The results obtained in this study is as follows : 1. Based on inside diameter and nominal inside area, overall heat transfer coefficients of finned tube are enhanced up to 1.6 ~ 3.7 times that of a plain tube at a constant Reynolds number. 2. Friction factors are up to 1.6 ~ 2.1 times those of plain tubes. 3. The constant pumping power ratio for the low integral-fin tubes increase directly with the effective area to the nominal area ratio, and with the effective area diameter ratio. 4. A tube having a fin density of 1299fpm and 30 grooves has the best heat transfer performance.

• Journal of Fisheries and Marine Sciences Education
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• v.6 no.1
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• pp.58-76
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• 1994

Heat transfer and pressure drop measurements are made on low integral-fin tubes in turbulent water flow condition. The integral-fin tubes investigated in this paper are nominally 19mm in diameter. Eight tubes have been used with trapezoidally shaped integral-fins having fin density from 748 to 1654 fpm and 10, 30 grooves. Plain tube having same diameter as finned tube is also tested for comparison. Experiments are carried out using R-11 as working fluid. The refrigerant condensates at a saturation state of $30^{\circ}C$ on the outside tube surface cooled by coolant. The amount of noncondensable gases present in the test loop is reduced to a negligible value by repeated purging. For a given heat input to the boiler and given cooling water flow rate, all test data are taken on steady state. The heat transfer loop is used for testing single long tubes and cooling water is pumped from a storage tank through filters and flowmeters to the horizontal test section where it is heated by steam condensing on the outside of the tube. The pressure drop across the test section is measured by means of pressure gauge and manometer. Each tube tested is cleaned with sodium dichromate pickling solution and well rinsed with water prior to installation in the test section. The results obtained in this study is as follows : 1. Based on inside diameter and nominal inside area, heat transfer of finned tube is enhanced up to 4 times as that of a plain tube at constant Reynolds number and up to 2 times at constant pumping power. 2. Friction factors are up to 1.6~2.1 times those of plain tube. 3. At a given Reynolds number, Nusselt number decrease with increasing pitch to diameter. 4. The constant pumping power ratio for low integral-fin tubes increase directly with the effective area to the nominal area ratio, and with the effective area diameter ratio.

• Journal of the Korean Society of Fisheries and Ocean Technology
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• v.52 no.3
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• pp.257-262
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• 2016

Flexible two-phase thermosyphons are devices that can transfer large amounts of heat flux with boiling and condensation of working fluid resulting from small temperature differences. A flexible two-phase thermosyphon consists of a evaporator, an insulation unit, and a condenser. The working fluid inside the evaporator is evaporated by heating the evaporator in the lower part of the flexible two-phase thermosyphon and the evaporated steam rises to the condenser in the upper part to transfer heat in response to the cooling fluid outside the tube. The resultant condensed working fluid flows downward along the inside surface of the tube due to gravity. These processes form a cycle. Using R134a refrigerant as the working fluid of a loop type flexible two-phase thermosyphon heat exchanger, an experiment was conducted to analyse changes in boiling heat transfer performances according to differences in the temperature of the oil for heating of the evaporator, the temperature variations of the refrigerant, and the mass flows. According to the results of the present study, the circulation rate of the refrigerant increased and the pressure in the evaporator also increased proportionally as the temperature of the oil in the evaporator increased. In addition, the heat transfer rate of the boiler increased as the temperature of the oil in the evaporator increased.

• Plant Journal
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• v.9 no.4
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• pp.26-30
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• 2013

Based on case that HRSG low pressure steam generator tube was damaged by FAC in 500 MW A CCPP. This case analyzed the effect of application about the block of hydrazine water treatment which is applied for increasing dissolved oxygen. And also try to deduce the major factor of FAC Which is caused by lacking of dissolved oxygen of boiler feed system. After 1 year of water treatment, the figure of dissolved oxygen in the boiler feed water has increased from 0.15 ppb to 3~5 ppb and the figure of oxidation reduction potential has increased from -245 mV to 170 mV. And Iron content, the corrosion products by FAC has decreased from 18.5 ppb to 5~7 ppb. According to the result of experiment, we could able to confirm that the interception of hydrazine of water treatment is effective to reduce FAC.